3,316 research outputs found
Pyridazines Lil. Polychloro Pyrido(2,3-d)- and -(3,4-d)pyridazines
The successful synthesis of perchloroimidazo(l,2-b)pyridazine1 prompted
us to investigate the possibility .of preparing chlorinated pyridopyridazines.
Although both parent bicyclic systems (I, II) are not expected to be susceptible to electrophilic substitution, pyrido(2,3-d)pyridazine, when brominated, formed primarily a complex which upon pyrolysis at 170- 180° is transformed into the 3-bromo derivative2
Fine-tuning the functional properties of carbon nanotubes via the interconversion of encapsulated molecules
Tweaking the properties of carbon nanotubes is a prerequisite for their
practical applications. Here we demonstrate fine-tuning the electronic
properties of single-wall carbon nanotubes via filling with ferrocene
molecules. The evolution of the bonding and charge transfer within the tube is
demonstrated via chemical reaction of the ferrocene filler ending up as
secondary inner tube. The charge transfer nature is interpreted well within
density functional theory. This work gives the first direct observation of a
fine-tuned continuous amphoteric doping of single-wall carbon nanotubes
Linear plasmon dispersion in single-wall carbon nanotubes and the collective excitation spectrum of graphene
We have measured a strictly linear pi-plasmon dispersion along the axis of
individualized single wall carbon nanotubes, which is completely different from
plasmon dispersions of graphite or bundled single wall carbon nanotubes.
Comparative ab initio studies on graphene based systems allow us to reproduce
the different dispersions. This suggests that individualized nanotubes provide
viable experimental access to collective electronic excitations of graphene,
and it validates the use of graphene to understand electronic excitations of
carbon nanotubes. In particular, the calculations reveal that local field
effects (LFE) cause a mixing of electronic transitions, including the 'Dirac
cone', resulting in the observed linear dispersion
THE EFFECT OF ROTATIONAL GRAZING ON FLORISTIC COMPOSITION AND YIELD OF Ranunculo repentis – Alopecuretum pratensis HILLY GRASSLAND
V letih 2001 in 2002 smo ugotavljali vpliv uvedbe celoletne čredinske paše z različno popasenostjo ruše - do 4 (obravnavanje 1) in do 7 cm (obravnavanje 2) na pridelek in spremembe v rastlinski sestavi donedavnega hribovskega travnika združbe Ranunculo repentis – Alopecuretum pratensis. Eksperimentalni pašnik (0.53 ha) je bil razdeljen na šest čredink – dve obravnavanji v treh ponovitvah (naključni bloki). S pašo v posamezni čredinki je osem krav svetlolisaste pasme pričelo ob višini ruše približno 15 cm in rušo v dnevu do dveh popaslo do ciljne višine. Celoletna paša ruše do različne višine v dveh letih izvajanja poskusa ni značilno različno vplivala na skupni pridelek sušine. Število različnih rastlinskih vrst v ruši se je iz začetnih 57 do spomladi 2002 zmanjšalo pod 40, nakar je do spomladi 2003 spet naraslo in sicer na 44 (1) oziroma 45 (2).
Shanonov indeks rastlinske pestrosti (H) je z uvedbo paše iz začetnih 3.16 v drugem letu upadel na 2.69 (1) oziroma na 2.72 (2). V naslednjem letu pa se je ponovno povečal na 2.87 (1) oziroma 2.91 (2).In the years 2001 and 2002 the effect of the introduction of the whole year rotational grazing with different post-grazing target sward heights (4 cm in the treatment 1, and 7 cm in the treatment 2) on the yield and changes in floristic composition of the Ranunculo repentis – Alopecuretum pratensis hilly grassland was studied. A meadow (0.53 ha) was divided into six paddocks (randomised block design - two treatments, three replications). Eight Simmental cows started grazing in paddocks at 15 cm sward height. After one or two days of grazing the target height of sward was achieved. During the two-year experiment, the whole year rotational grazing to various post-grazing target sward heights did not have a significantly different effect on the total dry matter (DM) yield. The number of different plant species in the sward, however, fell from the initial 57 to under 40 by the spring 2002, but by the spring 2003 the number rose again to 44 in the treatment 1, and to 45 in the treatment 2. Due to change in the utilisation, the Shannon diversity index (H) fell from the initial 3.16 to 2.69 in the second year (treatment 1) and to 2.72 (treatment 2). Next year it increased again to 2.87 (treatment
1) and to 2.91 (treatment 2)
Charge collection properties of irradiated depleted CMOS pixel test structures
Edge-TCT and charge collection measurements with passive test structures made
in LFoundry 150 nm CMOS process on p-type substrate with initial resistivity of
over 3 kcm are presented. Measurements were made before and after
irradiation with reactor neutrons up to 210
n/cm. Two sets of devices were investigated: unthinned (700
m) with substrate biased through the implant on top and thinned (200
m) with processed and metallised back plane.
Depleted depth was estimated with Edge-TCT and collected charge was measured
with Sr source using an external amplifier with 25 ns shaping time.
Depleted depth at given bias voltage decreased with increasing neutron fluence
but it was still larger than 70 m at 250 V after the highest fluence.
After irradiation much higher collected charge was measured with thinned
detectors with processed back plane although the same depleted depth was
observed with Edge-TCT. Most probable value of collected charge of over 5000
electrons was measured also after irradiation to 210
n/cm. This is sufficient to ensure successful operation of
these detectors at the outer layer of the pixel detector in the ATLAS
experiment at the upgraded HL-LHC
Gain Recovery in Heavily Irradiated Low Gain Avalanche Detectors by High Temperature Annealing
Studies of annealing at temperatures up to 450C with LGADs irradiated
with neutrons are described. It was found that the performance of LGADs
irradiated with 1.5e15 n/cm was already improved at 5 minutes of annealing
at 250C. Isochronal annealing for 30 minutes in 50C steps
between 300C and 450C showed that the largest beneficial effect
of annealing is at around 350C. Another set of devices was annealed for
60 minutes at 350C and this annealing significantly increased
V. The effect is equivalent to reducing the effective acceptor
removal constant by a factor of 4. Increase of V is the
consequence of increased effective space charge in the gain layer caused by
formation of electrically active defects or re-activation of interstitial Boron
atoms
Exciton-plasmon states in nanoscale materials: breakdown of the Tamm-Dancoff approximation
Within the Tamm-Dancoff approximation ab initio approaches describe excitons
as packets of electron-hole pairs propagating only forward in time. However, we
show that in nanoscale materials excitons and plasmons hybridize, creating
exciton--plasmon states where the electron-hole pairs oscillate back and forth
in time. Then, as exemplified by the trans-azobenzene molecule and carbon
nanotubes, the Tamm-Dancoff approximation yields errors as large as the
accuracy claimed in ab initio calculations. Instead, we propose a general and
efficient approach that avoids the Tamm--Dancoff approximation, and correctly
describes excitons, plasmons and exciton-plasmon states
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