4,289 research outputs found
Combined effects of a converging beam of light and mirror misalignment in Michelson interferometry
Expressions have been derived and calculations have been made which show that combined effects lead to asymmetric interferograms and reduction in power at zero path difference. Criteria are given for estimating maximum allowable mirror misalignment
Pairing of 1-hexyl-3-methylimidazolium and tetrafluoroborate ions in n-pentanol
Molecular dynamics simulations are obtained and analyzed to study pairing of
1-hexyl-3-methylimidazolium and tetrafluoroborate ions in n-pentanol, in
particular by evaluating the potential-of-mean-force between counter ions. The
present molecular model and simulation accurately predicts the dissociation
constant Kd in comparison to experiment, and thus the behavior and magnitudes
for the ion-pair pmf at molecular distances, even though the dielectric
constant of the simulated solvent differs from the experimental value by about
30%. A naive dielectric model does not capture molecule structural effects such
as multiple conformations and binding geometries of the Hmim+ and BF4-
ion-pairs. Mobilities identify multiple time-scale effects in the
autocorrelation of the random forces on the ions, and specifically a slow,
exponential time-decay of those long-ranged forces associated here with
dielectric friction effects.Comment: 5 pages, 7 figures. V2: Figs. 4 & 7 redrawn for better visual clarity
with log-scales. No change in results. In press J. Chem. Phys. 201
Ionic profiles close to dielectric discontinuities: Specific ion-surface interactions
We study, by incorporating short-range ion-surface interactions, ionic
profiles of electrolyte solutions close to a non-charged interface between two
dielectric media. In order to account for important correlation effects close
to the interface, the ionic profiles are calculated beyond mean-field theory,
using the loop expansion of the free energy. We show how it is possible to
overcome the well-known deficiency of the regular loop expansion close to the
dielectric jump, and treat the non-linear boundary conditions within the
framework of field theory. The ionic profiles are obtained analytically to
one-loop order in the free energy, and their dependence on different
ion-surface interactions is investigated. The Gibbs adsorption isotherm, as
well as the ionic profiles are used to calculate the surface tension, in
agreement with the reverse Hofmeister series. Consequently, from the
experimentally-measured surface tension, one can extract a single adhesivity
parameter, which can be used within our model to quantitatively predict hard to
measure ionic profiles.Comment: 14 pages, 6 figure
The GTC exoplanet transit spectroscopy survey. VI. A spectrally-resolved Rayleigh scattering slope in GJ 3470b
Aims. As a sub-Uranus-mass low-density planet, GJ 3470b has been found to
show a flat featureless transmission spectrum in the infrared and a tentative
Rayleigh scattering slope in the optical. We conducted an optical transmission
spectroscopy project to assess the impacts of stellar activity and to determine
whether or not GJ 3470b hosts a hydrogen-rich gas envelop. Methods. We observed
three transits with the low-resolution OSIRIS spectrograph at the 10.4 m Gran
Telescopio Canarias, and one transit with the high-resolution UVES spectrograph
at the 8.2 m Very Large Telescope. Results. From the high-resolution data, we
find that the difference of the Ca II H+K lines in- and out-of-transit is only
0.67 +/- 0.22%, and determine a magnetic filling factor of about 10-15%. From
the low-resolution data, we present the first optical transmission spectrum in
the 435-755 nm band, which shows a slope consistent with Rayleigh scattering.
Conclusions. After exploring the potential impacts of stellar activity in our
observations, we confirm that Rayleigh scattering in an extended
hydrogen/helium atmosphere is currently the best explanation. Further
high-precision observations that simultaneously cover optical and infrared
bands are required to answer whether or not clouds and hazes exist at
high-altitude.Comment: 12 pages, 11 figures, accepted for publication in A&
Level Crossing Along Sphaleron Barriers
In the electroweak sector of the standard model topologically inequivalent
vacua are separated by finite energy barriers, whose height is given by the
sphale\-ron. For large values of the Higgs mass there exist several sphaleron
solutions and the barriers are no longer symmetric. We construct paths of
classical configurations from one vacuum to a neighbouring one and solve the
fermion equations in the background field configurations along such paths,
choosing the fermions of a doublet degenerate in mass. As in the case of light
Higgs masses we observe the level crossing phenomenon also for large Higgs
masses.Comment: 17 pages, latex, 10 figures in uuencoded postscript files. THU-94/0
The Sphaleron Barrier in the Presence of Fermions
We calculate the minimal energy path over the sphaleron barrier in the
pre\-sen\-ce of fermions, assuming that the fermions of a doublet are
degenerate in mass. This allows for spherically symmetric ans\"atze for the
fields, when the mixing angle dependence is neglected. While light fermions
have little influence on the barrier, the presence of heavy fermions ( TeV) strongly deforms the barrier, giving rise to additional sphalerons
for very heavy fermions ( 10 TeV). Heavy fermions form
non-topological solitons in the vacuum sector.Comment: 19 pages, latex, 18 figures in 3 seperate uuencoded postscript files
THU-93/1
Nondegenerate Fermions in the Background of the Sphaleron Barrier
We consider level crossing in the background of the sphaleron barrier for
nondegenerate fermions. The mass splitting within the fermion doublets allows
only for an axially symmetric ansatz for the fermion fields. In the background
of the sphaleron we solve the partial differential equations for the fermion
functions. We find little angular dependence for our choice of ansatz. We
therefore propose a good approximate ansatz with radial functions only. We
generalize this approximate ansatz with radial functions only to fermions in
the background of the sphaleron barrier and argue, that it is a good
approximation there, too.Comment: LATEX, 20 pages, 11 figure
Comparison between two methods of solution of coupled equations for low-energy scattering
Cross sections from low-energy neutron-nucleus scattering have been evaluated
using a coupled channel theory of scattering. Both a coordinate-space and a
momentum-space formalism of that coupled-channel theory are considered.A simple
rotational model of the channel interaction potentials is used to find results
using two relevant codes, ECIS97 and MCAS, so that they may be compared. The
very same model is then used in the MCAS approach to quantify the changes that
occur when allowance is made for effects of the Pauli principle.Comment: 6 pages, 3 figure
Metal nanofilm in strong ultrafast optical fields
We predict that a metal nanofilm subjected to an ultrashort (single
oscillation) optical pulse of a high field amplitude at
normal incidence undergoes an ultrafast (at subcycle times ) transition to a state resembling semimetal. Its reflectivity is
greatly reduced, while the transmissivity and the optical field inside the
metal are greatly increased. The temporal profiles of the optical fields are
predicted to exhibit pronounced subcycle oscillations, which are attributed to
the Bloch oscillations and formation of the Wannier-Stark ladder of electronic
states. The reflected, transmitted, and inside-the-metal pulses have non-zero
areas approaching half-cycle pulses. The effects predicted are promising for
applications to nanoplasmonic modulators and field-effect transistors with
petahertz bandwidth
Structure factor and dynamics of the helix-coil transition
Thermodynamical properties of the helix-coil transition were successfully
described in the past by the model of Lifson, Poland and Sheraga. Here we
compute the corresponding structure factor and show that it possesses a
universal scaling behavior near the transition point, even when the transition
is of first order. Moreover, we introduce a dynamical version of this model,
that we solve numerically. A Langevin equation is also proposed to describe the
dynamics of the density of hydrogen bonds. Analytical solution of this equation
shows dynamical scaling near the critical temperature and predicts a gelation
phenomenon above the critical temperature. In the case when comparison of the
two dynamical approaches is possible, the predictions of our phenomenological
theory agree with the results of the Monte Carlo simulations.Comment: 11 pages, 7 figure
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