Nonstationary Synchronization of Equatorial QBO with SAO in Observations and a Model

It has often been suggested that the period of the quasi-biennial oscillation (QBO) has a tendency to synchronize with the semiannual oscillation (SAO). Apparently the synchronization is better the higher up the observation extends. Using 45 yr of the 40-yr European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERA-40) data of the equatorial stratosphere up to the stratopause, the authors confirm that this synchronization is not just a tendency but a robust phenomenon in the upper stratosphere. A QBO period starts when a westerly SAO (w-SAO) descends from the stratopause to 7 hPa and initiates the westerly phase of the QBO (w-QBO) below. It ends when another w-SAO, a few SAO periods later, descends again to 7 hPa to initiate the next w-QBO. The fact that it is the westerly but not the easterly SAO (e-SAO) that initiates the QBO is also explained by the general easterly bias of the angular momentum in the equatorial stratosphere so that the e-SAO does not create a zero-wind line, unlike the w-SAO. The currently observed average QBO period of 28 months, which is not an integer multiple of SAO periods, is a result of intermittent jumps of the QBO period from four SAO to five SAO periods. The same behavior is also found in the Two and a Half Dimensional Interactive Isentropic Research (THINAIR) model. It is found that the nonstationary behavior in both the observation and model is caused not by the 11-yr solar-cycle forcing but by the incompatibility of the QBO’s natural period (determined by its wave forcing) and the “quantized” period determined by the SAO. The wave forcing parameter for the QBO period in the current climate probably lies between four SAO and five SAO periods. If the wave forcing for the QBO is tuned so that its natural period is compatible with the SAO period above (e.g., at 24 or 30 months), nonstationary behavior disappears

Domain evolution of BaTiO3 ultrathin films under electric field: a first-principles study

A first-principles-derived method is used to study the morphology and electric-field-induced evolution of stripe nanodomains in (001) BaTiO3 (BTO) ultrathin films, and to compare them with those in (001) Pb(Zr,Ti)O3 (PZT) ultrathin films. The BaTiO3 systems exhibit 180o periodic stripe domains at null electric field, as in PZT ultrathin films. However, the stripes alternate along [1-10] in BTO systems versus [010] in PZT systems, and no in-plane surface dipoles occur in BTO ultrathin films (unlike in PZT materials). Moreover, the evolution of the 180o stripe domains in the BaTiO3 systems, when applying and increasing an electric field along [001], involves four regions: Region I for which the magnitude of the down dipoles (i.e., those that are antiparallel to the electric field) is reduced, while the domain walls do not move; Region II in which some local down dipoles adjacent to domain walls switch their direction, resulting in zigzagged domain walls - with the overall stripe periodicity being unchanged; Region III in which nanobubbles are created, then contract along [110] and finally collapse; and Region IV which is associated with a single monodomain. Such evolution differs from that of PZT ultrathin films for which neither Region I nor zigzagged domain walls exist, and for which the bubbles contract along [100]. Discussion about such differences is provided.Comment: 19 pages, 4 figures, 27 references, submitted to Phys. Rev.

A Student Led Investigation of the Landscape Dynamics of Campus Recycling

Two senior undergraduate students within the environmental science division at Stephen F. Austin State University (SFASU) quantitatively diagnosed the environmental, ecological, and socioeconomic dynamics involved in plastic recycling. This study incorporated actively collecting recycled plastic bottles on campus to produce an enumerated analysis of recycling on campus; and to gain an understanding of the socioeconomics of recycling via an anonymous survey used to determine the recycling knowledgebase of natural resource students at SFASU. Undergraduate students, via their incorporation into a campus wide environmental site assessment of recycling plastic bottles, were able to apply their classroom knowledge to a real-world environmental concern thus making them more well-rounded and society-ready environmental scientists

