Analysis of the Reaction Rate Coefficients for Slow Bimolecular Chemical Reactions

Simple bimolecular reactions $A_1+A_2\rightleftharpoons A_3+A_4$ are analyzed within the framework of the Boltzmann equation in the initial stage of a chemical reaction with the system far from chemical equilibrium. The Chapman-Enskog methodology is applied to determine the coefficients of the expansion of the distribution functions in terms of Sonine polynomials for peculiar molecular velocities. The results are applied to the reaction $H_2+Cl\rightleftharpoons HCl+H$, and the influence of the non-Maxwellian distribution and of the activation-energy dependent reactive cross sections upon the forward and reverse reaction rate coefficients are discussed.Comment: 11 pages, 5 figures, to appear in vol.42 of the Brazilian Journal of Physic

Strong Attraction between Charged Spheres due to Metastable Ionized States

We report a mechanism which can lead to long range attractions between like-charged spherical macroions, stemming from the existence of metastable ionized states. We show that the ground state of a single highly charged colloid plus a few excess counterions is overcharged. For the case of two highly charged macroions in their neutralizing divalent counterion solution we demonstrate that, in the regime of strong Coulomb coupling, the counterion clouds are very likely to be unevenly distributed, leading to one overcharged and one undercharged macroion. This long-living metastable configuration in turn leads to a long range Coulomb attraction.Comment: REVTEX-published versio

Field theory of self-avoiding walks in random media

Based on the analogy with the quantum mechanics of a particle propagating in a {\em complex} potential, we develop a field-theoretical description of the statistical properties of a self-avoiding polymer chain in a random environment. We show that the account of the non-Hermiticity of the quantum Hamiltonian results in a qualitatively different structure of the effective action, compared to previous studies. Applying the renormalisation group analysis, we find a transition between the weak-disorder regime, where the quenched randomness is irrelevant, and the strong-disorder regime, where the polymer chain collapses. However, the fact that the renormalised interaction constants and the chiral symmetry breaking regularisation parameter flow towards strong coupling raises questions about the applicability of the perturbative analysis.Comment: RevTeX, 9 pages; accepted for publication in J. Phys.

Irreversible Processes in Inflationary Cosmological Models

By using the thermodynamic theory of irreversible processes and Einstein general relativity, a cosmological model is proposed where the early universe is considered as a mixture of a scalar field with a matter field. The scalar field refers to the inflaton while the matter field to the classical particles. The irreversibility is related to a particle production process at the expense of the gravitational energy and of the inflaton energy. The particle production process is represented by a non-equilibrium pressure in the energy-momentum tensor. The non-equilibrium pressure is proportional to the Hubble parameter and its proportionality factor is identified with the coefficient of bulk viscosity. The dynamic equations of the inflaton and the Einstein field equations determine the time evolution of the cosmic scale factor, the Hubble parameter, the acceleration and of the energy densities of the inflaton and matter. Among other results it is shown that in some regimes the acceleration is positive which simulates an inflation. Moreover, the acceleration decreases and tends to zero in the instant of time where the energy density of matter attains its maximum value.Comment: 13 pages, 2 figures, to appear in PR

Interacting Growth Walk - a model for hyperquenched homopolymer glass?

We show that the compact self avoiding walk configurations, kinetically generated by the recently introduced Interacting Growth Walk (IGW) model, can be considered as members of a canonical ensemble if they are assigned random values of energy. Such a mapping is necessary for studying the thermodynamic behaviour of this system. We have presented the specific heat data for the IGW, obtained from extensive simulations on a square lattice; we observe a broad hump in the specific heat above the $\theta$-point, contrary to expectation.Comment: 4 figures; Submitted to PR

Two-Dimensional Polymers with Random Short-Range Interactions

We use complete enumeration and Monte Carlo techniques to study two-dimensional self-avoiding polymer chains with quenched ``charges'' $\pm 1$. The interaction of charges at neighboring lattice sites is described by $q_i q_j$. We find that a polymer undergoes a collapse transition at a temperature $T_{\theta}$, which decreases with increasing imbalance between charges. At the transition point, the dependence of the radius of gyration of the polymer on the number of monomers is characterized by an exponent $\nu_{\theta} = 0.60 \pm 0.02$, which is slightly larger than the similar exponent for homopolymers. We find no evidence of freezing at low temperatures.Comment: 4 two-column pages, 6 eps figures, RevTex, Submitted to Phys. Rev.

Collapse of Randomly Self-Interacting Polymers

We use complete enumeration and Monte Carlo techniques to study self--avoiding walks with random nearest--neighbor interactions described by $v_0q_iq_j$, where $q_i=\pm1$ is a quenched sequence of ``charges'' on the chain. For equal numbers of positive and negative charges ($N_+=N_-$), the polymer with $v_0>0$ undergoes a transition from self--avoiding behavior to a compact state at a temperature $\theta\approx1.2v_0$. The collapse temperature $\theta(x)$ decreases with the asymmetry $x=|N_+-N_-|/(N_++N_-)$Comment: 8 pages, TeX, 4 uuencoded postscript figures, MIT-CMT-

Trapping microparticles in a structured dark focus

We experimentally demonstrate stable trapping and controlled manipulation of silica microspheres in a structured optical beam consisting of a dark focus surrounded by light in all directions - the so-called Dark Focus Tweezer. Results from power spectrum and potential analysis demonstrate the non-harmonicity of the trapping potential landspace, which is reconstructed from experimental data in agreement to Lorentz-Mie numerical simulations. Applications of the dark tweezer in levitated optomechanics and biophysics are discussed.Comment: Final versio