566 research outputs found
The Yellow Excitonic Series of Cu2O Revisited by Lyman Spectroscopy
We report on the observation of the yellow exciton Lyman series up to the
fourth term in Cu2O by time-resolved mid-infrared spectroscopy. The dependence
of the oscillator strength on the principal quantum number n can be well
reproduced using the hydrogenic model including an AC dielectric constant, and
precise information on the electronic structure of the 1s exciton state can be
obtained. A Bohr radius a_{1s}=7.9 A and a 1s-2p transition dipole moment
\mu_{1s-2p}= 4.2 eA were found
Testing the validity of THz reflection spectra by dispersion relations
Complex response function obtained in reflection spectroscopy at terahertz
range is examined with algorithms based on dispersion relations for integer
powers of complex reflection coefficient, which emerge as a powerful and yet
uncommon tools in examining the consistency of the spectroscopic data. It is
shown that these algorithms can be used in particular for checking the success
of correction of the spectra by the methods of Vartiainen et al [1] and
Lucarini et al [2] to remove the negative misplacement error in the terahertz
time-domain spectroscopy.Comment: 17 pages, 4 figure
The Persistence and Memory of Polar Nano-Regions in a Ferroelectric Relaxor Under an Electric Field
The response of polar nanoregions (PNR) in the relaxor compound
Pb[(ZnNb)Ti]O subject to a [111]-oriented
electric field has been studied by neutron diffuse scattering. Contrary to
classical expectations, the diffuse scattering associated with the PNR
persists, and is even partially enhanced by field cooling. The effect of the
external electric field is retained by the PNR after the field is removed. The
``memory'' of the applied field reappears even after heating the system above
, and cooling in zero field
Polarization rotation via a monoclinic phase in the piezoelectric 92%PbZn1/3Nb2/3O3-8%PbTiO3
The origin of ultrahigh piezoelectricity in the relaxor ferroelectric
PbZn1/3Nb2/3O3-PbTiO3 was studied with an electric field applied along the
[001] direction. The zero-field rhombohedral R phase starts to follow the
direct polarization path to tetragonal symmetry via an intermediate monoclinic
M phase, but then jumps irreversibly to an alternate path involving a different
type of monoclinic distortion. Details of the structure and domain
configuration of this novel phase are described. This result suggests that
there is a nearby R-M phase boundary as found in the Pb(Ti,Zr)O3 system.Comment: REVTeX file. 4 pages. New version after referees' comment
Quasi-degenerate self-trapping in one-dimensional charge transfer exciton
The self-trapping by the nondiagonal particle-phonon interaction between two
quasi-degenerate energy levels of excitonic system, is studied. We propose this
is realized in charge transfer exciton, where the directions of the
polarization give the quasi-degeneracy. It is shown that this mechanism, unlike
the conventional diagonal one, allows a coexistence and resonance of the free
and self-trapped states even in one-dimensional systems and a quantitative
theory for the optical properties (light absorption and time-resolved
luminescence) of the resonating states is presented. This theory gives a
consistent resolution for the long-standing puzzles in quasi-one-dimensional
compound A-PMDA.Comment: accepted to Phys. Rev. Letter
Neutron Diffraction Study of Field Cooling Effects on Relaxor Ferroelectrics Pb[(Zn_{1/3} Nb_{2/3})_{0.92} Ti_{0.08}] O_{3}
High-temperature (T) and high-electric-field (E) effects on Pb[(Zn_{1/3}
Nb_{2/3})_{0.92} Ti_{0.08}]O_3 (PZN-8%PT) were studied comprehensively by
neutron diffraction in the ranges 300 <= T <= 550 K and 0 <= E <= 15 kV/cm. We
have focused on how phase transitions depend on preceding thermal and
electrical sequences. In the field cooling process (FC, E parallel [001] >= 0.5
kV/cm), a successive cubic (C) --> tetragonal (T) --> monoclinic (M_C)
transition was observed. In the zero field cooling process (ZFC), however, we
have found that the system does not transform to the rhombohedral (R) phase as
widely believed, but to a new, unidentified phase, which we call X. X gives a
Bragg peak profile similar to that expected for R, but the c-axis is always
slightly shorter than the a-axis. As for field effects on the X phase, we found
an irreversible X --> M_C transition via another monoclinic phase (M_A) as
expected from a previous report [Noheda et al. Phys. Rev. Lett. 86, 3891
(2001)]. At a higher electric field, we confirmed a c-axis jump associated with
the field-induced M_C --> T transition, which was observed by strain and x-ray
diffraction measurements.Comment: 8 pages, 9 figures, revise
Normal Modes and No Zero Mode Theorem of Scalar Fields in BTZ Black Hole Spacetime
Eigenfunctions for normal modes of scalar fields in BTZ black hole spacetime
are studied. Orthonormal relations among them are derived. Quantization for
scalar fields is done and particle number, energy and angular momentum are
expressed by the creation and annihilation operators. Allowed physical normal
mode region is studied on the basis of the no zero mode theorem. Its
implication to the statistical mechanics is also studied.Comment: 11 pages,v2 typos correcte
Symmetry of high-piezoelectric Pb-based complex perovskites at the morphotropic phase boundary I. Neutron diffraction study on Pb(Zn1/3Nb2/3)O3 -9%PbTiO3
The symmetry was examined using neutron diffraction method on
Pb(Zn1/3Nb2/3)O3 -9%PbTiO3 (PZN/9PT) which has a composition at the
morphotropic phase boundary (MPB) between Pb(Zn1/3Nb2/3)O3 and PbTiO3. The
results were compared with those of other specimens with same composition but
with different prehistory. The equilibrium state of all examined specimens is
not the mixture of rhombohedral and tetragonal phases of the end members but
exists in a new polarization rotation line Mc# (orthorhombic-monoclinic line).
Among examined specimens, one exhibited tetragonal symmetry at room temperature
but recovered monoclinic phase after a cooling and heating cycle
Detection and correction of the misplacement error in THz Spectroscopy by application of singly subtractive Kramers-Kronig relations
In THz reflection spectroscopy the complex permittivity of an opaque medium
is determined on the basis of the amplitude and of the phase of the reflected
wave. There is usually a problem of phase error due to misplacement of the
reference sample. Such experimental error brings inconsistency between phase
and amplitude invoked by the causality principle. We propose a rigorous method
to solve this relevant experimental problem by using an optimization method
based upon singly subtractive Kramers-Kronig relations. The applicability of
the method is demonstrated for measured data on an n-type undoped (100) InAs
wafer in the spectral range from 0.5 up to 2.5 THz.Comment: 16 pages, 5 figure
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