5 research outputs found
Structural and electrical properties of ceramic Li-ion conductors based on LiAlTi(PO)-LiF
The work presents the investigations of Li1.3Al0.3Ti1.7(PO4)3-xLiF Li-ion
conducting ceramics with 0 < x < 0.3 by means of X-ray diffractometry (XRD),
7Li, 19F, 27Al and 31P Magic Angle Spinning Nuclear Magnetic Resonance (MAS
NMR) spectroscopy, thermogravimetry (TG), scanning electron microscopy (SEM),
impedance spectroscopy (IS) and density method. It has been shown that the
total ionic conductivity of both as-prepared and ceramic Li1.3Al0.3Ti1.7(PO4)3
is low due to a grain boundary phase exhibiting high electrical resistance.
This phase consists mainly of berlinite crystalline phase as well as some
amorphous phase containing Al3+ ions. The electrically resistant phases of the
grain boundary decompose during sintering with LiF additive. The processes
leading to microstructure changes and their effect on the ionic properties of
the materials are discussed in the frame of the brick layer model (BLM). The
highest total ionic conductivity at room temperature was measured for
LATP-0.1LiF ceramic sintered at 800{\deg}C and was equal to {\sigma}tot = 1.1 x
10-4 Scm-1
Impact of LiBSO glass additive on the structure and electrical properties of the LATP-based ceramics
The existing solid electrolytes for lithium ion batteries suffer from low
total ionic conductivity, which restricts its usefulness for the lithium-ion
battery technology. Among them, the NASICON-based materials, such as
Li1.3Al0.3Ti1.7(PO4)3 (LATP) exhibit low total ionic conductivity due to highly
resistant grain boundary phase. One of the possible approaches to efficiently
enhance their total ionic conductivity is the formation of a composite
material. Herein, the Li2.9B0.9S0.1O3.1 glass, called LBSO hereafter, was
chosen as an additive material to improve the ionic properties of the ceramic
Li1.3Al0.3Ti1.7(PO4)3 base material. The properties of this
Li1.3Al0.3Ti1.7(PO4)3-xLi2.9B0.9S0.1O3.1 (0 < x < 0.3) system have been studied
by means of high temperature X-ray diffractometry (HTXRD), 7Li, 11B, 27Al and
31P magic angle spinning nuclear magnetic resonance spectroscopy (MAS NMR),
thermogravimetry (TG), scanning electron microscopy (SEM), impedance
spectroscopy (IS) and density methods. We show here that the introduction of
the foreign LBSO phase enhances their electric properties. This study reveals
several interesting correlations between the apparent density, the
microstructure, the composition, the sintering temperature and the ionic
conductivity. Moreover, the electrical properties of the composites will be
discussed in the terms of the brick-layer model (BLM). The highest value of
{\sigma}tot = 1.5 x 10-4 Scm-1 has been obtained for LATP-0.1LBSO material
sintered at 800{\deg}C