23,849 research outputs found
Calculation of the static and dynamical correlation energy of pseudo-one-dimensional beryllium systems via a many-body expansion
Low-dimensional beryllium systems constitute interesting case studies for the
test of correlation methods because of the importance of both static and
dynamical correlation in the formation of the bond. Aiming to describe the
whole dissociation curve of extended Be systems we chose to apply the method of
increments (MoI) in its multireference (MR) formalism. However, in order to do
so an insight into the wave function was necessary. Therefore we started by
focusing on the description of small Be chains via standard quantum chemical
methods and gave a brief analysis of the main characteristics of their wave
functions. We then applied the MoI to larger beryllium systems, starting from
the Be6 ring. First, the complete active space formalism (CAS-MoI) was employed
and the results were used as reference for local MR calculations of the whole
dissociation curve. Despite this approach is well established for the
calculation of systems with limited multireference character, its application
to the description of whole dissociation curves still requires further testing.
After discussing the role of the basis set, the method was finally applied to
larger rings and extrapolated to an infinite chain
Enabling Micro-level Demand-Side Grid Flexiblity in Resource Constrained Environments
The increased penetration of uncertain and variable renewable energy presents
various resource and operational electric grid challenges. Micro-level
(household and small commercial) demand-side grid flexibility could be a
cost-effective strategy to integrate high penetrations of wind and solar
energy, but literature and field deployments exploring the necessary
information and communication technologies (ICTs) are scant. This paper
presents an exploratory framework for enabling information driven grid
flexibility through the Internet of Things (IoT), and a proof-of-concept
wireless sensor gateway (FlexBox) to collect the necessary parameters for
adequately monitoring and actuating the micro-level demand-side. In the summer
of 2015, thirty sensor gateways were deployed in the city of Managua
(Nicaragua) to develop a baseline for a near future small-scale demand response
pilot implementation. FlexBox field data has begun shedding light on
relationships between ambient temperature and load energy consumption, load and
building envelope energy efficiency challenges, latency communication network
challenges, and opportunities to engage existing demand-side user behavioral
patterns. Information driven grid flexibility strategies present great
opportunity to develop new technologies, system architectures, and
implementation approaches that can easily scale across regions, incomes, and
levels of development
Renormalization group improved black hole space-time in large extra dimensions
By taking into account a running of the gravitational coupling constant with
an ultra violet fixed point, an improvement of classical black hole space-times
in extra dimensions is studied. It is found that the thermodynamic properties
in this framework allow for an effective description of the black hole
evaporation process. Phenomenological consequences of this approach are
discussed and the LHC discovery potential is estimated.Comment: 13 pages, 6 figure
Current Induced Excitations in Cu/Co/Cu Single Ferromagnetic Layer Nanopillars
Current-induced magnetic excitations in Cu/Co/Cu single layer nanopillars
(~50 nm in diameter) have been studied experimentally as a function of Co layer
thickness at low temperatures for large applied fields perpendicular to the
layers. For asymmetric junctions current induced excitations are observed at
high current densities for only one polarity of the current and are absent at
the same current densities in symmetric junctions. These observations confirm
recent predictions of spin-transfer torque induced spin wave excitations in
single layer junctions with a strong asymmetry in the spin accumulation in the
leads.Comment: 4 pages, 3 figures, submitted to Phys. Rev. Let
Slow synaptic transmission in frog sympathetic ganglia
Bullfrog ganglia contain two classes of neurone, B and C cells, which receive different inputs and exhibit different slow synaptic potentials. B cells, to which most effort has been directed, possess slow and late slow EPSPs. The sEPSP reflects a muscarinic action of acetylcholine released from boutons on B cells, whereas the late sEPSP is caused by a peptide (similar to teleost LHRH) released from boutons on C cells. During either sEPSP there is a selective reduction in two slow potassium conductances, designated 'M' and 'AHP'. The M conductance is voltage dependent and the AHP conductance is calcium dependent. Normally they act synergistically to prevent repetitive firing of action potentials during maintained stimuli. Computer stimulation of the interactions of these conductances with the other five voltage-dependent conductances present in the membrane allows a complete reconstruction of the effects of slow synaptic transmission on electrical behaviour
On the Number of Facets of Three-Dimensional Dirichlet Stereohedra III: Full Cubic Groups
We are interested in the maximum possible number of facets that Dirichlet
stereohedra for three-dimensional crystallographic groups can have. The problem
for non-cubic groups was studied in previous papers by D. Bochis and the second
author (Discrete Comput. Geom. 25:3 (2001), 419-444, and Beitr. Algebra Geom.,
47:1 (2006), 89-120). This paper deals with ''full'' cubic groups, while
''quarter'' cubic groups are left for a subsequent paper. Here, ''full'' and
''quarter'' refers to the recent classification of three-dimensional
crystallographic groups by Conway, Delgado-Friedrichs, Huson and Thurston
(math.MG/9911185, Beitr. Algebra Geom. 42.2 (2001), 475-507).
Our main result in this paper is that Dirichlet stereohedra for any of the 27
full groups cannot have more than 25 facets. We also find stereohedra with 17
facets for one of these groups.Comment: 28 pages, 12 figures. Changes from v1: apart of some editing (mostly
at the end of the introduction) and addition of references, an appendix has
been added, which analyzes the case where the base point does not have
trivial stabilize
Coupling to haloform molecules in intercalated C60?
For field-effect-doped fullerenes it was reported that the superconducting
transition temperature Tc is markedly larger for C60.2CHX_3 (X=Cl, Br)
crystals, than for pure C60. Initially this was explained by the expansion of
the volume per C60-molecule and the corresponding increase in the density of
states at the Fermi level in the intercalated crystals. On closer examination
it has, however, turned out to be unlikely that this is the mechanism behind
the increase in Tc. An alternative explanation of the enhanced transition
temperatures assumes that the conduction electrons not only couple to the
vibrational modes of the C60-molecule, but also to the modes of the
intercalated molecules. We investigate the possibility of such a coupling. We
find that, assuming the ideal bulk structure of the intercalated crystal, both
a coupling due to hybridization of the molecular levels, and a coupling via
dipole moments should be very small. This suggests that the presence of the
gate-oxide in the field-effect-devices strongly affects the structure of the
fullerene crystal at the interface.Comment: 4 pages, 1 figure, to be published in PRB (rapid communication
- …