Исследование процессов образования и разрушения водонефтяных эмульсий

В работе выполнен ряд экспериментальных исследований по приготовлению и отстаиванию искусственных водонефтяных эмульсий с использованием четырех типов деэмульгаторов. В результате работы выполнены исследования по влиянию физико-химических свойств нефти, начальной обводненности, интенсивности перемешивания при приготовлении водонефтяных эмульсий и влиянию деэмульгаторов на динамику и эффективность процесса отстаивания эмульсии при различных температурах.A number of experimental studies have been performed in the work on preparing and defending artificial water-oil emulsions using four types of demulsifiers. As a result of the work, studies were carried out on the effect of the physico-chemical properties of oil, the initial water cut, the intensity of mixing in the preparation of water-oil emulsions, and the effect of demulsifiers on the dynamics and efficiency of the emulsion settling process at various temperatures

Advanced Gas Turbine Cooling for the Carbon-Neutral Era

In the coming carbon-neutral era, industrial gas turbines (GT) will continue to play an important role as energy conversion equipment with high thermal efficiency and as stabilizers of the electric power grid. Because of the transition to a clean fuel, such as hydrogen or ammonia, the main modifications will lie with the combustor. It can be expected that small and medium-sized gas turbines will burn fewer inferior fuels, and the scope of cogeneration activities they are used for will be expanded. Industrial gas turbine cycles including CCGT appropriate for the carbon-neutral era are surveyed from the viewpoint of thermodynamics. The use of clean fuels and carbon capture and storage (CCS) will inevitably increase the unit cost of power generation. Therefore, the first objective is to present thermodynamic cycles that fulfil these requirements, as well as their verification tests. One conclusion is that it is necessary to realize the oxy-fuel cycle as a method to utilize carbon-heavy fuels and biomass and not generate NOx from hydrogen combustion at high temperatures. The second objective of the authors is to show the required morphology of the cooling structures in airfoils, which enable industrial gas turbines with a higher efficiency. In order to achieve this, a survey of the historical development of the existing cooling methods is presented first. CastCool® and wafer and diffusion bonding blades are discussed as turbine cooling technologies applicable to future GTs. Based on these, new designs already under development are shown. Most of the impetus comes from the development of aviation airfoils, which can be more readily applied to industrial gas turbines because the operation will become more similar. Double-wall cooling (DWC) blades can be considered for these future industrial gas turbines. It will be possible in the near future to fabricate the DWC structures desired by turbine cooling designers using additive manufacturing (AM). Another conclusion is that additively manufactured DWC is the best cooling technique for these future gas turbines. However, at present, research in this field and the data generated are scattered, and it is not yet possible for heat transfer designers to fabricate cooling structures with the desired accuracy