Intraplate strike-slip faulting in East Antarctica: new geophysical views from the Rennick Graben and Wilkes Subglacial Basin

Intraplate strike-slip faulting can occur in association with different geodynamic settings, ranging from subduction-related to collision and extension. Geological and geophysical research in Northern Victoria Land (NVL) in East Antarctica, has led to the interpretation that major fault systems that were active during the early Paleozoic Ross Orogen were reactivated much later as right-lateral intraplate strike-slip fault systems from ca 48 Ma, and that these faults may have accomodated differential shear along evolving oceanic transform faults located between southeastern Australia and Tasmania. One of the main structures in NVL that has been inferred to relate to this unusual geodynamic process is the Rennick Graben (RG), but its age, extent and kinematics have remained both poorly constrained and controversial. Even less well-understood are the potential tectonic linkages between the RG and the deep sub-basins that lie within the much broader Wilkes Subglacial Basin (WSB), in the hinterland of the Transantarctic Mountains. Here, we present new interpretations of enhanced potential field images derived from aeromagnetic and airborne and land-gravity observations to help constrain the extent and architecture of the RG and the sub-basins within the WSB. We show that the RG is a composite pull-part basin that extends from the Oates Coast towards the margin of the Ross Sea Rift, part of the West Antarctic Rift System. We suggest that the more cratonic WSB region was also affected by extensional and transtensional processes, the latter potentially linked to an evolving and distributed left-lateral Paleogene(?) strike-slip plate boundary between East Antarctica and Australia

Capturing player enjoyment in computer games

The current state-of-the-art in intelligent game design using Artificial Intelligence (AI) techniques is mainly focused on generating human-like and intelligent characters. Even though complex opponent behaviors emerge through various machine learning techniques, there is generally no further analysis of whether these behaviors contribute to the satisfaction of the player. The implicit hypothesis motivating this research is that intelligent opponent behaviors enable the player to gain more satisfaction from the game. This hypothesis may well be true; however, since no notion of entertainment or enjoyment is explicitly defined, there is therefore no evidence that a specific opponent behavior generates enjoyable games.peer-reviewe

New Zinc-Based Active Chitosan Films: Physicochemical Characterization, Antioxidant, and Antimicrobial Properties

The improvement of the antioxidant and antimicrobial activities of chitosan (CS) films can be realized by incorporating transition metal complexes as active components. In this context, bioactive films were prepared by embedding a newly synthesized acylpyrazolonate Zn(II) complex, [Zn(QPhtBu)2(MeOH)2], into the eco-friendly biopolymer CS matrix. Homogeneous, amorphous, flexible, and transparent CS@Znn films were obtained through the solvent casting method in dilute acidic solution, using different weight ratios of the Zn(II) complex to CS and characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR), Raman, and scanning electron microscopy (SEM) techniques. The X-ray single-crystal analysis of [Zn(QPhtBu)2(MeOH)2] and the evaluation of its intermolecular interactions with a protonated glucosamine fragment through hydrogen bond propensity (HBP) calculations are reported. The effects of the different contents of the [Zn(QPhtBu)2(MeOH)2] complex on the CS biological proprieties have been evaluated, proving that the new CS@Znn films show an improved antioxidant activity, tested according to the DPPH method, with respect to pure CS, related to the concentration of the incorporated Zn(II) complex. Finally, the CS@Znn films were tried out as antimicrobial agents, showing an increase in antimicrobial activity against Gram-positive bacteria (Staphylococcus aureus) with respect to pure CS, when detected by the agar disk-diffusion method

Low-Temperature Hydrogen Formation During Aqueous Alteration of Serpentinized Peridotite in the Samail Ophiolite

