488 research outputs found

    Abundance and distribution of gaseous ammonia and particulate ammonium at Delhi, India

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    This study reports abundance and distribution of gaseous NH<sub>3</sub> and particulate NH<sub>4</sub><sup>+</sup> at Delhi. Gaseous NH<sub>3</sub> and particulate NH<sub>4</sub><sup>+</sup> concentrations were measured during pre-monsoon, monsoon and post-monsoon seasons of the years 2010 and 2011. Average concentrations of gaseous NH<sub>3</sub> during pre-monsoon, monsoon and post-monsoon seasons were recorded as 26.4, 33.2 and 32.5 ÎŒg m<sup>−3</sup>, respectively. Gaseous NH<sub>3</sub> concentrations were the highest during monsoon, thought to be due to decay and decomposition of plants and other biogenic material under wet conditions, leading to increased NH<sub>3</sub> emission. The results showed that particulate NH<sub>4</sub><sup>+</sup> was always lower than the gaseous NH<sub>3</sub> during all the seasons. The concentrations of particulate NH<sub>4</sub><sup>+</sup> were recorded as 11.6, 22.9 and 8.5 ÎŒg m<sup>−3</sup> during pre-monsoon, monsoon and post-monsoon seasons, respectively. The percent fraction of particulate NH<sub>4</sub><sup>+</sup> was noticed to be highest during the monsoon season, which is attributed to increased humidity levels favouring partitioning into the aerosol phase. On an average, 33.3% of total N-NH<sub>x</sub> was present as particulate NH<sub>4</sub><sup>+</sup>. Higher concentrations of NH<sub>3</sub> noticed during night time may be due to stable atmospheric conditions. The study highlighted that, as compared with rural sites, urban sites showed higher concentrations of gaseous NH<sub>3</sub> in India, which may be due to higher population density, human activities and poor sanitation arrangements

    Search Bias Quantification: Investigating Political Bias in Social Media and Web Search

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    Users frequently use search systems on the Web as well as online social media to learn about ongoing events and public opinion on personalities. Prior studies have shown that the top-ranked results returned by these search engines can shape user opinion about the topic (e.g., event or person) being searched. In case of polarizing topics like politics, where multiple competing perspectives exist, the political bias in the top search results can play a significant role in shaping public opinion towards (or away from) certain perspectives. Given the considerable impact that search bias can have on the user, we propose a generalizable search bias quantification framework that not only measures the political bias in ranked list output by the search system but also decouples the bias introduced by the different sources—input data and ranking system. We apply our framework to study the political bias in searches related to 2016 US Presidential primaries in Twitter social media search and find that both input data and ranking system matter in determining the final search output bias seen by the users. And finally, we use the framework to compare the relative bias for two popular search systems—Twitter social media search and Google web search—for queries related to politicians and political events. We end by discussing some potential solutions to signal the bias in the search results to make the users more aware of them.publishe

    Antiandrogen and Antimicrobial Aspects of Coordination Compounds of Palladium(II), Platinum(II) and Lead(II)

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    Synthesis, characterization and antimicrobial activities of an interesting class of biologically potent macrocyclic complexes have been carried out. All the complexes have been evaluated for their antimicrobial effects on different species of pathogenic fungi and bacteria. The testicular sperm density, testicular sperm morphology, sperm motility, density of cauda epididymal spermatozoa and fertility in mating trails and biochemical parameters of reproductive organs have been examined and discussed. The resulting biologically active [M(MaLn)(R2)]Cl2 and [Pb(MaLn)(R2)X2] (where, M = PdII or PtII and X = Cl or NO3) type of complexes have been synthesized by the reactions of macrocyclic ligands (MaLn) with metal salts and different diamines in 1:1:1 molar ratio in methanol. Initially the complexes were characterized by elemental analyses, molecular weight determinations and conductivity measurements. The mode of bonding was established on the basis of IR, 1H NMR, 13C NMR, 195Pt NMR, 207Pb NMR, XRD and electronic spectral studies. The macrocyclic ligand coordinates through the four azomethine nitrogen atoms which are bridged by benzil moieties. IR spectra suggest that the pyridine nitrogen is not coordinating. The palladium and platinum complexes exhibit tetracoordinated square-planar geometry, whereas a hexacoordinated octahedral geometry is suggested for lead complexes

    Regulatory Aspects of Pharmaceuticals’ Exports in Gulf Cooperation Council Countries

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    The Gulf cooperation council (GCC) region is considered as “Emerging market” for pharmaceutical export and bilateral trade. The understanding of the regulatory requirements of this region can be beneficial for pharmaceutical export. Some incidents of the year 2008-09, like recession or economic slowdown in highly well-off and regulated market of the EU and US, raised the demand for alternate destinations for business. The regulations of Gulf countries are encouraging the import of quality generic products, which can be good news to the Indian drug manufacturers

    Uric acid in men with acute stroke

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    Abstract Higher levels of uric acid in men as compared to women can be a reason behind greater incidence of stroke in men. The objective of the present study was to evaluate the levels of uric acid in men with acute stroke and correlate with stroke severity.For the purpose of the study ,50 male patients of acute stroke admitted to the hospital and 50 age matched healthy controls were included in the study. Routine biochemical parameters including fasting blood glucose, uric acid and lipid profile were assessed in serum obtained from 5 ml of fasting blood sample. Patients with kidney or liver diseases, malignancies, diuretic use, alcohol intake, on iron or antioxidant therapy were excluded from the study. Initial stroke severity was measured by the National Institute of Health Stroke (NIHS) scale. It was found that , among the 50 cases, 38(76%) had ischemic stroke and 12(24%) had hemorrhagic stroke. Serum uric acid levels were very significantly higher in cases (p<0.001) than controls. There was strong positive correlation between uric acid levels and initial stroke severity (p=0.006, r=0.386). Also, serum uric acid showed a statistically significant correlation with fasting blood glucose, TG and VLDL and an inverse association with HDL in both cases and controls. The conclusion drawn was that the significantly higher levels of uric acid in men with stroke and the positive association of uric acid with stroke severity suggest a possible role of uric acid as a risk factor for stroke in men
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