3 research outputs found
Magnetic and electronic ordering phenomena in the Ru2O6 layer honeycomb lattice compound AgRuO3
The silver ruthenium oxide AgRuO3 consists of honeycomb Ru5 2O 6 layers and can be considered an analogue of SrRu2O6 with a different intercalation. We present measurements of magnetic susceptibility and specific heat on AgRuO3 single crystals, which reveal a sharp antiferromagnetic transition at 342 3 K. The electrical transport in single crystals of AgRuO3 is determined by a combination of activated conduction over an intrinsic semiconducting gap of almost equal to 100 meV and carriers trapped and thermally released from defects. From powder neutron diffraction data a N el type antiferromagnetic structure with the Ru moments along the c axis is derived. Raman spectroscopy on AgRuO3 single crystals and muon spin rotation spectroscopy on powder samples indicate a further weak phase transition or a crossover in the temperature range 125 200 K. The transition does not show up in the magnetic susceptibility, and its origin is argued to be related to defects but cannot be fully clarified. The experimental findings are complemented by density functional theory based electronic structure calculations. It is found that the magnetism in AgRuO3 is similar to that in SrRu2O6, however, with stronger intralayer and weaker interlayer magnetic exchange interaction
ΠΠ°Π½Π³ΡΠ΅Π½ΠΎΠ·Π½Π°Ρ ΠΏΠΈΠΎΠ΄Π΅ΡΠΌΠΈΡ, ΠΈΠΌΠΈΡΠΈΡΡΡΡΠ°Ρ Π³ΡΠ°Π½ΡΠ»Π΅ΠΌΠ°ΡΠΎΠ· Ρ ΠΏΠΎΠ»ΠΈΠ°Π½Π³ΠΈΠΈΡΠΎΠΌ: ΠΊΠ»ΠΈΠ½ΠΈΡΠ΅ΡΠΊΠΈΠΉ ΡΠ»ΡΡΠ°ΠΉ ΠΈ ΠΎΠ±Π·ΠΎΡ Π»ΠΈΡΠ΅ΡΠ°ΡΡΡΡ
