77 research outputs found

    Janus Nanosheets Derived from K<sub>4</sub>Nb<sub>6</sub>O<sub>17</sub>·3H<sub>2</sub>O <em>via</em> Regioselective Interlayer Surface Modification

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    Inorganic Janus nanosheets were successfully prepared using the difference in reactivity between interlayers I and II of layered hexaniobate K4Nb6O17·3H2O. Janus nanosheets exhibit the highest anisotropy among Janus compounds due to their morphology. It is therefore important to prepare Janus nanosheets with stable shapes in various solvents, robust chemical bonds between nanosheets and fuctional groups and high versatility due to surface functional groups. K4Nb6O17·3H2O, which possesses two types of interlayers and two types of organophosphonic acids that react with metal oxides to form robust covalent bonds, was employed to prepare Janus nanosheets for this study. Interlayer I was modified by octadecylphosphonic acid, followed by modification by carboxypropylphosphonic acid mainly at interlayer II. Preparation of Janus nanosheets with two organophosphonate moieties was confirmed by 31P MAS NMR. After these regioselective and sequential modifications, the products were exfoliated into single-layered nanosheets in THF. Two types of derivatives with different repeating distances were recovered from a dispersion containing nanosheets exfoliated by different processes, centrifugation, and solvent evaporation. AFM analysis of the exfoliated nanosheets revealed that the products were Janus compounds. There are high expectations for application of these types of Janus nanosheets in various fields and for design of various Janus nanosheets using this preparation method

    Influence of a warning stimulus on a motor response under a backward masking paradigm.

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    In this study, we examined whether a warning stimulus affected a motor response to a visual stimuluswhich was not perceived with a backward masking by inferring from electromyogram reaction times(EMG-RT) and event-related potentials (ERPs). Onsets of lateralized readiness potentials (LRPs), P100latency, and P300 amplitude, which indicate perceptual information processing and cognitive informationprocessing, were observed. EMG-RTs and these ERPs components were affected by warning stimulus withor without the backward masking, suggesting that perceptual information processing for motor responsesto the visual stimulus without awareness may be also influenced by the warning stimulus. Moreover,the degree to which a warning stimulus affected duration of perceptual information processing may notdiffered between under the backward masking paradigm and under other stimulus presentations. Therefore,perceptual information processing for the production of motor responses under the backward maskingparadigm may be independent from much higher stages of cognitive information processing such as theattentional resources

    Progress and Research Needs of Plant Biomass Degradation by Basidiomycete Fungi

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    Comparative transcriptome analysis reveals different strategies for degradation of steam-exploded sugarcane bagasse by Aspergillus niger and Trichoderma reesei

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