Black Hole Chemistry

The mass of a black hole has traditionally been identified with its energy. We describe a new perspective on black hole thermodynamics, one that identifies the mass of a black hole with chemical enthalpy, and the cosmological constant as thermodynamic pressure. This leads to an understanding of black holes from the viewpoint of chemistry, in terms of concepts such as Van der Waals fluids, reentrant phase transitions, and triple points. Both charged and rotating black holes exhibit novel chemical-type phase behaviour, hitherto unseen.Comment: 12 pages, Essay written for the Gravity Research Foundation 2014 Awards for Essays on Gravitatio

Breakdown of the Equal Area Law for Holographic Entanglement Entropy

We investigate a holographic version of Maxwell's equal area law analogous to that for the phase transition in the black hole temperature/black hole entropy plane of a charged AdS black hole. We consider proposed area laws for both the black hole temperature/holographic entanglement entropy plane and the black hole temperature/2-point correlation function plane. Despite recent claims to the contrary, we demonstrate numerically that neither proposal is valid. We argue that there is no physical reason to expect such a construction in these planes.Comment: 17 pages, 8 figures. v2: Added appendix and discussio

Reentrant Phase Transitions in Rotating AdS Black Holes

We study the thermodynamics of higher-dimensional singly spinning asymptotically AdS black holes in the canonical (fixed J) ensemble of extended phase space, where the cosmological constant is treated as pressure and the corresponding conjugate quantity is interpreted as thermodynamic volume. Along with the usual small/large black hole phase transition, we find a new phenomenon of reentrant phase transitions for all d>5 dimensions, in which a monotonic variation of the temperature yields two phase transitions from large to small and back to large black holes. This situation is similar to that seen in multicomponent liquids.Comment: 5 pages, 6 figure