Characterization of Aura TES carbonyl sulfide retrievals over ocean

We present a description of the NASA Aura Tropospheric Emission Spectrometer (TES) carbonyl sulfide (OCS) retrieval algorithm for oceanic observations, along with evaluation of the biases and uncertainties using aircraft profiles from the HIPPO (HIAPER Pole-to-Pole Observations) campaign and data from the NOAA Mauna Loa site. In general, the OCS retrievals (1) have less than 1.0 degree of freedom for signals (DOFs), (2) are sensitive in the mid-troposphere with a peak sensitivity typically between 300 and 500 hPa, (3) but have much smaller systematic errors from temperature, CO₂ and H₂O calibrations relative to random errors from measurement noise. We estimate the monthly means from TES measurements averaged over multiple years so that random errors are reduced and useful information about OCS seasonal and latitudinal variability can be derived. With this averaging, TES OCS data are found to be consistent (within the calculated uncertainties) with NOAA ground observations and HIPPO aircraft measurements. TES OCS data also captures the seasonal and latitudinal variations observed by these in situ data

Project Report No. 67, A Whole-Stand Growth and Yield Model for Unmanaged Loblolly and Slash Pine Plantations in East Texas

The amount of forestland in east Texas has been estimated at 11.8 million acres, with approximately 2.5 million acres classified as pine plantations. The majority of these plantations are owned by forest industry (71 percent), while non-industrial private forest landowners represent the next largest shareholder (23 percent). Pine plantations are typically managed to produce timber, so information is needed to make informed management decisions. Growth is one piece of information that managers often rely upon in their decision-making process. The purpose of this paper is to develop an updated whole-stand growth and yield model for unmanaged loblolly and slash pine plantations in east Texas that improves upon the whole-stand model of Coble (2009). Specifically, this updated model includes a new equation to predict average stand diameter as well as an improved survival function

Integration of CITYgreen Landscape Ecological Analysis into a Capstone Environmental Science Course

CITYgreen Geographic Information Systems software was used to develop a campus wide cover type map for Stephen F. Austin State University in an environmental science landscape ecology course. The finding indicated an equal division of forest cover type compared to impervious surface of buildings and paved surface. Once the classification was completed, students chose an area for reforestation identified in CITYgreen, while raising funds for the purchase of trees for the project. Before completing the project, students reviewed tenets of landscape ecology, civic ecology education, and benefits of urban forestry. At the completion of the project, students reviewed service-learning aspects of campus beautification reflecting on making a difference, working outdoors, and using high end technology to complete a real-world environmental project incorporating partnerships and teamwork. The outcome demonstrates the benefits of applying ecological planning to complete an environmental project based on a perceived need within a campus setting

Pressure Line Broadening and Feasibility of CO_2 Profile Retrieval using Near Infrared Observations of an Absorption Line

Analytic expressions are derived for the transmittance and reflectance of sunlight and their Jacobians for an absorption line with Lorentz line broadening. Rodgers information analysis is applied to calculate the information content, the degrees of freedom and the averaging kernel for a simple atmospheric model to investigate the feasibility of retrieving the profile of CO_2 using near-infrared (NIR) measurements over a single absorption line. The results have implications for the design of future space instruments with high spectral resolution and high signal to noise ratios to obtain global scale information on the CO_2 vertical distribution which is important for inferring the sources, sinks, and transport of CO_2

Diversity Synthesis of Complex Pyridines Yields a Probe of a Neurotrophic Signaling Pathway

Recognizing the value of including complex pyridines in small-molecule screening collections, we developed a previously unexplored [2 + 2 + 2]-cycloaddition of silyl-tethered diynes with nitriles. The tether provides high regioselectivity, while the solvent THF allows catalytic CpCo(CO)2 to be used without exogenous irradiation. One of the resulting bicyclic and monocyclic (desilylated) pyridines was identified as an inhibitor of neuregulin-induced neurite outgrowth (EC50 = 0.30 µM) in a screen that probes a pathway likely to be involved in breast cancers and schizophrenia.Chemistry and Chemical Biolog