Methods for characterising microphysical processes in plasmas

Advanced spectral and statistical data analysis techniques have greatly contributed to shaping our understanding of microphysical processes in plasmas. We review some of the main techniques that allow for characterising fluctuation phenomena in geospace and in laboratory plasma observations. Special emphasis is given to the commonalities between different disciplines, which have witnessed the development of similar tools, often with differing terminologies. The review is phrased in terms of few important concepts: self-similarity, deviation from self-similarity (i.e. intermittency and coherent structures), wave-turbulence, and anomalous transport.Comment: Space Science Reviews (2013), in pres

Autographs on the Books as Evidence for Local Lore Resurches (Based on the Materials of the Rare Book Collection of the Verkhnyaya Tura Library n. a. F. F. Pavlenkov)

Дан обзор автографов гостей города Верхняя Тура на книгах, хранящихся в фонде редких книг библиотеки им. Ф. Ф. Павленкова. Воспроизводятся тексты дарственных записей известных людей, а также обстоятельства их приезда в Верхнюю Туру.The article contains a review of the autographs on the books belonging to the collection of rare books of the Verhnyaya Tura Library n. a. F.F. Pavlenkov, which were made by visitors of the town. There are reproduced texts of inscriptions made by famous people along with the circumstances of their visits

USE OF INTERNATIONALISMS MOTIVATED BY GREEK ROOT MORPHEME `НАЕМАТ` IN MEDICAL TERMINOLOGY (SECOND COMMUNICATION)

No abstrac

USE OF INTERNATIONALISMS MOTIVATED BY GREEK ROOT MORPHEME `НАЕМАТ` IN MEDICAL TERMINOLOGY (FIRST COMMUNICATION)

No abstrac

Coking-Resistant Sub-Nano Dehydrogenation Catalysts: PtnSnx/SiO2 (n=4, 7)

We present a combined experimental/theoretical study of Pt$_n$/SiO$_2$ and Pt$_n$Sn$_x$/SiO$_2$ (n = 4, 7) model catalysts for the endothermic dehydrogenation of hydrocarbons, using the ethylene intermediate as a model reactant. Supported pure Ptn clusters are found to be highly active toward dehydrogenation of C2D4, quickly deactivating due to a combination of carbon deposition and sintering, resulting in loss of accessible Pt sites. Addition of Sn to Ptn clusters results in the complete suppression of C2D4 dehydrogenation and carbon deposition, and also stabilizes the clusters against thermal sintering. Theory shows that both systems have thermal access to a multitude of cluster structures and adsorbate configurations that form a statistical ensemble. While Pt4/SiO2 clusters bind ethylene in both di-sigma and pi-bonded configurations, Pt$_4$Sn$_3$/SiO$_2$ binds C2H4 only in the pi-mode, with di-sigma bonding suppressed by a combination of electronic and geometric features of the PtSn clusters. Dehydrogenation reaction profiles on the accessible cluster isomers were calculated using the climbing image nudged elastic band (CI-NEB) method

Selective recovery of tropane alkaloids applying liquid membrane technique

A tropine recovery from its solutions applying a liquid membrane technique was studied. Among several studied organic solvents, chloroform showed best extraction ability towards atropine. Pertraction studies were carried out in a laboratory bulk liquid membrane contactor with agitation of all three phases. Both, aqueous solutions of pure atropine and extract of Atropa Belladonna L. roots were used as feed solutions, as well as chloroform and diluted sulphuric acid as a liquid membrane and a stripping liquor, respectively. The effect of phase agitation on alkaloid pertraction was studied for the cases when pure atropine solutions were used as feed phase. A pertraction process carried out with native liquid extracts from A. Belladonna provided selective alkaloid recovery and its concentration in the acceptor solutio

Sn-modification of Pt7/alumina model catalysts: Suppression of carbon deposition and enhanced thermal stability.

An atomic layer deposition process is used to modify size-selected Pt7/alumina model catalysts by Sn addition, both before and after Pt7 cluster deposition. Surface science methods are used to probe the effects of Sn-modification on the electronic properties, reactivity, and morphology of the clusters. Sn addition, either before or after cluster deposition, is found to strongly affect the binding properties of a model alkene, ethylene, changing the number and type of binding sites, and suppressing decomposition leading to carbon deposition and poisoning of the catalyst. Density functional theory on a model system, Pt4Sn3/alumina, shows that the Sn and Pt atoms are mixed, forming alloy clusters with substantial electron transfer from Sn to Pt. The presence of Sn also makes all the thermally accessible structures closed shell, such that ethylene binds only by π-bonding to a single Pt atom. The Sn-modified catalysts are quite stable in repeated ethylene temperature programmed reaction experiments, suggesting that the presence of Sn also reduces the tendency of the sub-nano-clusters to undergo thermal sintering

Optical absorption in boron clusters B6_{6} and B6+_{6}^{+} : A first principles configuration interaction approach

The linear optical absorption spectra in neutral boron cluster B$_{6}$ and cationic B$_{6}^{+}$ are calculated using a first principles correlated electron approach. The geometries of several low-lying isomers of these clusters were optimized at the coupled-cluster singles doubles (CCSD) level of theory. With these optimized ground-state geometries, excited states of different isomers were computed using the singles configuration-interaction (SCI) approach. The many body wavefunctions of various excited states have been analysed and the nature of optical excitation involved are found to be of collective, plasmonic type.Comment: 22 pages, 38 figures. An invited article submitted to European Physical Journal D. This work was presented in the International Symposium on Small Particles and Inorganic Clusters - XVI, held in Leuven, Belgiu

Three-dimensional local anisotropy of velocity fluctuations in the solar wind

We analyse velocity fluctuations in the solar wind at magneto-fluid scales in two datasets, extracted from Wind data in the period 2005-2015, that are characterised by strong or weak expansion. Expansion affects measurements of anisotropy because it breaks axisymmetry around the mean magnetic field. Indeed, the small-scale three-dimensional local anisotropy of magnetic fluctuations ({\delta}B) as measured by structure functions (SF_B) is consistent with tube-like structures for strong expansion. When passing to weak expansion, structures become ribbon-like because of the flattening of SFB along one of the two perpendicular directions. The power-law index that is consistent with a spectral slope -5/3 for strong expansion now becomes closer to -3/2. This index is also characteristic of velocity fluctuations in the solar wind. We study velocity fluctuations ({\delta}V) to understand if the anisotropy of their structure functions (SF_V ) also changes with the strength of expansion and if the difference with the magnetic spectral index is washed out once anisotropy is accounted for. We find that SF_V is generally flatter than SF_B. When expansion passes from strong to weak, a further flattening of the perpendicular SF_V occurs and the small-scale anisotropy switches from tube-like to ribbon-like structures. These two types of anisotropy, common to SF_V and SF_B, are associated to distinct large-scale variance anisotropies of {\delta}B in the strong- and weak-expansion datasets. We conclude that SF_V shows anisotropic three-dimensional scaling similar to SF_B, with however systematic flatter scalings, reflecting the difference between global spectral slopes.Comment: accepted in MNRA