Sandwich-type zeolite intergrowths with MFI and the novel extralarge pore IDM-1 as ordered end-members

Stacking faults are two-dimensional planar defects frequently arising in zeolites, modifying their properties and potentially affecting their performance in catalysis and separation applications. In classical zeolite intergrowths, a topologically unique zeolite layer may often pile up after some spatial transformation (lateral translation, rotation, and/or reflection) that may occur in different amounts or directions with about similar probabilities, leading to a difficult to control disorder. Here, we present a new kind of zeolite intergrowth that requires an additional topologically distinct layer rather than a spatial transformation of a unique one. Stacking of the so-called pentasil layers produces the well-known medium pore zeolite MFI. Intercalation in strict alternation of a topologically distinct second layer sandwiched between pentasil layers expands the structure to produce the new extra-large pore IDM-1. Stacking disorder modulates the structural expansion along the stacking direction. The disordered materials have been studied by simulation of the X-ray diffraction patterns using the program DIFFaX and by Cs-corrected high-resolution electron microscopy. We show that disorder does not occur at random but in extended domains and can be controlled all the way from MFI to IDM-1 by just varying the concentration of the synthesis mixture

First Census of Gas-phase Metallicity Gradients of Star-forming Galaxies in Overdense Environments at Cosmic Noon

We report the first spatially resolved measurements of gas-phase metallicity radial gradients in star-forming galaxies in overdense environments at $z\gtrsim2$. The spectroscopic data are acquired by the \mg\ survey, a Hubble Space Telescope (HST) cycle-28 medium program. This program is obtaining 45 orbits of WFC3/IR grism spectroscopy in the density peak regions of three massive galaxy protoclusters (BOSS 1244, BOSS 1542 and BOSS 1441) at $z=2-3$. Our sample in the BOSS 1244 field consists of 20 galaxies with stellar-mass ranging from $10^{9.0}$ to $10^{10.3}$ \Msun\ , star formation rate (SFR) from 10 to 240 \Msun\,yr$^{-1}$, and global gas-phase metallicity (\oh) from 8.2 to 8.6. At $1\sigma$ confidence level, 2/20 galaxies in our sample show positive (inverted) gradients -- the relative abundance of oxygen increasing with galactocentric radius, opposite the usual trend. Furthermore, 1/20 shows negative gradients and 17/20 are consistent with flat gradients. This high fraction of flat/inverted gradients is uncommon in simulations and previous observations conducted in blank fields at similar redshifts. To understand this, we investigate the correlations among various observed properties of our sample galaxies. We find an anticorrelation between metallicity gradient and global metallicity of our galaxies residing in extreme overdensities, and a marked deficiency of metallicity in our massive galaxies as compared to their coeval field counterparts. We conclude that the cold-mode gas accretion plays an active role in shaping the chemical evolution of galaxies in the protocluster environments, diluting their central chemical abundance, and flattening/inverting their metallicity gradients.Comment: 13 pages, 6 figures, 1 table. Accepted for publication in ApJ

Highly Sensitive Fluorescence Probe Based on Functional SBA-15 for Selective Detection of Hg2+

An inorganic–organic hybrid fluorescence chemosensor (DA/SBA-15) was prepared by covalent immobilization of a dansylamide derivative into the channels of mesoporous silica material SBA-15 via (3-aminopropyl)triethoxysilane (APTES) groups. The primary hexagonally ordered mesoporous structure of SBA-15 was preserved after the grafting procedure. Fluorescence characterization shows that the obtained inorganic–organic hybrid composite is highly selective and sensitive to Hg2+ detection, suggesting the possibility for real-time qualitative or quantitative detection of Hg2+ and the convenience for potential application in toxicology and environmental science

Integrated photon sources for quantum information science applications

Ring resonators are used as photon pair sources by taking advantage of the materials second or third order non-linearities through the processes of spontaneous parametric downconversion and spontaneous four wave mixing respectively. Two materials of interest for these applications are silicon for the infrared and aluminum nitride for the ultraviolet through the infrared. When fabricated into ring type sources they are capable of producing pairs of indistinguishable photons but typically suffer from an effective 50% loss. By slightly decoupling the input waveguide from the ring, the drop port coincidence ratio can be significantly increased with the trade-off being that the pump is less efficiently coupled into the ring. Ring resonators with this design have been demonstrated having coincidence ratios of 96% but requiring a factor of ∼10 increase in the pump power. Through the modification of the coupling design that relies on additional spectral dependence, it is possible to achieve similar coincidence ratios without the increased pumping requirement. This can be achieved by coupling the input waveguide to the ring multiple times, thus creating a Mach-Zehnder interferometer. This coupler design can be used on both sides of the ring resonator so that resonances supported by one of the couplers are suppressed by the other. This is the ideal configuration for a photon-pair source as it can only support the pump photons at the input side while only allowing the generated photons to leave through the output side. Recently, this device has been realized with preliminary results exhibiting the desired spectral dependence and with a coincidence ratio as high as ∼ 97% while allowing the pump to be nearly critically coupled to the ring. The demonstrated near unity coincidence ratio infers a near maximal heralding efficiency from the fabricated device. This device has the potential to greatly improve the scalability and performance of quantum computing and communication systems.National Science Foundation (U.S.) (Grant ECCS- 1542081)National Science Foundation (U.S.) (Award No. ECCS14052481