TRACE ELEMENT ANALYSIS OF GROUNDWATER FROM RASIPURAM TALUK, TAMILNADU, INDIA

Groundwater is an important source of water for many municipalities, industries and for irrigation, which needs careful and critical assessment of its quality. The groundwater samples collected from Rasipuram Taluk, Which is located in southern part of India, have been used for the trace element analysis. The main reason behind this analysis is based on the fact that, the industrial wastewater contributes to the groundwater pollution. The samples were analyzed for trace elements such as cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), manganese (Mn) and zinc (Zn) using Atomic Absorption Spectrometer (AAS) and other associated equipments. It was found that the concentrations of trace elements in groundwater of the study area are well within the prescribed limit

Secure Message Dissemination with QoS Guaranteed Routing in Internet of Vehicles

Internet of Vehicles (IoV) is a variant of vehicular adhoc network (VANET) where vehicles can communicate with other vehicles, infrastructure devices, parking lots and even pedestrians.  Communication to other entities is facilitates through various services like DSRC, C2C-CC. Fake messages can be propagated by attackers for various selfish needs. Complex authentication procedures can affect the propagation of emergency messages. Thus a light weight mechanism to ensure the trust of messages without affecting the delivery deadlines for emergency messages. Addressing this problem, this work proposes a clustering based network topology for IoV where routing is optimized for message dissemination of various classes using hybrid meta-heuristics.  In addition, two stage message authentication technique combining collaborative authentication with Bayesian filtering is proposed to verify the authenticity of message. Through simulation analysis, the proposed solution is found to detect fake messages with an accuracy of 96% with 10% lower processing delay compared to existing works

Multi-modal multi-class Parkinson disease classification using CNN and decision level fusion

Parkinson disease is the second most common neurodegenerative disorder, as reported by the World Health Organization. In this paper, we propose a direct three-Class PD classification using two different modalities, namely, MRI and DTI. The three classes used for classification are PD, Scans Without Evidence of Dopamine Deficit and Healthy Control. We use white matter and gray matter from the MRI and fractional anisotropy and mean diffusivity from the DTI to achieve our goal. We train four separate CNNs on the above four types of data. At the decision level, the outputs of the four CNN models are fused with an optimal weighted average fusion technique. We achieve an accuracy of 95.53 percentage for the direct three class classification of PD, HC and SWEDD on the publicly available PPMI database. Extensive comparisons including a series of ablation studies clearly demonstrate the effectiveness of our proposed solution.Comment: 10th International Conference on Pattern Recognition and Machine Intelligence (Acepted

Evaluation of Energy Consumption using Receiver–Centric MAC Protocol in Wireless Sensor Networks

At present day’s wireless sensor networks, obtain a lot consideration to researchers. Maximum number of sensor nodes are scattered that can communicate with all others. Reliable data communication and energy consumption are the mainly significant parameters that are required in wireless sensor networks. Many of MAC protocols have been planned to improve the efficiency more by enhancing the throughput and energy consumption. The majority of the presented medium access control protocols to only make available, reliable data delivery or energy efficiency does not offer together at the same time. In this research work the author proposes a novel approach based on Receiver Centric-MAC is implemented using NS2 simulator. Here, the author focuses on the following parametric measures like - energy consumption, reliability and bandwidth. RC-MAC provides high bandwidth without decreasing energy efficiency. The results show that 0.12% of less energy consumption, reliability improved by 20.86% and bandwidth increased by 27.32% of RC-MAC compared with MAC IEEE 802.11

Thermal properties of siliconized epoxy interpenetrating coatings

This work involves the development of a novel siliconized epoxy interpenetrating coating system using epoxy resin as base, hydroxyl-terminated polydimethylsiloxane (HTPDMS) as modifier, γ-aminopropyltriethoxysilane (γ-APS) as crosslinking agent and dibutyltindilaurate (DBTDL) as catalyst. Polyamidoamine and aromatic polyamine adduct were used as curing agents for the above coating systems. The thermal behaviour, glass transition temperature (Tg) and morphological characteristics of unmodified epoxy and siliconized epoxy coating systems cured by polyamidoamine (B) and aromatic polyamine adduct (D) were studied using thermogravimetric analysis, differential scanning calorimetry and scanning electron microscopy, respectively, and the results are discussed. From the study, it is observed that the thermal stability of epoxy coating systems is enhanced when siloxane is incorporated to them. There is a slight decrease in the glass transition temperature observed for silicone-modified epoxy coatings and SEM analyses reveal that siliconized epoxy coating systems show heterogeneous morphology

Report of Acoustic Test on PSLV IS.1/2L Structure

The results of acoustic conducted on PSLV IS.1/2L at Acoustic Test Facility are briefly given. It contains test set up, Instrumentation details and tables of spectral response

Development and characterization of silicone/phosphorus modified epoxy materials and their application as anticorrosion and antifouling coatings

