PZT Sensor Arrays for Integrated Damage Monitoring in Concrete Structures

The broad objective of the work reported here is to provide a fundamental basis for the use of Lead Zirconate Titanate (PZT) patches in damage detection of concrete structures. Damage initiation in concrete structures starts with distributed microcracks, which eventually localize to form cracks. By the time surface manifestation in the form of visible cracking appears there may be significant degradation of the capacity of the structure. Early detection of damage, before visible signs appear on the surface of the structure is essential to initiate early intervention, which can effectively increase the service life of structures. Development of monitoring methodologies involves understanding the underlying phenomena and providing a physical basis for interpreting the observed changes in the parameters which are sensed. PZT is a piezoelectric material, which has a coupled constitutive relationship. In the case of the PZT patches bonded to a concrete structure, any sensing strategy requires developing an understanding of the coupled electromechanical (EM) response of the PZT-concrete system. The challenges associated with the use of PZT patches for damage monitoring in a concrete substrate include providing the following: a clear understanding of the fundamental response of the PZT patch when bonded to a concrete substrate; interpretation of the coupled response of the PZT patch under load induced damage; and development of an efficient, continuous monitoring methodology to sense a large area of the concrete substrate. Due to a lack of a fundamental basis, the use of PZT patches in concrete structures often involves inferring the measured response using model-based procedures. The work outlined in this thesis addresses the key issue of developing the theoretical basis and providing an experimental validation for PZT-based damage monitoring methodology for concrete structures. A fundamental understanding of response of the PZT patch when bonded to concrete substrate is developed. The outcome of the work is an integrated local and distributed sensing methodology for concrete structures by combining the electromechanical impedance and stress wave propagation methods using an array of bonded PZT patches. The work presented in this thesis is focused on using PZT patches bonded to a concrete substrate. A fundamental understanding of the coupled electromechanical behaviour of a PZT patch under an applied electrical excitation in an electrical impedance (EI) measurement, is developed. The influence of the substrate size and its material properties on the frequency dependent EI response of a PZT patch is investigated using concrete substrates of different sizes. The dynamic response of a PZT patch is shown to consist of resonance modes of the PZT patch with superimposed structural response. The resonance behaviour of the PZT patch is shown to be influenced by the material properties of the substrate. The size dependence in the EI response of a PZT patch bonded to a concrete substrate is produced by the dynamic behaviour of the structure. The size of the local zone of the concrete material substrate in the vicinity of the bonded PZT patch, which influences the frequency dependent EI response of the PZT patch is identified. For each resonant mode, a local zone of influence, which is free from the influence of boundary is identified. The dynamic response of the PZT resonant mode is influenced by the elastic material properties and damping within the zone of influence. The structural effects of the concrete substrate produced by the finite size of the specimen are separated from the material effects produced by the material properties and the material damping in the coupled EM response of the bonded PZT patch. The influence of size of the concrete substrate on the coupled impedance response of the PZT is identified with peaks of structural resonance, which are superimposed on the resonant peaks of the bonded PZT patch The EI response of the PZT patch when bonded to concrete for detecting load-induced damage from distributed microcrack to localized cracks within the zone of influence of the PZT patch is investigated. Using an approach which combines an understanding of the coupled EM constitutive behaviour of PZT with experimental validation, a methodology is developed to decouple the effects of stress and damage in the substrate on the coupled EM response of a PZT patch. The features in the EI signature of a bonded PZT patch associated with stress and damage are identified. An increasing level of distributed damage in the concrete substrate produces a decrease in the magnitude and the frequency of the resonant peak of the bonded PZT patch. The substrate stress produces a counter acting effect in the EI spectrum of the bonded PZT patch. A measurement procedure for the use of bonded PZT patches for continuous monitoring of stress-induced damage in the form of distributed microcracks in a structure under loading is developed. An integrated methodology for damage monitoring in concrete structures is developed by combining the EI method for local sensing and the stress wave propagation-based method in a distributed sensing mode. An array of surface mounted PZT sensors are deployed on a concrete beam. The EI measurements from individual PZT sensors are used for detecting damage within the local zone of influence. PZT sensor pairs are used as actuators and sensors for distributed monitoring using stress wave propagation. A stress-induced crack is introduced in a controlled manner. It is detected very accurately from the full-field displacement measurement obtained using digital image correlation. The crack opening profile in concrete produced by the fracture is established from the surface displacement measurements. From the measurements of bonded PZTs, the localized crack is detected in the zone of influence by EI. The change in compliance of the material medium due to a localized crack is small and it is reflected in the smaller change in the measured EI when compared to distributed damage. Stress wave based measurements sensitively detect crack openings on the order of 10m. The material discontinuity produced by a closed crack, after removal of the stress is also detected. A damage matrix is developed for stress wave based method which is independent of transmission path to assess the severity of damage produced by the crack in a concrete structure

Evaluation of Crack Propagation and Post-cracking Hinge-type Behavior in the Flexural Response of Steel Fiber Reinforced Concrete

