Spacelab 3 vapor crystal growth experiment

The Space Shuttle Challenger, with Spacelab 3 as its payload, was launched into orbit April 29, 1985. The mission, number 51-B, emphasized materials processing in space, although a wide variety of experiments in other disciplines were also carried onboard. One of the materials processing experiments on this flight is described, specifically the growth of single crystals of mercuric iodide by physical vapor transport

Variable Phase and Electrochemical Capacitance of Electrospun MnOx Fibers

• Supercapacitors are a next-generation energy storage technology with high power and energy densities. • Nanostructured electrodes maximize surface area and theoretical capacity; manganese oxides are low-cost, low-toxicity electrode materials. • Electrospinning and thermal treatments are used to prepare nanofiber-based electrodes. • Calcination conditions affect structure and composition of the ceramic fibers. • The effects of calcination pressure and time on fiber properties are studied herein

The New Zealand Strong Motion Earthquake Recorder Network

The network of strong-motion earthquake recorders, maintained throughout New Zealand by the Engineering Seismology Section of the Department of Scientific and Industrial Research, is described. The instruments are either deployed as ground instruments to measure potential earthquake attack on structures, or in structures, e.g. buildings, dams and industrial installations, to record structural response. Details are given of installation of instruments , maintenance, laboratory work, record retrieval and digitisation, costs and staffing for the network. Future developments mooted include an improved digitising system, the introduction of an improved version of the existing mechanical-optical instrument in 1979, and, in the long term, the introduction of an entirely new digital recorder, having an electrical output from its accelerometers, which will make possible the transmission of data by telephone or radio link

Theory of hopping conduction in arrays of doped semiconductor nanocrystals

The resistivity of a dense crystalline array of semiconductor nanocrystals (NCs) depends in a sensitive way on the level of doping as well as on the NC size and spacing. The choice of these parameters determines whether electron conduction through the array will be characterized by activated nearest-neighbor hopping or variable-range hopping (VRH). Thus far, no general theory exists to explain how these different behaviors arise at different doping levels and for different types of NCs. In this paper we examine a simple theoretical model of an array of doped semiconductor NCs that can explain the transition from activated transport to VRH. We show that in sufficiently small NCs, the fluctuations in donor number from one NC to another provide sufficient disorder to produce charging of some NCs, as electrons are driven to vacate higher shells of the quantum confinement energy spectrum. This confinement-driven charging produces a disordered Coulomb landscape throughout the array and leads to VRH at low temperature. We use a simple computer simulation to identify different regimes of conduction in the space of temperature, doping level, and NC diameter. We also discuss the implications of our results for large NCs with external impurity charges and for NCs that are gated electrochemically.Comment: 14 pages, 10 figures; extra schematic figures added; revised introductio

Can we predict the duration of an interglacial?

Differences in the duration of interglacials have long been apparent in palaeoclimate records of the Late and Middle Pleistocene. However, a systematic evaluation of such differences has been hampered by the lack of a metric that can be applied consistently through time and by difficulties in separating the local from the global component in various proxies. This, in turn, means that a theoretical framework with predictive power for interglacial duration has remained elusive. Here we propose that the interval between the terminal oscillation of the bipolar seesaw and three thousand years (kyr) before its first major reactivation provides an estimate that approximates the length of the sea-level highstand, a measure of interglacial duration. We apply this concept to interglacials of the last 800 kyr by using a recently-constructed record of interhemispheric variability. The onset of interglacials occurs within 2 kyr of the boreal summer insolation maximum/precession minimum and is consistent with the canonical view of Milankovitch forcing pacing the broad timing of interglacials. Glacial inception always takes place when obliquity is decreasing and never after the obliquity minimum. The phasing of precession and obliquity appears to influence the persistence of interglacial conditions over one or two insolation peaks, leading to shorter (~ 13 kyr) and longer (~ 28 kyr) interglacials. Glacial inception occurs approximately 10 kyr after peak interglacial conditions in temperature and CO2, representing a characteristic timescale of interglacial decline. Second-order differences in duration may be a function of stochasticity in the climate system, or small variations in background climate state and the magnitude of feedbacks and mechanisms contributing to glacial inception, and as such, difficult to predict. On the other hand, the broad duration of an interglacial may be determined by the phasing of astronomical parameters and the history of insolation, rather than the instantaneous forcing strength at inception

