Dynamics of diluted magnetic semiconductors from atomistic spin dynamics simulations: Mn doped GaAs as a case study

The dynamical behavior of the magnetism of diluted magnetic semiconductors (DMS) has been investigated by means of atomistic spin dynamics simulations. The conclusions drawn from the study are argued to be general for DMS systems in the low concentration limit, although all simulations are done for 5% Mn-doped GaAs with various concentrations of As antisite defects. The magnetization curve, $M(T)$, and the Curie temperature $T_C$ have been calculated, and are found to be in good correspondence to results from Monte Carlo simulations and experiments. Furthermore, equilibrium and non-equilibrium behavior of the magnetic pair correlation function have been extracted. The dynamics of DMS systems reveals a substantial short ranged magnetic order even at temperatures at or above the ordering temperature, with a non-vanishing pair correlation function extending up to several atomic shells. For the high As antisite concentrations the simulations show a short ranged anti-ferromagnetic coupling, and a weakened long ranged ferromagnetic coupling. For sufficiently large concentrations we do not observe any long ranged ferromagnetic correlation. A typical dynamical response shows that starting from a random orientation of moments, the spin-correlation develops very fast ($\sim$ 1ps) extending up to 15 atomic shells. Above $\sim$ 10 ps in the simulations, the pair correlation is observed to extend over some 40 atomic shells. The autocorrelation function has been calculated and compared with ferromagnets like bcc Fe and spin-glass materials. We find no evidence in our simulations for a spin-glass behaviour, for any concentration of As antisites. Instead the magnetic response is better described as slow dynamics, at least when compared to that of a regular ferromagnet like bcc Fe.Comment: 24 pages, 15 figure

New insights into the catalytic activity of gold nanoparticles for CO oxidation in electrochemical media

This study reports the interaction between metal oxides and gold in acidic media and its effect on the electrochemical oxidation of carbon monoxide. We describe the oxidation of CO in acidic media on Au nanoparticles of 3 and 7 nm on different oxide supports, diamond and carbon electrodes. In addition, the effect of a TiOx support on Au nanoparticles was mimicked by supporting TiOx nanoparticles on bulk gold. The comparison of these two systems strongly suggests that electronic interactions between Au and TiOx, rather than Au nanoparticle size effects, are the driving force of the catalytic activity in Au–TiOx

Scaling Law and Aging Phenomena in the Random Energy Model

We study the effect of temperature shift on aging phenomena in the Random Energy Model (REM). From calculation on the correlation function and simulation on the Zero-Field-Cooled magnetization, we find that the REM satisfies a scaling relation even if temperature is shifted. Furthermore, this scaling property naturally leads to results obtained in experiment and the droplet theory.Comment: 8 pages, 7 figures, to be submitted to J. Phys. Soc. Jp

Nonequilibrium Dynamics and Aging in the Three--Dimensional Ising Spin Glass Model

The low temperature dynamics of the three dimensional Ising spin glass in zero field with a discrete bond distribution is investigated via MC simulations. The thermoremanent magnetization is found to decay algebraically and the temperature dependent exponents agree very well with the experimentally determined values. The nonequilibrium autocorrelation function $C(t,t_w)$ shows a crossover at the waiting (or {\em aging}) time $t_w$ from algebraic {\em quasi-equilibrium} decay for times $t$$\ll$$t_w$ to another, faster algebraic decay for $t$$\gg$$t_w$ with an exponent similar to one for the remanent magnetization.Comment: Revtex, 11 pages + 4 figures (included as Latex-files

Rejuvenation in the Random Energy Model

We show that the Random Energy Model has interesting rejuvenation properties in its frozen phase. Different `susceptibilities' to temperature changes, for the free-energy and for other (`magnetic') observables, can be computed exactly. These susceptibilities diverge at the transition temperature, as (1-T/T_c)^-3 for the free-energy.Comment: 9 pages, 1 eps figur

Memory Effect, Rejuvenation and Chaos Effect in the Multi-layer Random Energy Model

We introduce magnetization to the Multi-layer Random Energy Model which has a hierarchical structure, and perform Monte Carlo simulation to observe the behavior of ac-susceptibility. We find that this model is able to reproduce three prominent features of spin glasses, i.e., memory effect, rejuvenation and chaos effect, which were found recently by various experiments on aging phenomena with temperature variations.Comment: 10 pages, 14 figures, to be submitted to J. Phys. Soc. Jp