Pyoderma gangrenosum is an autoinflammatory neutrophilic dermatosis. Diagnosis of the disease remains a difficult task to date, due to the lack of a standard of examination and differential diagnostic signs. The primary elements in the development of PG may be papules, pustules or bullae the dissection of which subsequently leads to the formation of ulcers with irregular, violaceous, undermined borders. In rare cases, the diagnosis of the disease can also be complicated by the rapid development of internal organs damage symptoms, which must be regarded as extracutaneous manifestations of PG. Extracutaneous lesions can occur before, during or after the appearance of skin rashes, and the detection of sterile neutrophil infiltrates in the defeat of internal organs confirm the concept of PG as a multisystemic disease. The presented case of a rare course of PG with multiple skin lesions and extracutaneous manifestations, simulating systemic vasculitis, emphasizes the importance of a detailed examination of patients in order to make a correct diagnosis and prescribe timely adequate treatment.ΠΠ°Π½Π³ΡΠ΅Π½ΠΎΠ·Π½Π°Ρ ΠΏΠΈΠΎΠ΄Π΅ΡΠΌΠΈΡ (ΠΠ) ΠΏΡΠ΅Π΄ΡΡΠ°Π²Π»ΡΠ΅Ρ ΡΠΎΠ±ΠΎΠΉ Π°ΡΡΠΎΠ²ΠΎΡΠΏΠ°Π»ΠΈΡΠ΅Π»ΡΠ½ΡΠΉ Π½Π΅ΠΉΡΡΠΎΡΠΈΠ»ΡΠ½ΡΠΉ Π΄Π΅ΡΠΌΠ°ΡΠΎΠ·. ΠΠΈΠ°Π³Π½ΠΎΡΡΠΈΠΊΠ° Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΡ Π΄ΠΎ Π½Π°ΡΡΠΎΡΡΠ΅Π³ΠΎ Π²ΡΠ΅ΠΌΠ΅Π½ΠΈ ΠΎΡΡΠ°Π΅ΡΡΡ ΡΠ»ΠΎΠΆΠ½ΠΎΠΉ Π·Π°Π΄Π°ΡΠ΅ΠΉ Π² ΡΠ²ΡΠ·ΠΈ Ρ ΠΎΡΡΡΡΡΡΠ²ΠΈΠ΅ΠΌ ΡΡΠ°Π½Π΄Π°ΡΡΠ° ΠΎΠ±ΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΠΈ Π΄ΠΈΡΡΠ΅ΡΠ΅Π½ΡΠΈΠ°Π»ΡΠ½ΠΎ-Π΄ΠΈΠ°Π³Π½ΠΎΡΡΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΏΡΠΈΠ·Π½Π°ΠΊΠΎΠ². ΠΠ΅ΡΠ²ΠΈΡΠ½ΡΠΌΠΈ ΡΠ»Π΅ΠΌΠ΅Π½ΡΠ°ΠΌΠΈ ΠΏΡΠΈ ΡΠ°Π·Π²ΠΈΡΠΈΠΈ ΠΠ ΠΌΠΎΠ³ΡΡ Π±ΡΡΡ ΠΏΠ°ΠΏΡΠ»Ρ, ΠΏΡΡΡΡΠ»Ρ ΠΈΠ»ΠΈ Π±ΡΠ»Π»Ρ, Π²ΡΠΊΡΡΡΠΈΠ΅ ΠΊΠΎΡΠΎΡΡΡ
