289 research outputs found
Magnetic properties and magnetostructural phase transitions in Ni2+xMn1-xGa shape memory alloys
A systematic study of magnetic properties of Ni2+xMn1-xGa (0 \le x \le 0.19)
Heusler alloys undergoing structural martensite-austenite transformations while
in ferromagnetic state has been performed. From measurements of spontaneous
magnetization, Ms(T), jumps \Delta M at structural phase transitions were
determined. Virtual Curie temperatures of the martensite were estimated from
the comparison of magnetization in martensitic and austenitic phases. Both
saturation magnetic moments in ferromagnetic state and effective magnetic
moments in paramagnetic state of Mn and Ni atoms were estimated and the
influence of delocalization effects on magnetism in these alloys was discussed.
The experimental results obtained show that the shift of martensitic transition
temperature depends weakly on composition. The values of this shift are in good
correspondence with Clapeyron-Clausius formalism taking into account the
experimental data on latent heat at martensite-austenite transformations.Comment: 7 pages, 8 figure
Distance learning course "Digital circuitry"
The training system is designed to generate, control and correction of knowledge and skills through their active use in different situations, is designed for use both in the classroom and in distance education and independent work of students. Provides increase learning efficiency through intensification and individualization of student's workΠΠ±ΡΡΠ°ΡΡΠΈΠΉ ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡ ΠΏΡΠ΅Π΄Π½Π°Π·Π½Π°ΡΠ΅Π½ Π΄Π»Ρ ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ, ΠΊΠΎΠ½ΡΡΠΎΠ»Ρ ΠΈ ΠΊΠΎΡΡΠ΅ΠΊΡΠΈΠΈ Π·Π½Π°Π½ΠΈΠΉ, ΡΠΌΠ΅Π½ΠΈΠΉ ΠΈ Π½Π°Π²ΡΠΊΠΎΠ² ΠΏΡΡΠ΅ΠΌ ΠΈΡ
Π°ΠΊΡΠΈΠ²Π½ΠΎΠ³ΠΎ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΡ Π² ΡΠ°Π·Π»ΠΈΡΠ½ΡΡ
ΡΠΈΡΡΠ°ΡΠΈΡΡ
, ΡΠ°ΡΡΡΠΈΡΠ°Π½ Π½Π° ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅, ΠΊΠ°ΠΊ Π² Π°ΡΠ΄ΠΈΡΠΎΡΠ½ΡΡ
Π·Π°Π½ΡΡΠΈΡΡ
, ΡΠ°ΠΊ ΠΈ ΠΏΡΠΈ Π΄ΠΈΡΡΠ°Π½ΡΠΈΠΎΠ½Π½ΠΎΠΌ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΠΈ ΠΈ Π² ΡΠ°ΠΌΠΎΡΡΠΎΡΡΠ΅Π»ΡΠ½ΠΎΠΉ ΡΠ°Π±ΠΎΡΠ΅ ΡΡΡΠ΄Π΅Π½ΡΠΎΠ². ΠΠ±Π΅ΡΠΏΠ΅ΡΠΈΠ²Π°Π΅Ρ ΠΏΠΎΠ²ΡΡΠ΅Π½ΠΈΠ΅ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΠΎΠ±ΡΡΠ΅Π½ΠΈΡ Π±Π»Π°Π³ΠΎΠ΄Π°ΡΡ Π°ΠΊΡΠΈΠ²ΠΈΠ·Π°ΡΠΈΠΈ ΠΈ ΠΈΠ½Π΄ΠΈΠ²ΠΈΠ΄ΡΠ°Π»ΠΈΠ·Π°ΡΠΈΠΈ ΡΠ°Π±ΠΎΡΡ ΡΡΡΠ΄Π΅Π½ΡΠΎ
Influence of intermartensitic transitions on transport properties of Ni2.16Mn0.84Ga alloy
Magnetic, transport, and x-ray diffraction measurements of ferromagnetic
shape memory alloy NiMnGa revealed that this alloy undergoes
an intermartensitic transition upon cooling, whereas no such a transition is
observed upon subsequent heating. The difference in the modulation of the
martensite forming upon cooling from the high-temperature austenitic state
[5-layered (5M) martensite], and the martensite forming upon the
intermartensitic transition [7-layered (7M) martensite] strongly affects the
magnetic and transport properties of the alloy and results in a large thermal
hysteresis of the resistivity and magnetization . The
intermartensitic transition has an especially marked influence on the transport
properties, as is evident from a large difference in the resistivity of the 5M
and 7M martensite, , which is larger than the jump of resistivity at
the martensitic transition from the cubic austenitic phase to the monoclinic 5M
martensitic phase. We assume that this significant difference in between
the martensitic phases is accounted for by nesting features of the Fermi
surface. It is also suggested that the nesting hypothesis can explain the
uncommon behavior of the resistivity at the martensitic transition, observed in
stoichiometric and near-stoichiometric Ni-Mn-Ga alloys.Comment: 7 pages, 6 figures, REVTEX
Stress-induced transformation in a Ni-Mn-In alloy and the concomitant change of resistivity
In this work, the influence of mechanical stress on magnetic properties and electric resistance of a Ni-Mn- In alloy was studied. It is shown that compression of Ni-Mn-In polycrystalline specimens brings about a stressinduced martensitic transformation. Optical images recorded in-situ confirmed the formation of a martensitic structure during loading and back-transformation upon unloading. Unloading after deformation of specimens that had experienced compressive strains up to 6%resulted in full recovery of their resistivity and magnetic susceptibility. The sharp increase in the electric resistance caused by the stress-induced transformation opens up new possibilities for Ni- Mn-In alloys to be used as a material for sensors responding to mechanical stress
