Theoretical molecular line absorption of CO in late spectral type atmospheres

Theoretical molecular line absorption of carbon monoxide in late spectral type stellar atmosphere

Fourier spectroscopy and planetary research

The application of Fourier Transform Spectroscopy (FTS) to planetary research is reviewed. The survey includes FTS observations of the sun, all the planets except Uranus and Pluto, the Galilean satellites and Saturn's rings. Instrumentation and scientific results are considered and the prospects and limitations of FTS for planetary research in the forthcoming years are discussed

Estimation of sea surface temperature from remote sensing in the 11-13 micron window region

The Nimbus 3 and 4 IRIS spectral data in the 11-13 micron water vapor window region are analyzed to determine the sea surface temperature (SST). The high spectral resolution data of IRIS are averaged over approximately 1 micron wide intervals to simulate channels of a radiometer to measure the SST. Three channels are utilized to measure SST over cloud-free oceans. However, two of these channels are sufficient in routine SST determination. The differential absorption properties of water vapor in the two channels enable one to determine the water vapor absorption correction without detailed knowledge of the vertical profiles of temperature and water vapor. The feasibility of determining the SST is demonstrated globally with Nimbus 3 data where cloud-free areas can be selected with the help of albedo data from the MRIR experiment on board the same satellite

Upcoming planetary missions and the applicability of high temperature superconductor bolometers

Planetary missions to Mars and beyond can last 11 years and longer, making impractical the use of stored cryogens. Passive radiative coolers and single-stage mechanical coolers remain possibilities. CRAF and CASSINI, both using the newly developed Mariner Mark 2 spacecraft, will be the next outer planet missions after Galileo; they are intended to provide information on the origin and evolution of the solar system. CRAF is a cometary rendezvous mission slated for a 1994 launch. CASSINI has been chosen by ESA and will be launched by a Titan 4/Centaur in 1996. It will fly by Jupiter in 2000, inject an ESA-supplied probe into Titan in 2002, and take data in Saturn orbit from 2002 to 2006. NASA/Goddard is currently developing a prototype Fourier transform spectrometer (CIRS) that will be proposed for the CASSINI mission. The baseline infrared detectors for CIRS are HgCdTe to 16 microns and Schwarz-type thermopiles from 16 to 1000 microns. The far infrared focal plane could be switched from thermopiles to high temperature superconductor (HTS) bolometers between now and 1996. An HTS bolometer could be built using the kinetic inductance effect, or the sharp resistance change at the transition. The transition-edge bolometer is more straightforward to implement and initial efforts at NASA/Goddard are directed to that device. A working device was made and tested in early 1989. It also has somewhat elevated noise levels below 100 Hz. Upcoming efforts will center on reducing the time constant of the HTS bolometer by attempting to deposit an HTS film on a diamond substrate, and by thinning SrTiO3 substrates. Attempts will be made to improve the film quality to reduce th 1/f noise level, and to improve the thermal isolation to increase the bolometer sensitivity. An attempt is being made to deposit good-quality HTS films on diamond films using an MOCVD technique

High spectral resolution ground-based observations of Venus in the 450-1250 cm sup-1 region

The thermal emission of Venus was recorded during the winter of 1970-1971, and in 1973 using the 2.7m telescope at McDonald Observatory. The double beam Michelson interferometer installed at the Coude focus was used. The spectrum was recorded between 400/cm and 1,400/cm. For the 1970 observations, the spectral resolution was 0.25/cm and the linear spatial resolution was 3/4 of the disk of Venus. In 1973 the spectral resolution was 0.20/cm with a spatial resolution 1/3 of the planetary disk. In addition to Venus, the moon, the sky adjacent to each object, and the zenith sky were recorded to help eliminate the absorption and emission effects of the earth's atmosphere

Water vapor in Jupiter's atmosphere

High spectral resolution observations of Jupiter at 2.7 and 5 microns acquired from the Kuiper Airborne Observatory were used to infer the vertical distribution of H2O between 0.7 and 6 bars. The H2O mole fraction, qH2O, is saturated for P<2 bars, qH2O = 4x.000001 in the 2 to 4 bar range and it increases to 3x.00001 at 6 bars where T = 288 K. The base of the 5 micron line formation region is determined by pressure-induced H2 opacity. At this deepest accessible level, the O/H ratio in Jupiter is depleted by a factor of 50 with respect to the solar atmosphere. High spatial resolution Voyager IRIS spectra of Jupiter's North Tropical Zone, Equatorial Zone, and Hot Spots in the North and South Equatorial Belt were analyzed to determine the spatial variation of H2O across the planet. The column abundance of H2O above the 4 bar level is the same in the zones as in the SEB Hot Spots, about 20 cm-amgt. A cloud model for Jupiter's belts and zones was developed in order to fit the IRIS 5 micron spectra. An absorbing cloud located at 2 bars whose 5 micron optical thickness varies between 1 in the Hot Spots and 4 in the coldest zones satisfactorily matches the IRIS data

The Nimbus 4 Infrared Spectroscopy Experiment, IRIS-D. Part 1: Calibrated Thermal Emission Spectra

Calibrated infrared emission spectra of earth and atmosphere using high resolution interferometer spectrophotometer on Nimbus 4 satellit

Mars: Mariner 9 spectroscopic evidence for H2O ice clouds

Spectral features observed with the Mariner 9 Interferometer Spectrometer are identified as those of water ice. Measured spectra are compared with theoretical calulations for the transfer of radiation through clouds of ice particles with variations in size distribution and integrated cloud mass. Comparisons with an observed spectrum from the Tharsis Ridge region indicate water ice clouds composed of particles with mean radius 2.0 microns and integrated cloud mass 0.00005 g/sq cm

Synaptic MAGUK multimer formation is mediated by PDZ domains and promoted by ligand binding

To examine the scaffolding properties of PSD-95, we have taken advantage of established ligand/PDZ domain interactions and developed a cell-based assay for investigating protein complex formation. This assay enables quantitative analysis of PDZ domain-mediated protein clustering using bimolecular fluorescence complementation (BiFC). Two nonfluorescent halves of EYFP were fused to C-terminal PDZ ligand sequences to generate probes that sense for PDZ domain binding grooves of adjacent (interacting) molecules. When these probes are brought into proximity by the PDZ domains of a multiprotein scaffold, a functional fluorescent EYFP molecule can be detected. We have used this system to examine the properties of selected PSD-95 variants and thereby delineated regions of importance for PSD-95 complex formation. Further analysis led to the finding that PSD-95 multimerization is PDZ domain-mediated and promoted by ligand binding

Stratospheric sounding by infrared heterodyne spectroscopy

Intensity profiles of infrared spectral lines of stratospheric constituents can be fully resolved with a heterodyne spectrometer of sufficiently high resolution. The constituents' vertical distributions can then be evaluated accurately by analytic inversion of the measured line profiles. Estimates of the detection sensitivity of a heterodyne receiver are given in terms of minimum detectable volume mixing ratios of stratospheric constituents, indicating a large number of minor constituents which can be studied. Stratospheric spectral line shapes, and the resolution required to measure them are discussed in light of calculated synthetic line profiles for some stratospheric molecules in a model atmosphere. The inversion technique for evaluation of gas concentration profiles is briefly described and applications to synthetic lines of O3, CO2, CH4 and N2O are given