Fire Protection Of Wooden Storage Containers For Explosive And Pyrotechnic Products

Analysis of the emergency storage facilities for explosive and pyrotechnic products is conducted. It is established that one of the greatest risks is their flammability. Since the explosive and pyrotechnic products are stored in wooden containers, there is a need for their fire protection. To determine the efficiency of fire resistant containers for packaging explosive products it is designed operating range of testing method. This method is necessary to establish mass loss, measuring the growth temperature and response time of the squibs. The results of the efficiency of the fire retardant treatment of wood and organic coated coating showed that when exposed to high–temperature destruction of the construction detonation of the squibs didn\u27t happen.Tests to determine the quality of the fire retardant treatment of wood coatings showed that the temperature on the inner surfaces of the untreated sample was more than 760 ºC, samples with fire retardant coatings – no more than 128 °C. The conclusion of the feasibility of using fire–retardants is not based on inorganic and organic binders for the treatment of wooden structures.Method of determining the fire protection is used to assess the efficiency of the fire protection of wooden structures. Method comprises determining the ratio of the sample rate of burnout, the temperature increment and the ignition time of untreated and treated samples. As a result of the firing testing it is established a speed burnout reduction of samples of the container with treated coatings compared with untreated coatings is decreased by 2,4-4,4 times and respectively fire protection efficiency factor of treated samples of the container compared to untreated is increased by1.8-4.1 times

Resource-saving technologies of derivatization of functional nanostructured coatings by high-speed application methods

The work objective is to study new application methods based on the resource-saving technologies for nanostructured coatings with different functionality. The main task of the work is investigating modern efficient methods to increase strength, corrosion resistance, and wearability. The subject of study is high-speed application methods for anti-corrosion and wear-resistant coatings that significantly improve the durability and reliability of products. Design, technological features, specifications, and a scope of applicability of various installation models for high-speed deposition methods, including a gas-plasma technique, are described. The analysis results of the basic physical, mechanical and performance properties of the coatings obtained with the compact high-performance process equipment are presented. As a result of this work, it is shown that coatings obtained by the high-speed methods, unlike the subsonic methods, are characterized by the high performance. The paper also presents perspectives for development of the processing methods of the multifunctional coating application, the improvement of equipment and materials. The data obtained can be used for designing processes of applying dense coatings of consistent quality on the complex products made from nearly all metals and alloys. The results obtained are applicable in the mechanical engineering, repair production, aviation, energy engineering, etc

Prediction of basal glycaemia dynamics during treatment with 6-month lipid-lowering therapy in patients at high risk of cardiovascular disease

Background. A major meta-analysis has confirmed the ability of statins to exert both diabetogenic and hyperglycaemic effects. To date, practical recommendations for predicting glucose dynamics during lipid-lowering therapy have not been developed. Aims. Identify the combination of factors that can predict changes in basal glycaemia during 6-month lipid-lowering therapy in patients at high risk of cardiovascular disease. Methods. This study reports on 50 patients with diabetes or impaired glucose tolerance, and 18 patients with coronary artery disease without disorders of carbohydrate metabolism. Of note, 29 of the 50 diabetic or glucose intolerant patients had documented ischaemic heart disease (stable angina). Patients were randomised into three groups: Gr.1 (n=33, atorvastatin therapy), Gr.2 (n=17, atorvastatin in combination with ezetimibe) and Gr.3 (n=18, rosuvastatin therapy). After treatment for 24 weeks, we assessed lipid profile dynamics, metabolism of glucose/insulin and the HOMA-IR index. Multivariate analysis was then performed to identify factors that predicted increases in basal glycaemia. Results. All of the included patients completed 24 weeks of treatment (N=68). Lipid-lowering effect was significant in all three groups, and overall, target LDL cholesterol level was achieved in 50% of patients (n=34). In Gr.2, basal glucose level increased from 5.5(5.36.6) to 6.3(5.67.8) mmol/l (p=0.0014), which was accompanied by an increase in HOMA-IR (p=0.024). No significant change in basal glycaemia was observed in Grs.1 and 3. Moreover, an increase in the basal glycaemia was observed in 48.5% of patients in Gr.1, 70.6% in Gr.2 and 44.4% in Gr.3. Multivariate discriminant analysis across all patient groups revealed a canonical linear discriminant function that included the following factors: baseline basal glucose levels, total cholesterol levels, triglycerides and ratio of LDL/HDL cholesterol. Sensitivity and specificity of the model accounted for 75%; 51 out of the 68 cases were correctly classified when predicting the dynamics of basal glucose during lipid-lowering therapy. Conclusions. Our data demonstrate the ability to predict the dynamics of the basal glycaemia during lipid-lowering therapy. This may allow for a new way to identify patients at high risk of statin-related increases in glycaemia