Ligand design for site-selective installation of Pd and Pt centers to generate homo- and heteropolymetallic motifs

The modular synthesis of a series of nitrogen-rich polydentate ligands that feature a common pincer-type framework is reported. These ligands allow for site-selective installation of palladium and platinum to give rise to bi- and trimetallic complexes that have d^(8)–d^(8) interactions

A VLBI polarization study of SiO masers towards VY CMa

Maser emission from the SiO molecule has been widely observed in the near-circumstellar envelopes of late-type, evolved stars. VLBI images can resolve individual SiO maser spots, providing information about the kinematics and magnetic field in the extended atmospheres of these stars. This poster presents full polarization images of several SiO maser lines towards the supergiant star VY CMa. VY CMa is a particularly strong SiO maser source and allows observations of a wide range of maser transitions. We discuss implications of these observations for VY CMa morphology, polarization, and pumping models.Comment: 3 pages, 1 figure: based on a poster paper at IAU Symposium 242: Astrophysical masers and their environments, held at Alice Springs (Australia), from March 12-16, 200

Tomography of a displacement photon counter for discrimination of single-rail optical qubits

We investigate the performance of a Kennedy receiver, which is known as a beneficial tool in optical coherent communications, to the quantum state discrimination of the two superpositions of vacuum and single photon states corresponding to the $\hat\sigma_x$ eigenstates in the single-rail encoding of photonic qubits. We experimentally characterize the Kennedy receiver in vacuum-single photon two-dimensional space using quantum detector tomography and evaluate the achievable discrimination error probability from the reconstructed measurement operators. We furthermore derive the minimum error rate obtainable with Gaussian transformations and homodyne detection. Our proof of principle experiment shows that the Kennedy receiver can achieve a discrimination error surpassing homodyne detection

Assessments of macroscopicity for quantum optical states

With the slow but constant progress in the coherent control of quantum systems, it is now possible to create large quantum superpositions. There has therefore been an increased interest in quantifying any claims of macroscopicity. We attempt here to motivate three criteria which we believe should enter in the assessment of macroscopic quantumness: The number of quantum fluctuation photons, the purity of the states, and the ease with which the branches making up the state can be distinguished

A terminal molybdenum carbide prepared by methylidyne deprotonation

The carbide anion [CMo{N(R)Ar}_3]– [R = C(CD_3)_2CH_3, Ar = C_6H_3Me_2-3,5], is obtained by deprotonation of the corresponding methylidyne compound, [HCMo{N(R)Ar}_3], and is characterized by X-ray diffraction as its {K(benzo-15-crown-5)_2}+ salt, thereby providing precedent for the carbon atom as a terminal substituent in transition-metal chemistry

Architecture and noise analysis of continuous variable quantum gates using two-dimensional cluster states

Due to its unique scalability potential, continuous variable quantum optics is a promising platform for large scale quantum computing and quantum simulation. In particular, very large cluster states with a two-dimensional topology that are suitable for universal quantum computing and quantum simulation can be readily generated in a deterministic manner, and routes towards fault-tolerance via bosonic quantum error-correction are known. In this article we propose a complete measurement-based quantum computing architecture for the implementation of a universal set of gates on the recently generated two-dimensional cluster states [1,2]. We analyze the performance of the various quantum gates that are executed in these cluster states as well as in other two-dimensional cluster states (the bilayer-square lattice and quad-rail lattice cluster states [3,4]) by estimating and minimizing the associated stochastic noise addition as well as the resulting gate error probability. We compare the four different states and find that, although they all allow for universal computation, the quad-rail lattice cluster state performs better than the other three states which all exhibit similar performance