626 research outputs found
Nonuniqueness and derivative discontinuities in density-functional theories for current-carrying and superconducting systems
Current-carrying and superconducting systems can be treated within
density-functional theory if suitable additional density variables (the current
density and the superconducting order parameter, respectively) are included in
the density-functional formalism. Here we show that the corresponding conjugate
potentials (vector and pair potentials, respectively) are {\it not} uniquely
determined by the densities. The Hohenberg-Kohn theorem of these generalized
density-functional theories is thus weaker than the original one. We give
explicit examples and explore some consequences.Comment: revised version (typos corrected, some discussion added) to appear in
Phys. Rev.
Effective vanishing order of the Levi determinant
On a smooth domain in complex n space of finite D'Angelo q-type at a point,
an effective upper bound for the vanishing order of the Levi determinant
\text{coeff}\{\partial r \wedge \dbar r \wedge (\partial \dbar r)^{n-q}\} at
that point is given in terms of the D'Angelo q-type, the dimension of the space
n, and q itself. The argument uses Catlin's notion of a boundary system as well
as techniques pioneered by John D'Angelo.Comment: 22 pages; typos in example from p.20 fixed in the second versio
Friedel oscillations in one-dimensional metals: from Luttinger's theorem to the Luttinger liquid
Charge density and magnetization density profiles of one-dimensional metals
are investigated by two complementary many-body methods: numerically exact
(Lanczos) diagonalization, and the Bethe-Ansatz local-density approximation
with and without a simple self-interaction correction. Depending on the
magnetization of the system, local approximations reproduce different Fourier
components of the exact Friedel oscillations.Comment: 3 pages, 3 figures, Manuscript accepted by Journal of Magnetism and
Magnetic Materials, special issue for LAWMMM 2007 conferenc
Stabilized jellium model and structural relaxation effects on the fragmentation energies of ionized silver clusters
Using the stabilized jellium model in two schemes of `relaxed' and `rigid',
we have calculated the dissociation energies and the fission barrier heights
for the binary fragmentations of singly-ionized and doubly-ionized Ag clusters.
In the calculations, we have assumed spherical geometries for the clusters.
Comparison of the fragmentation energies in the two schemes show differences
which are significant in some cases. This result reveals the advantages of the
relaxed SJM over the rigid SJM in dynamical processes such as fragmentation.
Comparing the relaxed SJM results and axperimental data on fragmentation
energies, it is possible to predict the sizes of the clusters just before their
fragmentations.Comment: 9 pages, 12 JPG figure
Exact-exchange density-functional theory for quasi-two-dimensional electron gases
A simple exact-exchange density-functional method for a quasi-two-dimensional
electron gas with variable density is presented. An analytical expression for
the exact-exchange potential with only one occupied subband is provided,
without approximations. When more subbands are occupied the exact-exchange
potential is obtained numerically. The theory shows that, in contradiction with
LDA, the exact-exchange potential exhibits discontinuities and the system
suffers a zero-temperature first-order transition each time a subband is
occupied. Results suggesting that the translational symmetry might be
spontaneously broken at zero temperature are presented. An extension of the
theory to finite temperatures allows to describe a drop in the intersubband
spacing in good quantitative agreement with recent experiments.Comment: 14 pages, 3 figure
Spin Resolution of the Electron-Gas Correlation Energy: Positive same-spin contribution
The negative correlation energy per particle of a uniform electron gas of
density parameter and spin polarization is well known, but its
spin resolution into up-down, up-up, and down-down contributions is not.
Widely-used estimates are incorrect, and hamper the development of reliable
density functionals and pair distribution functions. For the spin resolution,
we present interpolations between high- and low-density limits that agree with
available Quantum Monte Carlo data. In the low-density limit for ,
we find that the same-spin correlation energy is unexpectedly positive, and we
explain why. We also estimate the up and down contributions to the kinetic
energy of correlation.Comment: new version, to appear in PRB Rapid Communicatio
Compressibility and Electronic Structure of MgB2 up to 8 GPa
The lattice parameters of MgB2 up to pressures of 8 GPa were determined using
high-resolution x-ray powder diffraction in a diamond anvil cell. The bulk
modulus, B0, was determined to be 151 +-5 GPa. Both experimental and
first-principles calculations indicate nearly isotropic mechanical behavior
under pressure. This small anisotropy is in contrast to the 2 dimensional
nature of the boron pi states. The pressure dependence of the density of states
at the Fermi level and a reasonable value for the average phonon frequency
account within the context of BCS theory for the reduction of Tc under
pressure.Comment: REVTeX file. 4 pages, 4 figure
Exchange and correlation as a functional of the local density of states
A functional is presented, in which the exchange
and correlation energy of an electron gas depends on the local density of
occupied states. A simple local parametrization scheme is proposed, entirely
from first principles, based on the decomposition of the exchange-correlation
hole in scattering states of different relative energies. In its practical
Kohn-Sham-like form, the single-electron orbitals become the independent
variables, and an explicit formula for the functional derivative is obtained.Comment: 5 pages. Expanded version. Will appear in Phys. Rev.
Exact-exchange density-functional calculations for noble-gas solids
The electronic structure of noble-gas solids is calculated within density
functional theory's exact-exchange method (EXX) and compared with the results
from the local-density approximation (LDA). It is shown that the EXX method
does not reproduce the fundamental energy gaps as well as has been reported for
semiconductors. However, the EXX-Kohn-Sham energy gaps for these materials
reproduce about 80 % of the experimental optical gaps. The structural
properties of noble-gas solids are described by the EXX method as poorly as by
the LDA one. This is due to missing Van der Waals interactions in both, LDA and
EXX functionals.Comment: 4 Fig
Correlation energies of inhomogeneous many-electron systems
We generalize the uniform-gas correlation energy formalism of Singwi, Tosi,
Land and Sjolander to the case of an arbitrary inhomogeneous many-particle
system. For jellium slabs of finite thickness with a self-consistent LDA
groundstate Kohn-Sham potential as input, our numerical results for the
correlation energy agree well with diffusion Monte Carlo results. For a helium
atom we also obtain a good correlation energy.Comment: 4 pages,1 figur
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