Possible significance of cubic water-ice, H2O-Ic, in the atmospheric water cycle of Mars

The possible formation and potential significance of the cubic ice polymorph on Mars is discussed. When water-ice crystallizes on Earth, the ambient conditions of temperature and pressure result in the formation of the hexagonal ice polymorph; however, on Mars, the much lower termperature and pressures may permit the crystallization of the cubic polymorph. Cubic ice has two properties of possible importance on Mars: it is an excellant nucleator of other volatiles (such as CO2), and it undergoes an exothermic transition to hexagonal ice at temperatures above 170 K. These properties may have significant implications for both martian cloud formation and the development of the seasonal polar caps

Antarctic Meteorite Newsletter, volume 9, no. 2

Preliminary description and classifications of meteorites that were completed since publication of the February issue are contained. Most large (greater than 150 g) specimens (regardless of petrologic type) and all pebble sized (less than 150 g) specimens of special petrologic type are represented by separate descriptions. However, specimens of nonspecial petrologic type are listed only as single line entries. For convenience, new specimens are also recast by petrologic type. Each macroscopic description summarizes features that were visible to the eye at the time the meteorite was first examined. Classification is based on microscopic petrography and resonnaissance-level electron-probe microanalysis. The pairing list was updated

Mineralogical sinks for biogenic elements on Mars

The efficacy of biochemical reactions on Mars should depend not only on concentrations of the biogenic elements H, C, N, O, and S but also on the forms (compounds and water-souble ions) that are available to those elements. It is possible that mineralogical reactions could act to lock biogenic elements into relatively inaccessible inorganic forms or, alternatively, to shelter sensitive organic compounds from chemically hostile environments. Recognition of these competing pathways is essential in planning sampling mission and in situ experiments directed toward assessing the biological potential of Mars

Weathering of stony meteorites in Antarctica

Weathering produces undesirable physical, chemical, and isotopic changes that might disturb the records of cosmochemical evolution that are sought in meteorites. Meteorites are physically disintegrated by crack propagation phenomena, including ice riving and secondary mineral riving, and are probably abraded by wind that is laden with ice crystals or dust particles. Chemical weathering proceeds by oxidation, hydration, carbonation, and solution and produces a variety of secondary minerals and mineraloids. Differential weathering under freezing conditions is discussed, as well as, the mineralogy of weathering products. Furthermore, the use of Antarctic alteration of meteorites could be used as an excellent analog for weathering on Mars or on cometary bodies

Non-equilibrium freezing of water-ice in sandy basaltic regoliths and implications for fluidized debris flows on Mars

Many geomorphic features on Mars were attributed to Earth-analogous, cold-climate processes involving movement of water or ice lubricated debris. Clearly, knowledge of the behavior of water in regolith materials under Martian conditions is essential to understanding the postulated geomorphic processes. Experiments were performed with sand-sized samples of natural basaltic regoliths in order to further elucidate how water/regolith interactions depend upon grain size and mineralogy. The data reveal important contrasts with data for clay-mineral substrates and suggest that the microphysics of water/mineral interactions might affect Martian geomorphic processes in ways that are not fully appreciated. Sand and silt sized fractions of two soils from the summit of Mauna Kea were used as Mars-analogous regolith materials. Temperatures were measured for water/ice phase transitions as wet slurries of individual soil fractions which were cooled or heated at controlled rates under a carbon dioxide atmosphere. Freezing and melting of ice was studied as a function of water/soil mass ratio, soil particle size, and thermal-cycle rate. Comparison tests were done under the same conditions with U.S. Geological Survey standard rock powders

Water/rock interactions in experimentally simulated dirty snowball and dirty iceball cometary nuclei

In the dirty snowball model for cometary nuclei, comet-nucleus materials are regarded as mixtures of volatile ices and relatively non-volatile minerals or chemical compounds. Carbonaceous chondrite meteorites are regarded as useful analogs for the rocky component. To help elucidate the possible physical geochemistry of cometary nuclei, preliminary results are reported of calorimetric experiments with two-component systems involving carbonaceous chondrites and water ice. Based on collective knowledge of the physics of water ice, three general types of interactions can be expected between water and minerals at sub-freezing temperatures: (1) heterogeneous nucleation of ice by insoluble minerals; (2) adsorption of water vapor by hygroscopic phases; and (3) freezing- and melting-point depression of liquid water sustained by soluble minerals. The relative and absolute magnitude of all three effects are expected to vary with mineral composition

Pre-terrestrial origin of rust in the Nakhla meteorite

The authors present quantative elemental compositions and summarize textural evidence for the pre-terrestrial origin of rust on the Nakhla meteorite. The material in question is called 'rust' because its phase composition remains unknown. Compelling evidence for the pre-terrestrial origin of the rust is found in rust veins truncated by fusion crust and preserved as faults in sutured igneous crystals. Rust veins that approach the meteorite's fusion crust become discontinuous and exhibit vugs that suggest partial decrepitation; no veins that penetrate the fusion crust have been found. Because the rust probably contains volatile compounds, it is reasonable to expect that heating near the ablation surface (formed during atmospheric entry to Earth) would encourage devolatilization of the rust. Hence, the absence of rust veins in fusion crust and vugs in rust veins near fusion crust clearly imply that the rust existed in the meteorite before atmospheric entry

Carbonate and sulfate minerals in the Chassigny meteorite

SO2 and CO2 from pyrolysis and combustion of bulk Chassigny and infrared traces of sulfate and carbonate minerals have been previously reported. Using scanning electron microscopy (SEM) and energy-dispersive x ray spectrometry (EDS), portions of these samples are searched, and a Ca-sulfate/carbonate association is confirmed

Chemistry and mineralogy of Martian dust: An explorer's primer

A summary of chemical and mineralogical properties of Martian surface dust is offered for the benefit of engineers or mission planners who are designing hardware or strategies for Mars surface exploration. For technical details and specialized explanations, references should be made to literature cited. Four sources used for information about Martian dust composition: (1) Experiments performed on the Mars surface by the Viking Landers 1 and 2 and Earth-based lab experiments attempting to duplicate these results; (2) Infrared spectrophotometry remotely performed from Mars orbit, mostly by Mariner 9; (3) Visible and infrared spectrophotometry remotely performed from Earth; and (4) Lab studies of the shergottite nakhlite chassignite (SNC) clan of meteorites, for which compelling evidence suggests origin on Mars. Source 1 is limited to fine grained sediments at the surface whereas 2 and 3 contain mixed information about surface dust (and associated rock) and atmospheric dust. Source 4 has provided surprisingly detailed information but investigations are still incomplete

Martian weathering products as tracers of climate change and atmosphere/hydrosphere evolution on Mars

Primary objectives for exploration of Mars include determination of: (1) the distribution, abundance, and sources and sinks of volatile materials, and (2) the interaction of surface materials with the atmosphere. Both objectives fall within the purview of planetary surface weathering studies and require documented samples of weathered materials, including rock surfaces, soils, and sediments. Major issues to be addressed in selecting and studying Martian samples in this context are summarized