3,459 research outputs found
Three-dimensional charge transport mapping by two-photon absorption edge transient-current technique in synthetic single-crystalline diamond
We demonstrate the application of two-photon absorption transient current
technique to wide bandgap semiconductors. We utilize it to probe charge
transport properties of single-crystal Chemical Vapor Deposition (scCVD)
diamond. The charge carriers, inside the scCVD diamond sample, are excited by a
femtosecond laser through simultaneous absorption of two photons. Due to the
nature of two-photon absorption, the generation of charge carriers is confined
in space (3-D) around the focal point of the laser. Such localized charge
injection allows to probe the charge transport properties of the semiconductor
bulk with a fine-grained 3-D resolution. Exploiting spatial confinement of the
generated charge, the electrical field of the diamond bulk was mapped at
different depths and compared to an X-ray diffraction topograph of the sample.
Measurements utilizing this method provide a unique way of exploring spatial
variations of charge transport properties in transparent wide-bandgap
semiconductors.Comment: This article may be downloaded for personal use only. Any other use
requires prior permission of the author and AIP Publishing. The following
article appeared in Applied Physics Letters and may be found at
https://doi.org/10.1063/1.509085
Diameter selective characterization of single-wall carbon nanotubes
A novel method is presented which allows the characterization of diameter
selective phenomena in SWCNTs. It is based on the transformation of fullerene
peapod materials into double-wall carbon nanotubes and studying the diameter
distribution of the latter. The method is demonstrated for the diameter
selective healing of nanotube defects and yield from C peapod samples.
Openings on small diameter nanotubes are closed first. The yield of very small
diameter inner nanotubes from C peapods is demonstrated. This challenges
the theoretical models of inner nanotube formation. An anomalous absence of
mid-diameter inner tubes is observed and explained by the suppressed amount of
C peapods due to the competition of the two almost equally stable
standing and lying C peapod configurations
Fine-tuning the functional properties of carbon nanotubes via the interconversion of encapsulated molecules
Tweaking the properties of carbon nanotubes is a prerequisite for their
practical applications. Here we demonstrate fine-tuning the electronic
properties of single-wall carbon nanotubes via filling with ferrocene
molecules. The evolution of the bonding and charge transfer within the tube is
demonstrated via chemical reaction of the ferrocene filler ending up as
secondary inner tube. The charge transfer nature is interpreted well within
density functional theory. This work gives the first direct observation of a
fine-tuned continuous amphoteric doping of single-wall carbon nanotubes
Linear plasmon dispersion in single-wall carbon nanotubes and the collective excitation spectrum of graphene
We have measured a strictly linear pi-plasmon dispersion along the axis of
individualized single wall carbon nanotubes, which is completely different from
plasmon dispersions of graphite or bundled single wall carbon nanotubes.
Comparative ab initio studies on graphene based systems allow us to reproduce
the different dispersions. This suggests that individualized nanotubes provide
viable experimental access to collective electronic excitations of graphene,
and it validates the use of graphene to understand electronic excitations of
carbon nanotubes. In particular, the calculations reveal that local field
effects (LFE) cause a mixing of electronic transitions, including the 'Dirac
cone', resulting in the observed linear dispersion
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