Legal aspects of interests child in distance learning
Π ΡΡΠ°ΡΡΠ΅ ΡΠ°ΡΡΠΌΠ°ΡΡΠΈΠ²Π°ΡΡΡΡ ΠΏΡΠ°Π²ΠΎΠ²ΡΠ΅ Π°ΡΠΏΠ΅ΠΊΡΡ ΡΠΎΠ±Π»ΡΠ΄Π΅Π½ΠΈΡ ΠΈΠ½ΡΠ΅ΡΠ΅ΡΠΎΠ² ΡΠ΅Π±Π΅Π½ΠΊΠ° ΠΏΡΠΈ Π΄ΠΈΡΡΠ°Π½ΡΠΈΠΎΠ½Π½ΠΎΠΌ ΠΎΠ±ΡΡΠ΅Π½ΠΈΠΈ Π² Π ΠΎΡΡΠΈΠΉΡΠΊΠΎΠΉ Π€Π΅Π΄Π΅ΡΠ°ΡΠΈΠΈ, ΠΎΡΠ½ΠΎΠ²Π½ΡΠ΅ ΠΏΡΠ°Π²ΠΎΠ²ΡΠ΅ Π°ΠΊΡΡ Π΄Π°Π½Π½ΠΎΠΉ ΡΡΠ΅ΡΡ, ΠΎΡΠΎΠ±Π΅Π½Π½ΠΎΡΡΠΈ ΠΎΡΠ³Π°Π½ΠΈΠ·Π°ΡΠΈΠΈ Π΄ΠΈΡΡΠ°Π½ΡΠΈΠΎΠ½Π½ΠΎΠ³ΠΎ ΠΎΠ±ΡΡΠ΅Π½ΠΈΡ Π² ΠΏΠ΅ΡΠΈΠΎΠ΄ ΠΏΠ°Π½Π΄Π΅ΠΌΠΈΠΈ ΠΈ ΠΏΠΎΡΠ»Π΅ Π½Π΅Π΅.The article discusses the legal aspects of observing the interests of the child in distance learning in the Russian Federation, the main legal acts in this area, the features of the organization of distance learning during the pandemic and after it
Spin Density Distribution in a Nitroxide Biradical Containing 13C-Enriched Acetylene Groups in the Bridge: DFT Calculations and EPR Investigation
Abstract A specially synthesized nitroxide biradical R6-13C:C-p-C6H4βC:13CR6,B3, where R6 = 1-oxyl-2,2,6,6-tetramethyl-1,2,3,6-tetrahydropyridine nitroxide,
has been studied by electron paramagnetic resonance spectroscopy, and electron-nuclear double resonance (ENDOR). Spin density distribution and hyperfine
splitting (hfs) constant on 13C atoms calculations for biradical B3 were carried out using B3LYP and PBE0 functionals and several different basis sets including N07 family and were compared with the experimental value of the hfs constant on 13C atoms, measured from ENDOR spectra of B3. The mechanism of the intramolecular
electron spin exchange in B3 biradical is discussed
Left Ventricle Non-Compaction Myocardium and Thrombophilia in a Pregnant Woman
Non-compaction of the ventricular myocardium (NCM) is a genetic cardiomyopathy usually due to mutationof the G4.5 gene located in the Xq28 chromosomal region. This congenital disorder is characterized by pronounced trabeculations and intertrabecular recesses resulting from abnormal embryogenesis between the fifth and eighth fetal weeks. The reported prevalence in the general population is between 0.014% and 1.3%. The classic triad of complications includes heart failure, ventricular arrhythmias and systemic embolic events, although some patients have an asymptomatic form. NCM is commonly diagnosed by echocardiography, but contrast ventriculography, CT and MRI can also be used. Here we present a case of left ventricle NCM, manifested after respiratory infection, in a pregnant patient with congenital thrombophilia and a history of myocardial infarction
Dynamics of photogenerated charge carriers in TiO2 /MoO3, TiO2 /WO3 and TiO2 /V2O5 photocatalysts with mosaic structure
Titania is a widely used photocatalytic material possessing such advantages as low cost and high reactivity under the ultraviolet light illumination. However, the fast recombination of photoexcited charge carriers limits its application. Herein, we have synthesized original nanomaterials with mosaic structures that exhibited well-defined heterojunctions and new properties. Using SEM, XRD, EPR spectroscopy, photocatalytic measurements, and photoinduced pathphysiological activity of these photocatalysts, we studied the processes of charge carrier accumulation in TiO2 /MoO3, TiO2 /WO3, and TiO2 /V2 O5 under in situ UV illumination with emphasis on the charge exchange between energy levels of these nanosized semiconductors. It is shown that the accumulation of photoinduced charges occurs in two forms (i) filled electron traps corresponding to Ti4+ /Ti3+ levels and (ii) Mo5+ centers, both forms contributing to the photoinduced biocide activity of the samples. This work demonstrates that light exposure of heterostructure photocatalysts with mosaic surfaces produces different types of charge-trapping centers capable of interacting with molecular oxygen yielding peroxo species, which provide long-life light-induced βself-cleaningβ behavior. Such photoaccumulating materials open new opportunities in developing light-driven self-sterilization structures exhibiting a prolonged bactericidal effect up to 10 h after stopping light exposure. Β© 2020 by the authors. Licensee MDPI, Basel, Switzerland
Catalytic oxidation of hydrocarbons and thiophene at V2O5 : MoO3 nano- and microheterostructures
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