Π²ΠΏΠΎΡΠ»Π΅Π΄ΡΡΠ²ΠΈΠΈ ΠΏΡΠΈΠ²ΠΎΠ΄ΠΈΡ ΠΊ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ ΡΠ·Π² Ρ Π²Π°Π»ΠΈΠΊΠΎΠΎΠ±ΡΠ°Π·Π½ΠΎ ΠΏΡΠΈΠΏΠΎΠ΄Π½ΡΡΡΠΌΠΈ ΠΊΡΠ°ΡΠΌΠΈ Π±Π°Π³ΡΠΎΠ²ΠΎ-ΡΠΈΠ½ΡΡΠ½ΠΎΠΉ ΠΎΠΊΡΠ°ΡΠΊΠΈ. Π ΡΠ΅Π΄ΠΊΠΈΡ
ΡΠ»ΡΡΠ°ΡΡ
Π΄ΠΈΠ°Π³Π½ΠΎΡΡΠΈΠΊΡ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΡ ΡΠ°ΠΊΠΆΠ΅ ΠΌΠΎΠΆΠ΅Ρ ΡΡΠ»ΠΎΠΆΠ½ΠΈΡΡ Π±ΡΡΡΡΠΎΠ΅ ΡΠ°Π·Π²ΠΈΡΠΈΠ΅ ΡΠΈΠΌΠΏΡΠΎΠΌΠΎΠ² ΠΏΠΎΡΠ°ΠΆΠ΅Π½ΠΈΡ Π²Π½ΡΡΡΠ΅Π½Π½ΠΈΡ
ΠΎΡΠ³Π°Π½ΠΎΠ², ΠΊΠΎΡΠΎΡΡΠ΅ Π½Π΅ΠΎΠ±Ρ
ΠΎΠ΄ΠΈΠΌΠΎ ΡΠ°ΡΡΠ΅Π½ΠΈΠ²Π°ΡΡ ΠΊΠ°ΠΊ Π²Π½Π΅ΠΊΠΎΠΆΠ½ΡΠ΅ ΠΏΡΠΎΡΠ²Π»Π΅Π½ΠΈΡ ΠΠ. ΠΠ½Π΅ΠΊΠΎΠΆΠ½ΡΠ΅ ΠΏΠΎΡΠ°ΠΆΠ΅Π½ΠΈΡ ΠΌΠΎΠ³ΡΡ Π²ΠΎΠ·Π½ΠΈΠΊΠ°ΡΡ ΠΊΠ°ΠΊ Π΄ΠΎ, ΡΠ°ΠΊ ΠΈ Π²ΠΎ Π²ΡΠ΅ΠΌΡ ΠΈΠ»ΠΈ ΠΏΠΎΡΠ»Π΅ ΠΏΠΎΡΠ²Π»Π΅Π½ΠΈΡ ΠΊΠΎΠΆΠ½ΡΡ
Π²ΡΡΡΠΏΠ°Π½ΠΈΠΉ, Π° ΠΎΠ±Π½Π°ΡΡΠΆΠ΅Π½ΠΈΠ΅ ΡΡΠ΅ΡΠΈΠ»ΡΠ½ΡΡ
Π½Π΅ΠΉΡΡΠΎΡΠΈΠ»ΡΠ½ΡΡ
ΠΈΠ½ΡΠΈΠ»ΡΡΡΠ°ΡΠΎΠ² ΠΏΡΠΈ ΠΌΠΎΡΡΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠΉ Π΄ΠΈΠ°Π³Π½ΠΎΡΡΠΈΠΊΠ΅ ΠΏΠΎΠ΄ΡΠ²Π΅ΡΠΆΠ΄Π°Π΅Ρ ΠΊΠΎΠ½ΡΠ΅ΠΏΡΠΈΡ ΠΠ ΠΊΠ°ΠΊ ΠΌΡΠ»ΡΡΠΈΡΠΈΡΡΠ΅ΠΌΠ½ΠΎΠ³ΠΎ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΡ. ΠΡΠ΅Π΄ΡΡΠ°Π²Π»Π΅Π½Π½ΡΠΉ ΡΠ»ΡΡΠ°ΠΉ ΡΠ΅Π΄ΠΊΠΎΠ³ΠΎ ΡΠ΅ΡΠ΅Π½ΠΈΡ ΠΠ Ρ ΠΌΠ½ΠΎΠΆΠ΅ΡΡΠ²Π΅Π½Π½ΡΠΌΠΈ ΠΏΠΎΡΠ°ΠΆΠ΅Π½ΠΈΡΠΌΠΈ ΠΊΠΎΠΆΠΈ ΠΈ Π²Π½Π΅ΠΊΠΎΠΆΠ½ΡΠΌΠΈ ΠΏΡΠΎΡΠ²Π»Π΅Π½ΠΈΡΠΌΠΈ, ΠΈΠΌΠΈΡΠΈΡΡΡΡΠΈΠΉ ΡΠΈΡΡΠ΅ΠΌΠ½ΡΠΉ Π³ΡΠ°Π½ΡΠ»Π΅ΠΌΠ°ΡΠΎΠ·Π½ΡΠΉ Π²Π°ΡΠΊΡΠ»ΠΈΡ (Π³ΡΠ°Π½ΡΠ»Π΅ΠΌΠ°ΡΠΎΠ· Ρ ΠΏΠΎΠ»ΠΈΠ°Π½Π³ΠΈΠΈΡΠΎΠΌ Π³ΡΠ°Π½ΡΠ»Π΅ΠΌΠ°ΡΠΎΠ· ΠΠ΅Π³Π΅Π½Π΅ΡΠ°), ΠΏΠΎΠ΄ΡΠ΅ΡΠΊΠΈΠ²Π°Π΅Ρ Π²Π°ΠΆΠ½ΠΎΡΡΡ ΠΏΠΎΠ΄ΡΠΎΠ±Π½ΠΎΠ³ΠΎ ΠΎΠ±ΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΠΏΠ°ΡΠΈΠ΅Π½ΡΠΎΠ² Ρ ΡΠ΅Π»ΡΡ ΠΏΠΎΡΡΠ°Π½ΠΎΠ²ΠΊΠΈ ΠΏΡΠ°Π²ΠΈΠ»ΡΠ½ΠΎΠ³ΠΎ Π΄ΠΈΠ°Π³Π½ΠΎΠ·Π° ΠΈ Π½Π°Π·Π½Π°ΡΠ΅Π½ΠΈΡ ΡΠ²ΠΎΠ΅Π²ΡΠ΅ΠΌΠ΅Π½Π½ΠΎΠ³ΠΎ Π°Π΄Π΅ΠΊΠ²Π°ΡΠ½ΠΎΠ³ΠΎ Π»Π΅ΡΠ΅Π½ΠΈΡ