An experimental evaluation of crack propagation and post-cracking behavior in steel fiber reinforced concrete (SFRC) beams, using full-field displacements obtained from the digital image correlation technique is presented. Surface displacements and strains during the fracture test of notched SFRC beams with volume fractions (Vf) of steel fibers equal to 0.5 and 0.75% are analyzed. An analysis procedure for determining the crack opening width over the depth of the beam during crack propagation in the flexure test is presented. The crack opening width is established as a function of the crack tip opening displacement and the residual flexural strength of SFRC beams. The softening in the post-peak load response is associated with the rapid surface crack propagation for small increases in crack tip opening displacement. The load recovery in the flexural response of SFRC is associated with a hinge-type behavior in the beam. For the stress gradient produced by flexure, the hinge is established before load recovery is initiated. The resistance provided by the fibers to the opening of the hinge produces the load recovery in the flexural response

Silver Nanoparticle Aggregates as Highly Efficient Plasmonic Antennas for Fluorescence Enhancement

The enhanced local fields around plasmonic structures can lead to enhancement of the excitation and modification of the emission quantum yield of fluorophores. So far, high enhancement of fluorescence intensity from dye molecules was demonstrated using bow-tie gap antenna made by e-beam lithography. However, the high manufacturing cost and the fact that currently there are no effective ways to place fluorophores only at the gap prevent the use of these structures for enhancing fluorescence-based biochemical assays. We report on the simultaneous modification of fluorescence intensity and lifetime of dye-labeled DNA in the presence of aggregated silver nanoparticles. The nanoparticle aggregates act as efficient plasmonic antennas, leading to more than 2 orders of magnitude enhancement of the average fluorescence. This is comparable to the best-reported fluorescence enhancement for a single molecule but here applies to the average signal detected from all fluorophores in the system. This highlights the remarkable efficiency of this system for surface-enhanced fluorescence. Moreover, we show that the fluorescence intensity enhancement varies with the plasmon resonance position and measure a significant reduction (300×) of the fluorescence lifetime. Both observations are shown to be in agreement with the electromagnetic model of surface-enhanced fluorescence

Stress-Crack Separation Relationship for Macrosynthetic, Steel and Hybrid Fiber Reinforced Concrete

An experimental evaluation of the crack propaga tion and post-cracking response of macro fiber reinforced concrete in flexure is c onducted. Two types of structur al fibers, hooked end steel fibers and continuousl y embossed macro-synthetic fibers are used in this study. A fiber blend of the two fibers is evaluated for spec ific improvements in the post peak residual load carrying response. At 0.5% volume fraction, both steel and macrosynthetic fiber reinforced concrete exhibits load recovery at large crack opening. The blend of 0.2% macrosynthetic fibers and 0.3% steel fibers shows a significa nt improvement in the immediate post peak load response with a significantly smaller load drop and a constant residual load carrying capacity equal to 80% of the peak load. An analytical formulation to predict fle xure load-displacement behaviour considering a multi-linear stress- crack separation (σ -w) relationship is developed. An inverse analysis is developed for obtaining the multi- linear σ -w relation, from the experimental response. The � -w curves of the steel and macrosynthetic fiber reinforced concrete exhibit a stress recovery after a significant drop with increa sing crack opening. Significant residual load carrying capacity is attained only at large crack separation. The fiber blend exhibits a constant residual stress with increasing crack sepa ration following an initial decrease. The constant residual stress is attained at a small crack separation

Damage Assessment in Concrete Structures using PZT patches

Piezoelectric based PZT smart sensors offer significant potential for continuously monitoring the development and progression of internal damage in concrete structures. PZT-based damage sensors consisting of piezo-electric patches, which are bonded to the surface of a concrete structure can be developed for assessing the damage progression of concrete members. The primary challenge in developing a PZT-based sensor lies in developing a methodology to infer about the level of damage in the material from measurement. Changes in the resonant behavior in the measured electrical conductance obtained from electro-mechanical (EM) response of a PZT bonded to a concrete substrate is investigated for increasing levels of damage. The sensitivity of EM impedance- based measurements to level of damage in concrete is reported. Incipient damage in the form of microcracks in the concrete substrate produces a change in the electrical conductance signature associated with the resonant peaks. Changes in the conductance resonant signature from EM conductance measurement are detected before visible signs of cracking. The root mean square deviation of the conductance signature at resonant peaks is shown to accurately reflect the level of damage in the substrate. The findings presented here provide a basis for developing a sensing methodology using PZT patches for continuous monitoring of concrete structures

Lineage dynamics of murine pancreatic development at single-cell resolution.

Organogenesis requires the complex interactions of multiple cell lineages that coordinate their expansion, differentiation, and maturation over time. Here, we profile the cell types within the epithelial and mesenchymal compartments of the murine pancreas across developmental time using a combination of single-cell RNA sequencing, immunofluorescence, in situ hybridization, and genetic lineage tracing. We identify previously underappreciated cellular heterogeneity of the developing mesenchyme and reconstruct potential lineage relationships among the pancreatic mesothelium and mesenchymal cell types. Within the epithelium, we find a previously undescribed endocrine progenitor population, as well as an analogous population in both human fetal tissue and human embryonic stem cells differentiating toward a pancreatic beta cell fate. Further, we identify candidate transcriptional regulators along the differentiation trajectory of this population toward the alpha or beta cell lineages. This work establishes a roadmap of pancreatic development and demonstrates the broad utility of this approach for understanding lineage dynamics in developing organs