Strong Two--Body Decays of Light Mesons

In this paper, we present results on strong two-body decay widths of light $q\bar q$ mesons calculated in a covariant quark model. The model is based on the Bethe-Salpeter equation in its instantaneous approximation and has already been used for computing the complete meson mass spectrum and many electroweak decay observables. Our approach relies on the use of a phenomenological confinement potential with an appropriate spinorial Dirac structure and 't Hooft's instanton--induced interaction as a residual force for pseudoscalar and scalar mesons. The transition matrix element for the decay of one initial meson into two final mesons is evaluated in lowest order by considering conventional decays via quark loops as well as Zweig rule violating instanton--induced decays generated by the six--quark vertex of 't Hooft's interaction; the latter mechanism only contributes if all mesons in the decay have zero total angular momentum. We show that the interference of both decay mechanisms plays an important role in the description of the partial widths of scalar and pseudoscalar mesons.Comment: 35 pages, 7 figure

Synthesis, characterization and antifungal assessment of optically active bis-organotin compounds derived from (S)-BINOL diesters

Background: Organotin(IV) derivatives have appeared recently as potential biologically active metallopharmaceuticals exhibiting a variety of therapeutic activities. Hence, it is important to study the synthesis of new organotin compounds with low toxicity that may be of pharmacological interest.Objectives:This study focuses on the synthesis of new bis-stannylated derivatives with C2 symmetry that could be tested as antifungal agents against two clinical important fungal species, Cryptococcus neoformans and Candida albicans.Methods:The radical addition of triorganotin hydrides (R3SnH) and diorganotin chlorohydrides (R2ClSnH) to bis-α,β-unsaturated diesters derived from (S)-BINOL led to the corresponding new bis-stannylated derivatives with C2 symmetry. Nine pure organotin compounds were synthesized with defined stereochemistry. Four of them were enantiomerically pure and four were diastereoisomeric mixtures.Results:All new organotin compounds were fully characterized, those with phenyl ligands bonded to tin were the most active compounds against both the strains (Cryptococcus neoformans and Candida albicans), with activity parameters of IC50 close to those of the reference drug (amphotericin B).Conclusion:Nine pure organotin compounds with C2 symmetry were synthesized with defined stereochemistry and their antifungal properties were tested against two clinical important fungi with IC values close to those of the reference drug. The structure-containing preferably two or three phenyl groups joined to the tin atom were highly active against both the strains compared with those possessing tri-n-butyl groups.Fil: Costantino, Andrea Rosana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Neudörfl, Jörg M.. Universitat zu Köln; Alemania. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; ArgentinaFil: Ocampo, Romina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Svetaz, Laura Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario; Argentina. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; ArgentinaFil: Zacchino, Susana Alicia Stella. Universitat zu Köln; AlemaniaFil: Koll, Liliana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Mandolesi, Sandra Delia. Universidad Nacional del Sur; Argentin

Dual character of the electronic structure in YBa2Cu4O8: conduction bands of CuO2 planes and CuO chains

We use microprobe Angle-Resolved Photoemission Spectroscopy (muARPES) to separately investigate the electronic properties of CuO2 planes and CuO chains in the high temperature superconductor, YBa2Cu4O8. In the CuO2 planes, a two dimensional (2D) electronic structure with nearly momentum independent bilayer splitting is observed. The splitting energy is 150 meV at (pi,0), almost 50% larger than in Bi2Sr2CaCu2O(8+d) and the electron scattering at the Fermi level in the bonding band is about 1.5 times stronger than in the antibonding band. The CuO chains have a quasi one dimensional (1D) electronic structure. We observe two 1D bands separated by ~ 550meV: a conducting band and an insulating band with an energy gap of ~ 240meV. We find that the conduction electrons are well confined within the planes and chains with a non-trivial hybridization.Comment: 4 pages, 4 figure

Wärmespeicherkraftwerke - Ein Lösungsansatz für das Residuallastproblem im Stromsektor

Der Ausbau variabler erneuerbarer Stromquellen wie der Windkraft und der Photovoltaik führt im Zuge der Energiewende zu dem Phänomen der ähnlich variablen Residuallast für thermische Kraftwerke, deren Auslastung und Wirtschaftlichkeit infolge stetig sinkt. Dabei besteht der Anspruch, auch die Residuallast langfristig mit erneuerbarer Energie zu decken. Gleichzeitig kann die sicher abrufbare Leistung konventioneller thermischer Kraftwerke nicht einfach aufgegeben werden. Im vorliegenden Beitrag wird ein neues Geschäftsmodell für thermische Kraftwerke zur Diskussion gestellt, das diesen gordischen Knoten möglicherweise lösen kann