Epoxy resin is chosen for our present study owing to its exceptional combination of properties such as easy processing, high safety, excellent solvent and chemical resistance, toughness, low shrinkage on cure, good electrical, mechanical and corrosion resistance with excellent adhesion to many substrates. This versatility in formulation made epoxy resins widely applied for surface coatings, adhesives, laminates, composites, potting, painting materials, encapsulant for semiconductor and insulating material for electric devices. There are numerous paint/coating systems based on epoxy resin available for corrosion and fouling prevention. They however are not completely satisfactory in field applications, where high corrosion, fouling and flame resistance are required. The demand for epoxy resin as corrosion/fouling resistant coatings is restricted mainly due to its inferior characteristics like poor impact strength, high rigidity, and moisture absorbing nature besides inadequate flame retardant properties. It is for this reason that silicones and phosphorus-based compounds are used as modifier in this work by intercrosslinking network mechanism (ICN) to obtain epoxy resin with desired properties ideally suitable for field applications for preventing corrosion and fouling with flame retardantancy. The present work involves the development of solvent free silicone/phosphorus modified epoxy coating systems, since solvent free coating systems are widely used for numerous applications due to their lower cost per unit film thickness, freedom from fire and pollution hazard and ability to provide better performance. For the development of coating systems, epoxy resin (X) serves as base material, hydroxyl terminated dimethylsiloxane (HTPDMS) as modifier, aminopropyltriethoxysilane (APS) as crosslinking agent and dibutyltindilaurate (DBTDL) as catalyst. Polyamidoamine (A), aromatic amine adducts (B) and phosphorus-containing diamine (C) were used as curing agents. The study also describes the evaluation of corrosion resistant behaviour of unmodified epoxy and siliconized epoxy coatings by potentiodynamic polarization method, electrochemical impedance spectroscopy (EIS), salt-spray and antifouling tests. The results are discussed.CSIR. National Metallurgical Laboratory. Madras Centre. Fundação para a Ciência e Tecnologia

Ternary Complexes of some Divalent Metal Ions with Potentially Tridentate Ligands in Dioxane-Water Mixtures

Chemical speciation of mixed ligand complexes of Ca(II), Mg(II) and Zn(II) with L-histidine and L-glutamic acid have been studied in varying concentrations (0.0–60.0 % v/v) of 1, 4-dioxane-water mixtures maintaining an ionic strength of 0.16 mol L–1 sodium chloride at 303.0 K. Titrations were carried out in the presence of different relative concentrations (M:L:X = 1.0:2.5:2.5, 1.0:2.5:5.0, 1.0:5.0:2.5) of metal (M) to L-histidine (L) to L-glutamic acid (X) with sodium hydroxide. Stability constants of ternary complexes were refined with MINIQUAD75. The best-fit chemical models were selected based on statistical parameters and residual analysis. The predominant species detected were ML2XH2, MLXH2 and MLX2 for Ca(II), Mg(II) and Zn(II). The formation and distribution of different species with relative concentrations of metal and ligands with varying pH are represented in the form of distribution diagrams. The influence of the solvent on the speciation is discussed in terms of the dielectric constant of the medium.Keywords: Speciation, mixed ligand complexes, L-histidine, L-glutamic acid, essential metals, dioxan

Enhancing the Thermal and Mechanical Properties of Organic-Inorganic Hybrid Nanocomposite Films Based on Poly Lactic Acid/OMMT Nano Clay

Abstract: Organic (PLA) inorganic (OMMT nano clay) hybrid nanocomposite films were fabricated using poly lactic acid (PLA) with various weight percentages (1-3wt%) of organically modified montmorillonite (OMMT) nano clay by means of one step solvent casting method. The thermal, mechanical and water absorption properties were determined as per standard testing methods to determine the optimum percentage of OMMT nano clay within the nanocomposite was investigated. The surface morphology of the organic-inorganic hybrid nanocomposite films was analyzed through XRD, SEM, and TEM surface analytical techniques. The incorporation of OMMT clay in to PLA matrix is found to have enhanced the thermo-mechanical properties. The water absorption and solubility test results also support the data from thermo-mechanical tests. The 2 wt % OMMT clay loaded PLA films showed the best results among all. The obtained results showed that the thermal, mechanical and water absorption properties could be increased significantly with the optimum incorporation of OMMT nano clay in a PLA matrix, in comparision wih the neat PLA

Speciation of Co(II), Ni(II) and Cu(II) Complexes with L-Glutamic Acid in Dioxan–Water Mixtures

Chemical speciation of Co(II), Ni(II) and Cu(II) complexes of L-glutamic acid in the presence of Dioxan-Water mixtures at an ionic strength of 0.16 mol L–1 at 303 K was studied pH–metrically. Glu is taken as a model compound for amino acid residues and dioxan is used to mimic the low dielectric constant at the active site cavities in bioactive molecules like enzymes and proteins. The active forms of the ligand were LH3+, LH2, LH– and L2–. The models containing different numbers of species were refined using the computer program, MINIQUAD75. The predominant species detected were ML2H2, ML2H–, ML22–, MLH+ and ML. The best fit chemical models were arrived at based on statistical parameters. The trend in variation of complex stability constants with the medium composition was explained on the basis of changes in the dielectric constant of the solution. Effect of errors in the ingredients on the stability constants was also studied. Chemical speciation is discussed based on the distribution diagrams.Keywords: Complex equilibria, chemical speciation, L-glutamic acid, essential metals, dioxa