Cervelleite, Ag4TeS: solution and description of the crystal structure

Copyright: Springer-Verlag Wien 2015. This is the final, post refereeing version. You are advised to consult the publisher's version if you wish to cite from it, http://link.springer.com/article/10.1007%2Fs00710-015-0384-

Grundmannite, CuBiSe2, the Se-analogue of emplectite, a new mineral from the El Dragón mine, Potosí, Bolivia

© 2016 E. Schweizerbart'sche Verlagsbuchhandlung Science Publishers. Also published by Deutsche Mineralogische Gesellschaft, Sociedad Española de Mineralogía, Società Italiana di Mineralogia e Petrologia, Société Française de Minéralogie et de Cristallographie under the auspices of the European Mineralogical Union. This document attached is the author's submitted version of the journal article. You are advised to consult the publisher's version if you wish to cite from it

Potassium-bearing clinopyroxene: a review of experimental, crystal chemical and thermodynamic data with petrological applications

Adsorption of chlorinated organic compounds (COC) on activated charcoal and determination of ionic chlorine by gas chromatography were used for assessment of water pollution by COC. Content of adsorbing COC was the following (micrograms CI-/l): in river water 10-470, in drinking water 10-1180, in underground water 90-150; content of volatile COC was (micrograms CI-/l): in drinking water 2-117, in underground water 14-16

Task 2 - Deliverable 4: Software for strong-motion data display and processing

The deliverable 4 is composed by a set of routines created to read and process the time series stored in the data base format, that is an ASCII file with a 43 row header, with the name codified as specified in the Deliverable 1. The files can also be read in SAC format

The Local Interstellar Spectrum of Cosmic Ray Electrons

The direct measurements of electrons and positrons over the last 30 years, corrected for the solar effect in the force-field approximation, are considered. The resulting overall electron spectrum may be fitted with a single power law above few GeV with spectral index ($\gamma_{-} = 3.41 \pm 0.02$), consistent with the spectral index of the positron spectrum ($\gamma_{+} = 3.40 \pm 0.06$), therefore suggesting a common acceleration process for both species. We propose that the engine was a shock wave originating from the last supernova explosion among those that formed the local bubble. In addition, at low energy, the electron spectrum measured during the last $A+$ solar phase is damped, whereas the positron spectrum is well represented by a single power law down to the lowest inferred local interstellar energy (0.8 GeV). We suggest that this difference arises from a time- and charge-dependent effect of the solar modulation that is not taken into account by the force-field approximation.Comment: 10 pages, 9 figures, 1 table. OBSOLETE: please refer to ApJ 612 (2004) 262-267, that is the final version of this wor

The crystal structure of alstonite, BaCa(CO3)2: An extraordinary example of 'hidden' complex twinning in large single crystals

Alstonite, BaCa(CO3)2, is a mineral described almost two centuries ago. It is widespread in Nature and forms magnificent cm-sized crystals. Notwithstanding, its crystal structure was still unknown. Here, we report the crystal-structure determination of the mineral and discuss it in relationship to other polymorphs of BaCa(CO3)2. Alstonite is trigonal, space group P31m, with unit-cell parameters a = 17.4360(6), c = 6.1295(2) Å, V = 1613.80(9) Å3 and Z = 12. The crystal structure was solved and refined to R1 = 0.0727 on the basis of 4515 reflections with Fo > 4σ(Fo) and 195 refined parameters. Alstonite is formed by the alternation, along c, of Ba-dominant and Ca-dominant layers, separated by CO3 groups parallel to {0001}. The main take-home message is to show that not all structure determinations of minerals/compounds can be solved routinely. Some crystals, even large ones displaying excellent diffraction quality, can be twinned in complex ways, thus making their study a crystallographic challenge

Crystal chemistry of sulfates from the apuan alps (Tuscany, Italy). V. Scordariite, K8(Fe3+0.67 0.33)[Fe3+3O(SO4)6(H2O)3]2(H2O)11: A new metavoltine-related mineral

The new mineral species scordariite, K8(Fe3+0.67 0.33)[Fe3+3O(SO4)6(H2O)3]2(H2O)11, was discovered in the Monte Arsiccio mine, Apuan Alps, Tuscany, Italy. It occurs as pseudo-hexagonal tabular crystals, yellowish to brownish in color, up to 0.5 mm in size. Cleavage is perfect on 0001. It is associated with giacovazzoite, krausite, gypsum, jarosite, alum-(K), and magnanelliite. Electron microprobe analyses give (wt %): SO3 47.31, Al2O3 0.66, Fe2O3 24.68, FeO 0.69, Na2O 0.52, K2O 17.36, H2Ocalc 15.06, total 106.28. The partitioning of Fe between Fe2+ and Fe3+ was based on Mössbauer spectroscopy. On the basis of 67 O atoms per formula unit, the empirical chemical formula is (K7.50Na0.34)Σ7.84(Fe3+6.29Al0.26Fe2+0.20)Σ6.75S12.02O50·17H2O. The ideal end-member formula can be written as K8(Fe3+0.67 0.33)[Fe3+3O(SO4)6(H2O)3]2(H2O)11. Scordariite is trigonal, space group R-3, with (hexagonal setting) a = 9.7583(12), c = 53.687(7) Å, V = 4427.4(12) Å3, Z = 3. The main diffraction lines of the observed X-ray powder pattern are [d(in Å), estimated visual intensity]: 8.3, strong; 6.6, medium; 3.777, medium; 3.299, medium; 3.189, medium; 2.884, strong. The crystal structure of scordariite has been refined using X-ray single-crystal data to a final R1 = 0.057 on the basis of 1980 reflections with Fo > 4σ(Fo) and 165 refined parameters. It can be described as a layered structure formed by three kinds of layers. As with other metavoltine-related minerals, scordariite is characterized by the occurrence of the [Fe3+3O(SO4)6(H2O)3]5- heteropolyhedral cluster

Can quasicrystals survive in planetary collisions?

We investigated the compressional behavior of i-AlCuFe quasicrystal using diamond anvil cell under quasi-hydrostatic conditions by in situ angle-dispersive X-ray powder diffraction measurements (in both compression and decompression) up to 76 GPa at ambient temperature using neon as pressure medium. These data were compared with those collected up to 104 GPa using KCl as pressure medium available in literature. In general, both sets of data indicate that individual d-spacing shows a continuous decrease with pressure with no drastic changes associated to structural phase transformations or amorphization. The d/d0, where d0 is the d-spacing at ambient pressure, showed a general isotropic compression behavior. The zero-pressure bulk modulus and its pressure derivative were calculated fitting the volume data to both the Murnaghan- and Birch-Murnaghan equation of state models. Results from this study extend our knowledge on the stability of icosahedrite at very high pressure and reinforce the evidence that natural quasicrystals formed during a shock event in asteroidal collisions and survived for eons in the history of the Solar System. [Figure not available: see fulltext.

Quijarroite, Cu6HgPb2Bi4Se12, a New Selenide from the El Dragόn Mine, Bolivia

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