Thermal Raman study of Li4Ti5O12 and discussion about the number of its characteristic bands

Lithium battery industry is booming, and this fast growth should be supported by developing industry friendly tools to control the quality of positive and negative electrode materials. Raman spectroscopy was shown to be a cost effective and sensitive instrument to study defects and heterogeneities in lithium titanate, popular negative electrode material for high power applications, but there are still some points to be clarified. This work presents a detailed thermal Raman study for lithium titanate and discusses the difference of the number of predicted and experimentally observed Raman-active bands. The low temperature study and the analysis of thermal shifts of bands positions during heating let us to conclude about advantages of the proposed approach with surplus bands and recommend using shifts of major band to estimate the sample heating

Geological structure of the northern part of the Kara Shelf near the Severnaya Zemlya archipelago according to recent studies

Until recently, the North of the Kara Shelf was completely unexplored by seismic methods. Seismic and seismo-acoustic data that have appeared in recent years have made it possible to decipher features of the regional geological structure. This study solves the urgent problem of determining the prospects for the oil and gas potential of the North Kara sedimentary basin. The relevance of the research is associated with determining the prospects of the oil and gas potential of the North Kara sedimentary basin. The aim of the study is to clarify the age of the reflecting horizons using data on the geology of the island, as well as to determine the tectonic position of the sedimentary cover and basement structures in the north of the Kara shelf. The sedimentary cover is divided into three structural levels: Cambrian-Devonian, Middle Carboniferous-Cretaceous, Miocene-Quarter. The Cambrian-Devonian complex fills the deep troughs of the North Kara shelf. The most noticeable discontinuity is the base of Carboniferous-Permian rocks, lying on the eroded surface of folded Silurian-Devonian seismic complexes. The blanket-like plate part of the cover is composed of thin Carbon-Quarter complexes. The authors came to the conclusion that the fold structures of the Taimyr-Severozemelskiy fold belt gradually degenerate towards the Kara sedimentary basin and towards the continental slope of the Eurasian basin of the Arctic Ocean. A chain of narrow uplifts within the seabed relief, which correspond to narrow anticlines is traced to the West of the Severnaya Zemlya islands. Paleozoic rocks have subhorizontal bedding further to the West, within the Kara shelf. Mesozoic folding in the North of the Kara Sea is expressed exclusively in a weak activation of movements along faults. At the neotectonic stage, the shelf near Severnaya Zemlya was raised and the Mesozoic complexes were eroded. The modern seismic activity of the North Zemlya shelf is associated with the ongoing formation of the continental margin

Soliton Squeezing in a Mach-Zehnder Fiber Interferometer

A new scheme for generating amplitude squeezed light by means of soliton self-phase modulation is experimentally demonstrated. By injecting 180-fs pulses into an equivalent Mach-Zehnder fiber interferometer, a maximum noise reduction of $4.4 \pm 0.3$ dB is obtained ($6.3 \pm 0.6$ dB when corrected for losses). The dependence of noise reduction on the interferometer splitting ratio and fiber length is studied in detail.Comment: 5 pages, 4 figure

Model of vocational school, high school and manufacture integration in the regional system of professional education

The article is aimed at the model development of vocational, high school and manufacture integration in the regional system of vocational education. The basic approach to the structural-functional model development of vocational, high school and manufacture integration in the regional system of vocational education is an integrative one, taking into consideration the integrated system ?vocational school-high school-manufacture? components in their unity and cooperation, giving it the integrity and structural and functional stability. Structural-functional model of vocational, high school and manufacture integration in the regional system of vocational education includes functional-target, organizational-structural, content, process and result components

Ocean-bottom seismographs based on broadband MET sensors: architecture and deployment case study in the Arctic

The Arctic seas are now of particular interest due to their prospects in terms of hydrocarbon extraction, development of marine transport routes, etc. Thus, various geohazards, including those related to seismicity, require detailed studies, especially by instrumental methods. This paper is devoted to the ocean-bottom seismographs (OBS) based on broadband molecular–electronic transfer (MET) sensors and a deployment case study in the Laptev Sea. The purpose of the study is to introduce the architecture of several modifications of OBS and to demonstrate their applicability in solving different tasks in the framework of seismic hazard assessment for the Arctic seas. To do this, we used the first results of several pilot deployments of the OBS developed by Shirshov Institute of Oceanology of the Russian Academy of Sciences (IO RAS) and IP Ilyinskiy A.D. in the Laptev Sea that took place in 2018–2020. We highlighted various seismological applications of OBS based on broadband MET sensors CME-4311 (60 s) and CME-4111 (120 s), including the analysis of ambient seismic noise, registering the signals of large remote earthquakes and weak local microearthquakes, and the instrumental approach of the site response assessment. The main characteristics of the broadband MET sensors and OBS architectures turned out to be suitable for obtaining high-quality OBS records under the Arctic conditions to solve seismological problems. In addition, the obtained case study results showed the prospects in a broader context, such as the possible influence of the seismotectonic factor on the bottom-up thawing of subsea permafrost and massive methane release, probably from decaying hydrates and deep geological sources. The described OBS will be actively used in further Arctic expeditions

