173 research outputs found
Electronic structure, magnetic and optical properties of intermetallic compounds R2Fe17 (R=Pr,Gd)
In this paper we report comprehensive experimental and theoretical
investigation of magnetic and electronic properties of the intermetallic
compounds Pr2Fe17 and Gd2Fe17. For the first time electronic structure of these
two systems was probed by optical measurements in the spectral range of 0.22-15
micrometers. On top of that charge carriers parameters (plasma frequency and
relaxation frequency) and optical conductivity s(w) were determined.
Self-consistent spin-resolved bandstructure calculations within the
conventional LSDA+U method were performed. Theoretical interpetation of the
experimental s(w) dispersions indicates transitions between 3d and 4p states of
Fe ions to be the biggest ones. Qualitatively the line shape of the theoretical
optical conductivity coincides well with our experimental data. Calculated by
LSDA+U method magnetic moments per formula unit are found to be in good
agreement with observed experimental values of saturation magnetization.Comment: 16 pages, 5 figures, 1 tabl
Competing anisotropy in the (TmxPr1-x)2Fe17 system
The magnetization curves of magnetically aligned finely powdered samples of the (TmxPr1-x)2Fe17 compounds have been measured at 4 K. The easy magnetization axis is oriented in the basal plane or along the hexagonal axis for the compounds with x = 0-0.3 and 0.7-1, respectively. This is because of the absence of magnetic ordering in the Tm and Pr subsystems in these ranges, respectively, and because of competing anisotropy of the subsystems. For the compositions with x = 0.4-0.6, both rare-earth subsystems are magnetically ordered and the easy magnetization axis is oriented between the basal plane and the hexagonal axis. The critical fields of FOMPs decrease quickly as the Pr or Tm content decreases in the ranges 0-0.3 and 0.7-1, respectively. The magnetization anisotropy also diminishes as the Tm content becomes smaller than x = 0.7. No influence of the intrinsic microdeformations on the magnetization of the compounds was detected. © 2018 The Authors, published by EDP Sciences
A crystallographic phase transition within the magnetically ordered state of Ce_2Fe_17
X-ray diffraction experiments were performed on polycrystalline and
single-crystal specimens of CeFe at temperatures between 10 K and
300 K. Below = 1182 K, additional weak superstructure
reflections were observed in the antiferromagnetically ordered state. The
superstructure can be described by a doubling of the chemical unit cell along
the direction in hexagonal notation with the same space group as the room-temperature structure. The additional antiferromagnetic
satellite reflections observed in earlier neutron diffraction experiments can
be conclusively related to the appearance of this superstructure.Comment: 8 pages, figures, submitted for publication in Phys. Rev.
Magnetic properties of the GdFeSi - GdTiSi solid solutions
The GdFe1-xTixSi, x=0-0.2 intermetallic compounds with a tetragonal crystal structure of the CeFeSi (P4/nmm)-type have been studied. It was obtained that the lattice parameter c and the Curie temperature increase quickly, whereas the lattice parameter a is almost unchanged in the system with increasing of Ti content. The GdFeSi compound is easily magnetized along the [001] axis, the field of magnetic anisotropy equals to ∼3.8 kOe at T = 90 K. The saturation magnetization does not change in the GdFe1-xTi x Si system. © Published under licence by IOP Publishing Ltd.Russian Science Foundation, RSF: 18-72-10098Support by RSF (Project No. 18-72-10098) is acknowledged
Unusual weak increase of Curie temperature and lattice parameters in Pr2Fe16.5Zr0.5
Crystal structure and magnetic and thermomagnetic properties of the Pr2Fe17-xMx compounds with M = Ti, V, Cr, Zr, Nb have been studied. The change of interatomic distances is not enough to explain the growth of the Curie point and it is necessary to assume the distribution of M = Ti, V, Cr, Nb atoms over the lattice positions, similar to that previously published for the Nd2Fe17-xMx compounds. It was established by neutron diffraction that Zr atoms substitute for Pr atoms in the 6c site and do not substitute for Fe atoms as might be expected from the original formula Pr2Fe16.5Zr0.5. So, the real composition of the substituted compound studied is Pr14.8(8)Zr0.52(8)Fe17. The magnetic moment of Fe atom and the magnetocaloric effect in the Pr2Fe17-xMx compounds decrease with decreasing Fe content. © Published under licence by IOP Publishing Ltd.Russian Foundation for Basic Research, RFBR: 18-02-00294The research was carried out within the state assignment of Minobrnauki of Russia (themes “Magnet” No. АААА-А18-118020290129-5, “Alloys” and “Flux” No. АААА-А18-118020190112-8) and supported in part by RFBR (project No. 18-02-00294)
The Total Synthesis of Convolutamydine a in the Conditions of the Catalysis by β-Aminoalcohols of Pinane and Carane Structure
This work was supported by the Russian Foundation of Basic Research (grant № 15-03-09352 A)
STRUCTURAL AND MAGNETIC PHASE TRANSITIONS IN THE GdFeAl1-XSiX SYSTEM
GdFeAl1-xSix crystallizes into the phases: hexagonal of the MgZn2 (P63/mmc) type (x=0-0.8), tetragonal of the CeFeSi (P4/nmm) type (x=0.3-1) and cubic of the MgCu2 (Fd3m) type (x=0-0.7). Curie point increases for the hexagonal and cubic and decreases for the te-tragonal phases, moment Fe vanishes.Работа выполнена при поддержке проекта РНФ № 18-72-10098
Transcatheter mitral valve edge-to-edge repair in patients with severe mitral regurgitation: data from the MitraClip Russia Trial
Aim. To study the immediate and short-term outcomes of transcatheter mitral valve edge-to-edge repair with the MitraClip NT in patients with severe mitral regurgitation as part of the MitraClip Russia prospective single-center study.Material and methods. The study included 16 patients (men, 10; women, 6) with mean age of 70,1±2,1 years (mean Euroscore II, 6,90±5,56%; STS, 6,33±3,94%). Immediate technical success was defined as successful access, delivery, and removal of the device, and adequate placing the clip(s) to reduce the mitral regurgitation to grade 2 or below without the need for device- or procedure-related reintervention.Results. Immediate technical success was achieved in all patients. The average number of implanted clips per 1 patient was 1,7. In 1 patient (6,3%), a clip was attached to one mitral leaflet, which required an non-scheduled implantation of a second clip. In hospital mortality was 6,3%: a 92-year-old patient on the 3rd day after the operation had a sudden cardiac arrest followed by coma, hemispheric ischemic stroke and death on the 6th day. An autopsy revealed an iatrogenic atrial septal defect. Echocardiography performed on the 10th and 30th day after surgery showed a decrease in mitral regurgitation grade in 15 patients, while grade 3 residual mitral regurgitation did not reveal in any patient.Conclusion. Transcatheter mitral valve edge-to-edge repair with the MitraClip is a minimally invasive method for treating severe symptomatic mitral regurgitation (degenerative and functional). The results demonstrate high immediate efficacy and an acceptable safety profile in high surgical risk patients. Based on the analysis of death causes, the authors conclude that it is necessary to include initial pulmonary hypertension above 75 mm Hg as a relative contraindication to this procedure. The study limitations are the small sample size and short follow-up period
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