Atmospheric bromoform at Cape Point, South Africa: an initial fixed-point data set on the African continent

Bromoform mixing ratios in marine air were measured at Cape Point Global Atmospheric Watch Station, South Africa. This represents the first such bromoform data set recorded at this location. Manual daily measurements were made during a month-long field campaign (austral spring 2011) using a gas chromatograph-electron capture detector (GC-ECD) with a custom-built front end thermal desorption trap. The measured concentrations ranged between 4.4 and 64.6 ( 22.2 %) ppt with a mean of 24.8 14.8 ppt. The highest mixing ratios recorded here occurred at, or shortly after, low tide. The diurnal cycle exhibited a morning and evening maximum with lower concentrations throughout the rest of the day. Initial analysis of the data presented indicates that the local kelp beds were the dominant source of the bromoform reported. A concentration-weighted trajectory analysis of the bromoform measurements suggests that two offshore source areas may exist. These source areas appear to be centred on the Agulhas retroflection and extend from St Helena Bay to the southwest

The effects of an integrated care intervention for the frail elderly on informal caregivers: A quasi-experimental study

__Abstract__ Background: This study explored the effects of an integrated care model aimed at the frail elderly on the perceived health, objective burden, subjective burden and quality of life of informal caregivers. Methods. A quasi-experimental design with before/after measurement (with questionnaires) and a control group was used. The analysis encompassed within and between groups analyses and regression analyses with baseline measurements, control variables (gender, age, co-residence with care receiver, income, education, having a life partner, employment and the duration of caregiving) and the intervention as independent variables. Results: The intervention significantly contributed to the reduction of subjective burden and significantly contributed to the increased likelihood that informal caregivers assumed household tasks. No effects were observed on perceived, health, time investment and quality of life. Conclusions: This study implies that integrated care models aimed at the frail elderly can benefit informal caregivers and that such interventions can be implemented without demanding additional time investments from informal caregivers. Recommendations for future interventions and research are provided. Trial registration. Current Controlled Trials. Registration date: 14/03/2013

Do integrated care structures foster processes of integration? A quasi-experimental study in frail elderly care from the professional perspective

Objective: This study explores the processes of integration that are assumed to underlie integrated care delivery. Design: A quasi-experimental design with a control group was used; a new instrument was developed to measure integration from the professional perspective. Setting and participants: Professionals from primary care practices and home-care organizations delivering care to the frail elderly in the Walcheren region of the Netherlands. Intervention: An integrated care intervention specifically targeting frail elderly patients was implemented. Main Outcome Measures: Structural, cultural, social and strategic integration and satisfaction with integration. Results: The intervention significantly improved structural, cultural and social integration, agreement on goals, interests, power and resources and satisfaction with integration. Conclusions: This study confirms that integrated care structures foster processes of integration among professionals. Trial registration: Current Controlled Trials ISRCTN05748494

Rapid decomposition of traditionally produced biochar in an Oxisol under savannah in Northeastern Brazil.

Soil amendment with biochar has been claimed as an option for carbon (C) sequestration in agricultural soils. Most studies on biochar/soil organic carbon (SOC) interactions were executed under laboratory conditions. Here we tested the stability of biochar produced in a traditional kiln and its effects on the stocks of native SOC under field conditions

A Zero-Gravity Instrument to Study Low Velocity Collisions of Fragile Particles at Low Temperatures