Non-linear susceptibility in glassy systems: a probe for cooperative dynamical length scales

We argue that for generic systems close to a critical point, an extended Fluctuation-Dissipation relation connects the low frequency non-linear (cubic) susceptibility to the four-point correlation function. In glassy systems, the latter contains interesting information on the heterogeneity and cooperativity of the dynamics. Our result suggests that if the abrupt slowing down of glassy materials is indeed accompanied by the growth of a cooperative length ell, then the non-linear, 3 omega response to an oscillating field should substantially increase and give direct information on the temperature (or density) dependence of ell. The analysis of the non-linear compressibility or the dielectric susceptibility in supercooled liquids, or the non-linear magnetic susceptibility in spin-glasses, should give access to a cooperative length scale, that grows as the temperature is decreased or as the age of the system increases. Our theoretical analysis holds exactly within the Mode-Coupling Theory of glasses.Comment: 12 pages, 3 figures; a careful discussion of the spin-glass case in a field adde

Aryl hydrocarbon receptor activation during in vitro and in vivo digestion of raw and cooked broccoli (brassica oleracea var. Italica)

Broccoli is rich in glucosinolates, which can be converted upon chewing and processing into Aryl hydrocarbon Receptor (AhR) ligands. Activation of AhR plays an important role in overall gut homeostasis but the role of broccoli processing on the generation of AhR ligands is still largely unknown. In this study, the effects of temperature, cooking method (steaming versus boiling), gastric pH and further digestion of broccoli on AhR activation were investigated in vitro and in ileostomy subjects. For the in vitro study, raw, steamed (t = 3 min and t = 6 min) and boiled (t = 3 min and t = 6 min) broccoli were digested in vitro with different gastric pH. In the in vivo ileostomy study, 8 subjects received a broccoli soup or a broccoli soup plus an exogenous myrosinase source. AhR activation was measured in both in vitro and in vivo samples by using HepG2-Lucia™ AhR reporter cells. Cooking broccoli reduced the AhR activation measured after gastric digestion in vitro, but no effect of gastric pH was found. Indole AhR ligands were not detected or detected at very low levels both after intestinal in vitro digestion and in the ileostomy patient samples, which resulted in no AhR activation. This suggests that the evaluation of the relevance of glucosinolates for AhR modulation in the gut cannot prescind from the way broccoli is processed, and that broccoli consumption does not necessarily produce substantial amounts of AhR ligands in the large intestine

Clinical aspects of glucocorticoid sensitivity

Recent studies demonstrate that primary (hereditary) abnormalities in the glucocorticoid receptor gene make 6.6% of the normal population relatively 'hypersensitive' to glucocorticoids, while 2.3% are relatively 'resistant.' These abnormalities might explain why some individuals develop severe adverse effects during low dose glucocorticoid therapy, while others do not develop side effects even during long-term therapy with a much higher dose. Awareness of this heterogeneity in glucocorticoid sensitivity in the normal population might eventually allow the prediction of a 'safe' dose of glucocorticoid in individual patients. 'Resistance' to the beneficial clinical effects of glucocorticoid therapy in part of the patients with severe rheumatoid arthritis and asthma is probably rarely related to generalized primary (hereditary) glucocorticoid resistance. In the majority of patients this 'resistance' seems to be acquired and localized to the sites of inflammation, where it reflects high local cytokine production, which interferes with glucocorticoid action. Recognition of localized, acquired glucocorticoid resistance is of great importance indicating as alternative drug therapy with other immune-modulating drugs like cyclosporin and methotrexate. Chronic high dose glucocorticoid treatment in such patients is ineffective in alleviating symptomatology, while generalized side effects occur, reflecting the patient's normal systemic sensitivity to these drugs

Fluctuation Dissipation Ratio in Three-Dimensional Spin Glasses

We present an analysis of the data on aging in the three-dimensional Edwards Anderson spin glass model with nearest neighbor interactions, which is well suited for the comparison with a recently developed dynamical mean field theory. We measure the parameter $x(q)$ describing the violation of the relation among correlation and response function implied by the fluctuation dissipation theorem.Comment: LaTeX 10 pages + 4 figures (appended as uuencoded compressed tar-file), THP81-9