Хронические нарушения сознания: клинические рекомендации Общероссийской общественной организации «Федерация анестезиологов и реаниматологов»

Хронические нарушения сознания (ХНС) представляют собой синдромы тяжелого поражения центральной нервной системы, приводящие к длительной грубой инвалидизации и требующие значительных усилий по лечению и реабилитации, которые ложатся на медицинские учреждения и на плечи близких пациентов. ХНС развиваются у пациентов после комы и характеризуются наличием бодрствования при полном или практически полном отсутствии признаков осознанного поведения. К ХНС относятся вегетативное состояние (ВС) и состояние минимального сознания (СМС). Также для описания начальных стадий этих состояний используется термин «продленное нарушение сознания» (ПНС). Отдельно выделяют выход из СМС — состояние, которое формируется по мере восстановления когнитивных функций. Диагностика ХНС основывается на многократном структурированном клиническом осмотре с применением специализированных шкал при условии исключения обратимых причин нарушения сознания. Лечение пациентов с ХНС включает в себя поддержание жизненно важных функций, обеспечение оптимального питания и борьбу с типичными осложнениями и сопутствующими состояниями (пролежни, спастичность, боль, пароксизмальная симпатическая гиперактивность и др.). У пациентов с ХНС должна проводиться реабилитация с участием мультидисциплинарной реабилитационной команды в объеме, который определяется проблемами и возможностями конкретного пациента. Наиболее эффективной реабилитация является при условии ее раннего начала. На данный момент однозначных доказательств эффективности каких-либо специфических методов, направленных на восстановление сознания, не получено; изучается ряд соответствующих фармакологических и нефармакологических вмешательств, обязательным условием применения которых является максимально возможная коррекция соматических проблем пациента. Важную роль в ведении пациентов с ХНС играет вовлечение близких пациента, которые, в свою очередь, нуждаются в получении объективной практической информации о состоянии своего родственника и о направлениях реабилитации, а также в психологической помощи

Software for the frontiers of quantum chemistry:An overview of developments in the Q-Chem 5 package

This article summarizes technical advances contained in the fifth major release of the Q-Chem quantum chemistry program package, covering developments since 2015. A comprehensive library of exchange–correlation functionals, along with a suite of correlated many-body methods, continues to be a hallmark of the Q-Chem software. The many-body methods include novel variants of both coupled-cluster and configuration-interaction approaches along with methods based on the algebraic diagrammatic construction and variational reduced density-matrix methods. Methods highlighted in Q-Chem 5 include a suite of tools for modeling core-level spectroscopy, methods for describing metastable resonances, methods for computing vibronic spectra, the nuclear–electronic orbital method, and several different energy decomposition analysis techniques. High-performance capabilities including multithreaded parallelism and support for calculations on graphics processing units are described. Q-Chem boasts a community of well over 100 active academic developers, and the continuing evolution of the software is supported by an “open teamware” model and an increasingly modular design

Numerical Modeling of Nonlinear Response of Seafloor Porous Saturated Soil Deposits to SH-Wave Propagation

Numerical modeling of seismic response of soil deposits is usually conducted as part of seismic hazard assessment, preceding facility construction in any tectonically active regions, including offshore sites. A significant feature of subsea soils is their porous and water-saturated structure. Thus, the purpose of the present study is to introduce a procedure for modeling nonlinear behavior of porous, moist soils during SH-wave propagation, to verify it and compare response for synthetic soil profiles with porous medium parameters specific for low moisture onshore and high moisture offshore sites with cohesive and non-cohesive soils. The well-known and approved NERA code was used as a basis and improved to incorporate the Biot and Gassman equations for elastic waves propagation in a fluid-saturated porous solid. The applicability of the presented approach was substantiated for integration into other well-known algorithms. Obtained results showed good agreement between the simulated by different methods and observed spectra. The modeling also showed that the response of cohesive and non-cohesive soils with moisture specific both for onshore and offshore sites is explained by effects of resonances and effect of seismic amplitude saturation, which, in turn, depend on the corresponding value of the layer thickness and S-wave impedance for porous saturated soil layer. The proposed scheme could have significant practical usage for studying the effect of porous medium parameters on the seismic response of the moist soil deposits