Making a case for telehealth: measuring the carbon cost of health-related travel

Background: Telehealth services are promoted to reduce the cost of travel for people living in rural areas. The previous Australian Government, through the national Digital Economy Strategy, invested heavily in telehealth service development, at the same time introducing a carbon pricing mechanism. In planning a range of new telehealth services to a rural community the authors sought to quantify the travel conducted by people from one rural area in Australia to access health care, and to calculate the associated carbon emissions.Methods: A population survey was conducted over a 1-week period of health-related travel events for the year 1 July 2011 to 30 June 2012 of all households on King Island, a community situated between the Australian mainland state of Victoria and the state of Tasmania. Validated emissions calculators were sourced from the Carbon Neutral website, including the vehicle and fuel use calculator and air travel carbon calculator, to calculate the total emissions associated with the fuel burned in tonnes of carbon dioxide equivalent (tCO2e).Results: Thirty nine percent of the population (625 participants) reported a total of 511 healthcare-related travel events. Participants travelled a total of 346 573 km and generated 0.22 tCO2e per capita. Participants paid the cost of their own travel more than 70% of the time.Conclusions: Dependence on fossil fuels for transport in a carbon economy has a significant impact on total healthcare carbon emissions. Alternative models of care, such as telehealth, need be developed for an environmentally sustainable healthcare system for rural and remote areas

Radiocarbon evidence for enhanced respired carbon storage in the Atlantic at the Last Glacial Maximum

The influence of ocean circulation changes on atmospheric CO2 hinges primarily on the ability to alter the ocean interior's respired nutrient inventory. Here we investigate the Atlantic overturning circulation at the Last Glacial Maximum and its impact on respired carbon storage using radiocarbon and stable carbon isotope data from the Brazil and Iberian Margins. The data demonstrate the existence of a shallow well-ventilated northern-sourced cell overlying a poorly ventilated, predominantly southern-sourced cell at the Last Glacial Maximum. We also find that organic carbon remineralisation rates in the deep Atlantic remained broadly similar to modern, but that ventilation ages in the southern-sourced overturning cell were significantly increased. Respired carbon storage in the deep Atlantic was therefore enhanced during the last glacial period, primarily due to an increase in the residence time of carbon in the deep ocean, rather than an increase in biological carbon export

Millennial-scale variability of deep-water temperature and δ18Odwindicating deep-water source variations in the Northeast Atlantic, 0-34 cal. ka BP

Paired measurements of Mg/Ca and δ18Occ (calcite δ18O) in benthic foraminifera from a deep-sea core recovered on the Iberian Margin (MD99-2334K; 37°48′N, 10°10′W; 3,146 m) have been performed in parallel with planktonic δ18Occ analyses and counts of ice-rafted debris (IRD). The synchrony of temperature changes recorded in the Greenland ice cores and in North Atlantic planktonic δ18Occ allows the proxy records from MD99-2334K to be placed confidently on the GISP2 time-scale. This correlation is further corroborated by AMS 14C-dates. Benthic Mg/Ca measurements in MD99-2334K permit the reconstruction of past deep-water temperature (Tdw) changes since ∼34 cal. ka BP (calendar kiloyears before present). Using these Tdw estimates and parallel benthic δ18Occ measurements, a record of deep-water δ18O (δ18Odw) has been calculated. Results indicate greatly reduced Tdw in the deep Northeast Atlantic during the last glaciation until ∼15 cal. ka BP, when Tdw warmed abruptly to near-modern values in parallel with the onset of the Bølling-Allerød interstadial. Subsequently, Tdw reverted to cold glacial values between ∼13.4 and ∼11.4 cal. ka BP, in parallel with the Younger Dryas cold reversal and the H0 ice-rafting event. Similar millennial-scale Tdw changes also occurred during the last glaciation. Indeed, throughout the last ∼34 cal. ka, millennial δ18Odw and Tdw changes have remained well coupled and are linked with IRD pulses coincident with Heinrich events 3, 2, 1, and the Younger Dryas, when transitions to lower Tdw and δ18Odw conditions occurred. In general, millennial Tdw and δ18Odw variations recorded in MD99-2334K describe an alternation between colder, low-δ18Odw and warmer, high δ18Odw conditions, which suggests the changing local dominance of northern-sourced North Atlantic Deep Water (NADW) versus southern-sourced Antarctic Bottom Water (AABW). The observed similarity of the Tdw and GISP2 δ18Oice records would therefore suggest a common component of variability resulting from the coupling of NADW formation and Greenland climate. A link between Greenland stadials and the incursion of cold, low-δ18Odw AABW in the deep Northeast Atlantic is thus implied, which contributes to the relationship between Greenland climate and the millennial benthic δ18Occ signal since ∼34 cal. ka BP