Ising magnets with mobile defects

Motivated by recent experiments on cuprates with low-dimensional magnetic interactions, a new class of two-dimensional Ising models with short-range interactions and mobile defects is introduced and studied. The non-magnetic defects form lines, which, as temperature increases, first meander and then become unstable. Using Monte Carlo simulations and analytical low- and high-temperature considerations, the instability of the defect stripes is monitored for various microscopic and thermodynamic quantities in detail for a minimal model, assuming some of the couplings to be indefinitely strong. The robustness of the findings against weakening the interactions is discussed as well

Pigouvian tax aversion and inequity aversion in the lab

We use an experimental market with externalities to test whether inequality aversion could help explain the popularity of earmarking tax revenues. We find that voter opposition is not fully explained by material self-interest: Results indicate that preferences for fairness influence voting behavior, with greater inequality in tax revenue distribution negatively affecting the acceptability of the tax. In addition to this, we also discover a significant degree of tax-aversion in the votes. Our findings provide greater understanding of the behavioral underpinnings of the positive impact that earmarking has on the acceptability of Pigouvian taxes.Pigouvian taxes, public acceptability, earmarking, fairness, inequity aversion, laboratory experiments

Initial experiments concerning quantum information processing in rare-earth-ion doped crystals

In this paper initial experiments towards constructing simple quantum gates in a solid state material are presented. Instead of using specially tailored materials, the aim is to select a subset of randomly distributed ions in the material, which have the interaction necessary to control each other and therefore can be used to do quantum logic operations. The experimental results demonstrate that part of an inhomogeneously broadened absorption line can be selected as a qubit and that a subset of ions in the material can control the resonance frequency of other ions. This opens the way for the construction of quantum gates in rare-earth-ion doped crystals.Comment: 24 pages, including 12 figure

Nitrogen-rich transition metal nitrides

The solid state chemistry leading to the synthesis and characterization of metal nitrides with N:M ratios >1 is summarized. Studies of these compounds represent an emerging area of research. Most transition metal nitrides have much lower nitrogen contents, and they often form with non- or sub-stoichiometric compositions. These materials are typically metallic with often superconducting properties, and they provide highly refractory, high hardness materials with many technological applications. The higher metal nitrides should achieve formal oxidation states (OS) attaining those found among corresponding oxides, and they are expected to have useful semiconducting properties. Only a very few examples of such high OS nitrogen-rich compounds are known at present. The main group elements typically form covalently bonded nitride ceramics such as Si3N4, Ge3N4 and Sn3N4, and the early transition metals Zr and Hf produce Zr3N4 and Hf3N4. However, the only main example of a highly nitrided transition metal compound known to date is Ta3N5 that has a formal oxidation state +5 and is a semiconductor with visible light absorption leading to applications as a pigment and in photocatalysis. New synthesis routes are being explored to study the possible formation of other N-rich materials that are predicted to exist by ab initio calculations. There is a useful interplay between theoretical predictions and experimental synthesis studies at ambient and high pressure conditions, as we explore and establish the existence and structure–property relations of these new nitride compounds and polymorphs. Here we review the state of current investigations and indicate possible new directions for further work

The Logos of Maximus : History and Storytelling in Herodotus and Charles Olson

Charles Olson\u27s theory of history, istorin , harkens back to Herodotus. As Olson explains it, this term means to find out for yourself . Olson\u27s understanding of the concept is significantly informed by classicist J.A. K. Thompson. This paper examines Olson\u27s concept of istorin and storytelling techniques as employed in The Maximus Poems

Kinetic modeling of Secondary Organic Aerosol formation: effects of particle- and gas-phase reactions of semivolatile products

The distinguishing mechanism of formation of secondary organic aerosol (SOA) is the partitioning of semivolatile hydrocarbon oxidation products between the gas and aerosol phases. While SOA formation is typically described in terms of partitioning only, the rate of formation and ultimate yield of SOA can also depend on the kinetics of both gas- and aerosol-phase processes. We present a general equilibrium/kinetic model of SOA formation that provides a framework for evaluating the extent to which the controlling mechanisms of SOA formation can be inferred from laboratory chamber data. With this model we examine the effect on SOA formation of gas-phase oxidation of first-generation products to either more or less volatile species, of particle-phase reaction (both first- and second-order kinetics), of the rate of parent hydrocarbon oxidation, and of the extent of reaction of the parent hydrocarbon. The effect of pre-existing organic aerosol mass on SOA yield, an issue of direct relevance to the translation of laboratory data to atmospheric applications, is examined. The importance of direct chemical measurements of gas- and particle-phase species is underscored in identifying SOA formation mechanisms

Constitutional Law - Intergovernmental Tax Immunities - Erosion of Distinction Between Taxation of Property and of Privilege

Plaintiff Murray Corporation, a manufacturer of airplane parts for the federal government, was assessed a tax by the city of Detroit under the General Property Tax Act of Michigan, based in part on the value of materials. which the corporation had in its possession. Legal title to these materials was in the federal government. The corporation paid the taxes under protest and sued for a refund, contending that the taxes infringed the federal government\u27s immunity from state taxation to the extent the taxes were based on the value of government property. The district court entered judgment for Murray and the Court of Appeals for the Sixth Circuit affirmed. On appeal to the United States Supreme Court, held, reversed, four justices dissenting. Although on its face a tax on property, in essence the tax is on possession of property which plaintiff used in profit-making activities. Since it thus has the same effect as a privilege tax which has uniformly been upheld, the tax is valid. Detroit v. Murray Corporation of America, 355 U.S. 489 (1958), reh. den., Justice Frankfurter dissenting, 26 U.S. LAW WEEK 3357 (1958)

Genome wide expression profiling reveals suppression of host defence responses during colonisation by Neisseria meningitides but not N. lactamica.

