4,289 research outputs found

    Combined effects of a converging beam of light and mirror misalignment in Michelson interferometry

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    Expressions have been derived and calculations have been made which show that combined effects lead to asymmetric interferograms and reduction in power at zero path difference. Criteria are given for estimating maximum allowable mirror misalignment

    Pairing of 1-hexyl-3-methylimidazolium and tetrafluoroborate ions in n-pentanol

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    Molecular dynamics simulations are obtained and analyzed to study pairing of 1-hexyl-3-methylimidazolium and tetrafluoroborate ions in n-pentanol, in particular by evaluating the potential-of-mean-force between counter ions. The present molecular model and simulation accurately predicts the dissociation constant Kd in comparison to experiment, and thus the behavior and magnitudes for the ion-pair pmf at molecular distances, even though the dielectric constant of the simulated solvent differs from the experimental value by about 30%. A naive dielectric model does not capture molecule structural effects such as multiple conformations and binding geometries of the Hmim+ and BF4- ion-pairs. Mobilities identify multiple time-scale effects in the autocorrelation of the random forces on the ions, and specifically a slow, exponential time-decay of those long-ranged forces associated here with dielectric friction effects.Comment: 5 pages, 7 figures. V2: Figs. 4 & 7 redrawn for better visual clarity with log-scales. No change in results. In press J. Chem. Phys. 201

    Ionic profiles close to dielectric discontinuities: Specific ion-surface interactions

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    We study, by incorporating short-range ion-surface interactions, ionic profiles of electrolyte solutions close to a non-charged interface between two dielectric media. In order to account for important correlation effects close to the interface, the ionic profiles are calculated beyond mean-field theory, using the loop expansion of the free energy. We show how it is possible to overcome the well-known deficiency of the regular loop expansion close to the dielectric jump, and treat the non-linear boundary conditions within the framework of field theory. The ionic profiles are obtained analytically to one-loop order in the free energy, and their dependence on different ion-surface interactions is investigated. The Gibbs adsorption isotherm, as well as the ionic profiles are used to calculate the surface tension, in agreement with the reverse Hofmeister series. Consequently, from the experimentally-measured surface tension, one can extract a single adhesivity parameter, which can be used within our model to quantitatively predict hard to measure ionic profiles.Comment: 14 pages, 6 figure

    The GTC exoplanet transit spectroscopy survey. VI. A spectrally-resolved Rayleigh scattering slope in GJ 3470b

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    Aims. As a sub-Uranus-mass low-density planet, GJ 3470b has been found to show a flat featureless transmission spectrum in the infrared and a tentative Rayleigh scattering slope in the optical. We conducted an optical transmission spectroscopy project to assess the impacts of stellar activity and to determine whether or not GJ 3470b hosts a hydrogen-rich gas envelop. Methods. We observed three transits with the low-resolution OSIRIS spectrograph at the 10.4 m Gran Telescopio Canarias, and one transit with the high-resolution UVES spectrograph at the 8.2 m Very Large Telescope. Results. From the high-resolution data, we find that the difference of the Ca II H+K lines in- and out-of-transit is only 0.67 +/- 0.22%, and determine a magnetic filling factor of about 10-15%. From the low-resolution data, we present the first optical transmission spectrum in the 435-755 nm band, which shows a slope consistent with Rayleigh scattering. Conclusions. After exploring the potential impacts of stellar activity in our observations, we confirm that Rayleigh scattering in an extended hydrogen/helium atmosphere is currently the best explanation. Further high-precision observations that simultaneously cover optical and infrared bands are required to answer whether or not clouds and hazes exist at high-altitude.Comment: 12 pages, 11 figures, accepted for publication in A&

    Level Crossing Along Sphaleron Barriers

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    In the electroweak sector of the standard model topologically inequivalent vacua are separated by finite energy barriers, whose height is given by the sphale\-ron. For large values of the Higgs mass there exist several sphaleron solutions and the barriers are no longer symmetric. We construct paths of classical configurations from one vacuum to a neighbouring one and solve the fermion equations in the background field configurations along such paths, choosing the fermions of a doublet degenerate in mass. As in the case of light Higgs masses we observe the level crossing phenomenon also for large Higgs masses.Comment: 17 pages, latex, 10 figures in uuencoded postscript files. THU-94/0

    The Sphaleron Barrier in the Presence of Fermions

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    We calculate the minimal energy path over the sphaleron barrier in the pre\-sen\-ce of fermions, assuming that the fermions of a doublet are degenerate in mass. This allows for spherically symmetric ans\"atze for the fields, when the mixing angle dependence is neglected. While light fermions have little influence on the barrier, the presence of heavy fermions (MFM_F \sim TeV) strongly deforms the barrier, giving rise to additional sphalerons for very heavy fermions (MFM_F \sim 10 TeV). Heavy fermions form non-topological solitons in the vacuum sector.Comment: 19 pages, latex, 18 figures in 3 seperate uuencoded postscript files THU-93/1

    Nondegenerate Fermions in the Background of the Sphaleron Barrier

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    We consider level crossing in the background of the sphaleron barrier for nondegenerate fermions. The mass splitting within the fermion doublets allows only for an axially symmetric ansatz for the fermion fields. In the background of the sphaleron we solve the partial differential equations for the fermion functions. We find little angular dependence for our choice of ansatz. We therefore propose a good approximate ansatz with radial functions only. We generalize this approximate ansatz with radial functions only to fermions in the background of the sphaleron barrier and argue, that it is a good approximation there, too.Comment: LATEX, 20 pages, 11 figure

    Comparison between two methods of solution of coupled equations for low-energy scattering

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    Cross sections from low-energy neutron-nucleus scattering have been evaluated using a coupled channel theory of scattering. Both a coordinate-space and a momentum-space formalism of that coupled-channel theory are considered.A simple rotational model of the channel interaction potentials is used to find results using two relevant codes, ECIS97 and MCAS, so that they may be compared. The very same model is then used in the MCAS approach to quantify the changes that occur when allowance is made for effects of the Pauli principle.Comment: 6 pages, 3 figure

    Metal nanofilm in strong ultrafast optical fields

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    We predict that a metal nanofilm subjected to an ultrashort (single oscillation) optical pulse of a high field amplitude 3V/A˚\sim 3 \mathrm{V/\AA} at normal incidence undergoes an ultrafast (at subcycle times 1fs\lesssim 1 \mathrm{fs}) transition to a state resembling semimetal. Its reflectivity is greatly reduced, while the transmissivity and the optical field inside the metal are greatly increased. The temporal profiles of the optical fields are predicted to exhibit pronounced subcycle oscillations, which are attributed to the Bloch oscillations and formation of the Wannier-Stark ladder of electronic states. The reflected, transmitted, and inside-the-metal pulses have non-zero areas approaching half-cycle pulses. The effects predicted are promising for applications to nanoplasmonic modulators and field-effect transistors with petahertz bandwidth

    Structure factor and dynamics of the helix-coil transition

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    Thermodynamical properties of the helix-coil transition were successfully described in the past by the model of Lifson, Poland and Sheraga. Here we compute the corresponding structure factor and show that it possesses a universal scaling behavior near the transition point, even when the transition is of first order. Moreover, we introduce a dynamical version of this model, that we solve numerically. A Langevin equation is also proposed to describe the dynamics of the density of hydrogen bonds. Analytical solution of this equation shows dynamical scaling near the critical temperature and predicts a gelation phenomenon above the critical temperature. In the case when comparison of the two dynamical approaches is possible, the predictions of our phenomenological theory agree with the results of the Monte Carlo simulations.Comment: 11 pages, 7 figure
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