Design overview of high pressure dense phase CO2 pipeline transport in flow mode

In open literature, there is little information available with regards to the engineering and technological issues for material corrosion, in relation to high pressure supercritical CO2 pipeline transport from single point sources, such as the power industry. A typical CO2 pipeline is designed to operate at high pressure in the dense phase. However, it is evident that although there is considerable experience of testing materials in lower pressure gaseous CO2 in the oil and gas industry, there is little understanding of the behaviour of pipeline materials when in contact with impure CO2 captured either from power plants or the oil and gas industry. In this particular project development, a dynamic dense phase CO2 corrosion rig has been built (conditions: ∼85 bar, 40 °C and up to 5 l/min flow rate) in flow mode, to understand the effect of impurities (SO2, O2, H2, NO2 & CO) present in captured CO2 on the pipeline transport materials. This unique facility in the UK was developed via the MATTRANS project funded by the E.ON-EPSRC strategic partnership (EP/G061955/1). The test rig includes different metallic materials (X grade steel: X60, X70 and X100) to assess the corrosion of pipelines, and different geometry components (tubes, plates, charpy and tensile coupons), to assess ageing and decompression behavior of polymeric seals (Neoprene, fluorocarbon, ethylene and Buna N) under water-saturated dense phase CO2 with different impurity concentrations (0.05 mol % SO2; 4 mol % O2; 2 mol % H2; 0.05 mol % NO2; 1 mol % CO). The dynamic data generated from this dense phase CO2 corrosion rig will give vital information with regards to pipeline suitability and lifetimes, when operating with dense CO2

Nonlinear Effects in Cavitation Cloud Dynamics

This paper presents a spectral analysis of the response of a fluid containing bubbles to the motions of a wall oscillating normal to itself. First, a fourier series analysis of the Rayleigh-Plesset equation is used to obtain an approximate solution for the nonlinear effects in the oscillations of a single bubble. This is used in the approximate solution of the oscillating wall problem and the resulting expressions are evaluated numerically in order to examine the nonlinear effects. The frequency content of the bubble radius and pressure oscillations near the wall is examined. Nonlinear effects are seen to increase with increased amplitude of wall oscillation, reduced void fraction and viscous and surface tension effects

Statistics of Noise Generated by Travelling Bubble Cavitation

This paper presents the details of the collapse process for single bubbles generated in travelling bubble cavitation around two axisymmetric headforms. The details of the bubble collapse process have been examined acoustically to understand the phenomena of rebounding and multipeaking. We find that both rebounding and multipeaking increased with reduction in the cavitation number for the ITTC headform. However with the Schiebe headform rebounding increases and multipeaking is decreased with reduction in the cavitation number. Some possible physical explanations for these phenomena are presented

Multiwavelength Observations of an Eruptive Flare: Evidence for Blast Waves and Break-out

Images of an east-limb flare on 3 November 2010 taken in the 131 \AA\ channel of the Atmospheric Imaging Assembly onboard the Solar Dynamics Observatory provide a convincing example of a long current sheet below an erupting plasmoid, as predicted by the standard magnetic reconnection model of eruptive flares. However, the 171 \AA\ and 193 \AA\ channel images hint at an alternative scenario. These images reveal that large-scale waves with velocity greater than 1000 km/s propagated alongside and ahead of the erupting plasmoid. Just south of the plasmoid, the waves coincided with type-II radio emission, and to the north, where the waves propagated along plume-like structures, there was increased decimetric emission. Initially the cavity around the hot plasmoid expanded. Later, when the erupting plasmoid reached the height of an overlying arcade system, the plasmoid structure changed, and the lower parts of the cavity collapsed inwards. Hot loops appeared alongside and below the erupting plasmoid. We consider a scenario in which the fast waves and the type-II emission were a consequence of a flare blast wave, and the cavity collapse and the hot loops resulted from the break-out of the flux rope through an overlying coronal arcade.Comment: Solar Physics (published), 15 pages, 8 figure

Giant Tunneling Magnetoresistance, Glassiness, and the Energy Landscape at Nanoscale Cluster Coexistence

We present microscopic results on the giant tunneling magnetoresistance that arises from the nanoscale coexistence of ferromagnetic metallic (FMM) and antiferromagnetic insulating (AFI) clusters in a disordered two dimensional electron system with competing double exchange and superexchange interactions. Our Monte Carlo study allows us to map out the different field regimes in magnetotransport and correlate it with the evolution of spatial structures. At coexistence, the isotropic O(3) model shows signs of slow relaxation, and has a high density of low energy metastable states, but no genuine glassiness. However, in the presence of weak magnetic anisotropy, and below a field dependent irreversibility temperature $T_{irr}$, the response on field cooling (FC) differs distinctly from that on zero field cooling (ZFC). We map out the phase diagram of this `phase coexistence glass', highlight how its response differs from that of a standard spin glass, and compare our results with data on the manganites.Comment: Final published versio

Can re-entrance be observed in force induced transitions?

A large conformational change in the reaction co-ordinate and the role of the solvent in the formation of base-pairing are combined to settle a long standing issue {\it i.e.} prediction of re-entrance in the force induced transition of DNA. A direct way to observe the re-entrance, i.e a strand goes to the closed state from the open state and again to the open state with temperature, appears difficult to be achieved in the laboratory. An experimental protocol (in direct way) in the constant force ensemble is being proposed for the first time that will enable the observation of the re-entrance behavior in the force-temperature plane. Our exact results for small oligonucleotide that forms a hairpin structure provide the evidence that re-entrance can be observed.Comment: 12 pages and 5 figures (RevTex4). Accepted in Europhys Lett. (2009