We discuss the design, operation, and performance of a vacuum setup constructed for use in zero (or reduced) gravity conditions to initiate collisions of fragile millimeter-sized particles at low velocity and temperature. Such particles are typically found in many astronomical settings and in regions of planet formation. The instrument has participated in four parabolic flight campaigns to date, operating for a total of 2.4 hours in reduced gravity conditions and successfully recording over 300 separate collisions of loosely packed dust aggregates and ice samples. The imparted particle velocities achieved range from 0.03-0.28 m s^-1 and a high-speed, high-resolution camera captures the events at 107 frames per second from two viewing angles separated by either 48.8 or 60.0 degrees. The particles can be stored inside the experiment vacuum chamber at temperatures of 80-300 K for several uninterrupted hours using a built-in thermal accumulation system. The copper structure allows cooling down to cryogenic temperatures before commencement of the experiments. Throughout the parabolic flight campaigns, add-ons and modifications have been made, illustrating the instrument flexibility in the study of small particle collisions.Comment: D. M. Salter, D. Hei{\ss}elmann, G. Chaparro, G. van der Wolk, P. Rei{\ss}aus, A. G. Borst, R. W. Dawson, E. de Kuyper, G. Drinkwater, K. Gebauer, M. Hutcheon, H. Linnartz, F. J. Molster, B. Stoll, P. C. van der Tuijn, H. J. Fraser, and J. Blu

Geochemical Processes and Controls Affecting Water Quality of the Karst Area of Big Creek near Mt. Judea, Arkansas

Karst regions typically are considered to be vulnerable with respect to various land-use activities, owing to the intimate association of surface and groundwater and lack of contaminant attenuation provided by most karst aquifers. Inasmuch as the soluble rocks of the karst landscape can be dissolved to create large, rapid-flow zones that compete successfully with surface streams, groundwater and subsurface flow represent a much larger component of the hydrologic budget in karst regions than in areas where non-soluble rocks predominate. Karst areas typically are distinguished by being unique, but some general approaches can be applied to characterize the hydrology of the area. These approaches include an evaluation of the degree of karstification, the hydrologic attributes of the groundwater flow system, the baseline water quality, the time-of-travel through the karst flow system, and the general flux moving through the system. The nature of potential contaminants and their total mass and range of concentrations are critical to understanding the potential environmental risk. This study describes the characterization of the baseline water quality of the shallow karst Boone aquifer and surface streams and springs to determine major processes and controls affecting water quality in the region, and to assess 2 years of waste spreading. Parameters evaluated include major constituents, contaminants and their breakdown products from the industrial operation of a concentrated animal-feeding operation (CAFO) on Big Creek, the indicator pathogen, E. coli, dissolved oxygen, selected trace metals, and other ancillary water-quality attributes that are directly observable in the environment. Determination of pre-CAFO water quality was accomplished by sampling approximately 40 sites that included wells, springs, and streams

Physical and biological processes at the Subtropical Convergence in the South-west Indian Ocean

A detailed hydrographic and biological survey was conducted in the region of the Subtropical Convergence in the Indian sector of the Southern Ocean in April 2007. Hydrographic data revealed that the subsurface expression of the Subtropical Convergence (at 200 m), marked by the 10°C isotherm, appeared to meander considerably between 41°S and 42°15’S. Total surface chlorophyll- a concentration was low and ranged from 0.03 to 0.42 µg l–1 and was always dominated by the pico- ( 0.05). The zooplankton community was dominated, numerically and by biomass, by mesozooplankton comprising mainly copepods of the genera, Oithona,Paraeuchaeta, Pleuromamma, Calanus and Clausocalanus. An exception was recorded at those stations in the region of the front where the tunicate, Salpa thompsoni, dominated the total zooplankton biomass

Physical and biological processes at the Subtropical Convergence in the South-west Indian Ocean

A detailed hydrographic and biological survey was conducted in the region of the Subtropical Convergence in the Indian sector of the Southern Ocean in April 2007. Hydrographic data revealed that the subsurface expression of the Subtropical Convergence (at 200 m), marked by the 10°C isotherm, appeared to meander considerably between 41°S and 42°15'S. Total surface chlorophyll-a concentration was low and ranged from 0.03 to 0.42 μg l-1 and was always dominated by the pico- ( 0.05). The Zooplankton community was dominated, numerically and by biomass, by mesozooplankton comprising mainly copepods of the genera, Oithona, Paraeuchaeta, Pleuromamma, Calanus and Clausocalanus. An exception was recorded at those stations in the region of the front where the tunicate, Salpa thompsoni, dominated the total Zooplankton biomass