Serpentinized peridotite is reacting with groundwater in the subsurface of the Samail ophiolite in Oman. Although these rocks are partially to completely serpentinized, they interact with a groundwater aquifer containing hyperalkaline fluids rich in H2 and CH4. Since the mechanisms by which H2 production may continue at low temperatures (<50\ub0C) are not fully understood, core recovered during the Oman Drilling Project provides an excellent opportunity to study the mineralogy and Fe speciation in highly serpentinized harzburgite recording multiple stages of water/rock interaction. In Hole BA3A, early hydration of olivine and pyroxene, which likely occurred at temperatures of 3c100\ub0C\u2013200\ub0C, produced serpentine, Fe-rich brucite, awaruite, and little magnetite. Notably, Fe-rich brucite is only preserved at > 3c100 m depth in the core. Fe-rich brucite is nearly absent within two near-surface reaction zones where later stages of reaction are recorded, which include replacement of Fe-rich brucite by Fe(III)-bearing serpentine, and increases in the proportion of other Fe(III)-bearing phases such as magnetite and hydroandradite. Thus, Fe-rich brucite at depth represents substantial stored capacity for H2 production that can continue at low temperature, even after primary olivine and pyroxene are exhausted, thereby sustaining habitable conditions for microbial life

Anion dependent mesomorphism in coordination networks based on 2,2 -bipyridine silver(I) complexes

The reaction of the promesogenic dihexadecyl-2,2\ua2-bipyridine-4,4\ua2-dicarboxylate (L16) with a number of AgX salts produces a series of silver(I) complexes [(L16)Ag(sac)], 1, [(L16)Ag(NO3)], 2, [(L16)Ag(OTf)], 3, and [(L16)3Ag2](ClO4)2, 4, whose stoichiometries, molecular architectures, supramolecular networks and mesomorphic behaviour are \u201canion dependent\u201d. In spite of the large differences in the single molecular structure, the one-dimensional coordination networks involving the triflate and perchlorate in complexes 3 and 4, are the key element for inducing significant argentophilic intermolecular interactions responsible for the induction of lamello-columnar mesomorphism in both Ag(I) derivatives. Moreover, a series of Ag(I) triflate model complexes have been synthesized and in order to get more insights about their solid state architectures, systematic structural studies have been performed

Carbonation of subduction-zone serpentinite (high-pressure ophicarbonate; Ligurian Western Alps) and implications for the deep carbon cycling

Much of the long-term carbon cycle in solid earth occurs in subduction zones, where processes of devolatilization, partial melting of carbonated rocks, and dissolution of carbonate minerals lead to the return of CO2 to the atmosphere via volcanic degassing. Release of COH fluids from hydrous and carbonate minerals influences C recycling and magmatism at subduction zones. Contradictory interpretations exist regarding the retention/storage of C in subducting plates and in the forearc to subarc mantle. Several lines of evidence indicate mobility of C, of uncertain magnitude, in forearcs. A poorly constrained fraction of the 40-115 Mt/yr of C initially subducted is released into fluids (by decarbonation and/or carbonate dissolution) and 18-43 Mt/yr is returned at arc volcanoes. Current estimates suggest the amount of C released into subduction fluids is greater than that degassed at arc volcanoes: the imbalance could reflect C subduction into the deeper mantle, beyond subarc regions, or storage of C in forearc/subarc reservoirs.We examine the fate of C in plate-interface ultramafic rocks, and by analogy serpentinized mantle wedge, via study of fluid-rock evolution of marble and variably carbonated serpentinite in the Ligurian Alps. Based on petrography, major and trace element concentrations, and carbonate C and O isotope compositions, we demonstrate that serpentinite dehydration at 2-2.5 GPa, 550 °C released aqueous fluids triggering breakdown of dolomite in nearby marbles, thus releasing C into fluids. Carbonate + olivine veins document flow of COH fluids and that the interaction of these COH fluids with serpentinite led to the formation of high-P carbonated ultramafic-rock domains (high-P ophicarbonates). We estimate that this could result in the retention of ~0.5-2.0 Mt C/yr in such rocks along subduction interfaces. As another means of C storage, 1 to 3 km-thick layers of serpentinized forearc mantle wedge containing 50 modal % dolomite could sequester 1.62 to 4.85 Mt C/yr.We stress that lithologically complex interfaces could contain sites of both C release and C addition, further confounding estimates of net C loss at forearc and subarc depths. Sites of C retention, also including carbonate veins and graphite as reduced carbonate, could influence the transfer of slab C to at least the depths beneath volcanic fronts