Both Neisseria meningitidis and the closely related bacterium Neisseria lactamica colonise human nasopharyngeal mucosal surface, but only N. meningitidis invades the bloodstream to cause potentially life-threatening meningitis and septicaemia. We have hypothesised that the two neisserial species differentially modulate host respiratory epithelial cell gene expression reflecting their disease potential. Confluent monolayers of 16HBE14 human bronchial epithelial cells were exposed to live and/or dead N. meningitidis (including capsule and pili mutants) and N. lactamica, and their transcriptomes were compared using whole genome microarrays. Changes in expression of selected genes were subsequently validated using Q-RT-PCR and ELISAs. Live N. meningitidis and N. lactamica induced genes involved in host energy production processes suggesting that both bacterial species utilise host resources. N. meningitidis infection was associated with down-regulation of host defence genes. N. lactamica, relative to N. meningitidis, initiates up-regulation of proinflammatory genes. Bacterial secreted proteins alone induced some of the changes observed. The results suggest N. meningitidis and N. lactamica differentially regulate host respiratory epithelial cell gene expression through colonisation and/or protein secretion, and that this may contribute to subsequent clinical outcomes associated with these bacteria

Global modeling of secondary organic aerosol formation from aromatic hydrocarbons: high- vs low-yield pathways

Formation of SOA from the aromatic species toluene, xylene, and, for the first time, benzene, is added to a global chemical transport model. A simple mechanism is presented that accounts for competition between low and high-yield pathways of SOA formation, wherein secondary gas-phase products react further with either nitrogen oxide (NO) or hydroperoxy radical (HO2) to yield semi- or non-volatile products, respectively. Aromatic species yield more SOA when they react with OH in regions where the [NO]/[HO2] ratios are lower. The SOA yield thus depends upon the distribution of aromatic emissions, with biomass burning emissions being in areas with lower [NO]/[HO2] ratios, and the reactivity of the aromatic with respect to OH, as a lower initial reactivity allows transport away from industrial source regions, where [NO]/[HO2] ratios are higher, to more remote regions, where this ratio is lower and, hence, the ultimate yield of SOA is higher. As a result, benzene is estimated to be the most important aromatic species with regards to formation of SOA, with a total production nearly equal that of toluene and xylene combined. In total, while only 39% percent of the aromatic species react via the low-NOx pathway, 72% of the aromatic SOA is formed via this mechanism. Predicted SOA concentrations from aromatics in the Eastern United States and Eastern Europe are actually largest during the summer, when the [NO]/[HO2] ratio is lower. Global production of SOA from aromatic sources is estimated at 3.5 Tg/yr, resulting in a global burden of 0.08 Tg, twice as large as previous estimates. The contribution of these largely anthropogenic sources to global SOA is still small relative to biogenic sources, which are estimated to comprise 90% of the global SOA burden, about half of which comes from isoprene. Compared to recent observations, it would appear there are additional pathways beyond those accounted for here for production of anthropogenic SOA. However, owing to differences in spatial distributions of sources and seasons of peak production, there are still regions in which aromatic SOA produced via the mechanisms identified here are predicted to contribute substantially to, and even dominate, the local SOA concentrations, such as outflow regions from North America and South East Asia during the wintertime, though total SOA concentrations there are small (~0.1 μg/m^³)

The near-synchronous polar V1432 Aql (RX J1940.1-1025): Accretion geometry and synchronization time scale

The magnetic Cataclysmic Variable (mCV) V1432 Aql (RX 1940.1-1025) belongs to the four-member subclass of near-synchronous polars with a slight non-synchronism (<2 %) between the spin period of the white dwarf and the binary period. In these systems the accretion geometry changes periodically with phase of the beat cycle. We present the application of a dipole accretion model for near-synchronous systems developed by Geckeler & Staubert (1997a) to extended optical and X-ray data. We detect a significant secular change of the white dwarf spin period in V1432 Aql of dP_spin/dt = -5.4 (+3.7/-3.2) 10-9 s/s from the optical data set alone. This corresponds to a synchronization time scale tau_sync = 199 (+441/-75) yr, comparable to the time scale of 170 yr for V1500 Cyg. The synchronization time scale in V1432 Aql is in excellent agreement with the theoretical prediction from the dominating magnetic torque in near-synchronous systems. We also present period analyses of optical CCD photometry and RXTE X-ray data, which argue against the existence of a 4000 s period and an interpretation of V1432 Aql as an intermediate polar. The dipole accretion model also allows to constrain the relevant parameters of the accretion geometry in this system: the optical data allow an estimate of the dimensionless parameter (R_t0'/R_wd)1/2 sin(beta) = 3.6 (+2.7/-1.1), with a lower limit for the threading radius of R_t0' > 10 R_wd (68% confidence).Comment: 12 pages, 10 figures, 6 tables accepted by A&