Calculation of the static and dynamical correlation energy of pseudo-one-dimensional beryllium systems via a many-body expansion

Low-dimensional beryllium systems constitute interesting case studies for the test of correlation methods because of the importance of both static and dynamical correlation in the formation of the bond. Aiming to describe the whole dissociation curve of extended Be systems we chose to apply the method of increments (MoI) in its multireference (MR) formalism. However, in order to do so an insight into the wave function was necessary. Therefore we started by focusing on the description of small Be chains via standard quantum chemical methods and gave a brief analysis of the main characteristics of their wave functions. We then applied the MoI to larger beryllium systems, starting from the Be6 ring. First, the complete active space formalism (CAS-MoI) was employed and the results were used as reference for local MR calculations of the whole dissociation curve. Despite this approach is well established for the calculation of systems with limited multireference character, its application to the description of whole dissociation curves still requires further testing. After discussing the role of the basis set, the method was finally applied to larger rings and extrapolated to an infinite chain

Enabling Micro-level Demand-Side Grid Flexiblity in Resource Constrained Environments

The increased penetration of uncertain and variable renewable energy presents various resource and operational electric grid challenges. Micro-level (household and small commercial) demand-side grid flexibility could be a cost-effective strategy to integrate high penetrations of wind and solar energy, but literature and field deployments exploring the necessary information and communication technologies (ICTs) are scant. This paper presents an exploratory framework for enabling information driven grid flexibility through the Internet of Things (IoT), and a proof-of-concept wireless sensor gateway (FlexBox) to collect the necessary parameters for adequately monitoring and actuating the micro-level demand-side. In the summer of 2015, thirty sensor gateways were deployed in the city of Managua (Nicaragua) to develop a baseline for a near future small-scale demand response pilot implementation. FlexBox field data has begun shedding light on relationships between ambient temperature and load energy consumption, load and building envelope energy efficiency challenges, latency communication network challenges, and opportunities to engage existing demand-side user behavioral patterns. Information driven grid flexibility strategies present great opportunity to develop new technologies, system architectures, and implementation approaches that can easily scale across regions, incomes, and levels of development

Renormalization group improved black hole space-time in large extra dimensions

By taking into account a running of the gravitational coupling constant with an ultra violet fixed point, an improvement of classical black hole space-times in extra dimensions is studied. It is found that the thermodynamic properties in this framework allow for an effective description of the black hole evaporation process. Phenomenological consequences of this approach are discussed and the LHC discovery potential is estimated.Comment: 13 pages, 6 figure

Current Induced Excitations in Cu/Co/Cu Single Ferromagnetic Layer Nanopillars

Current-induced magnetic excitations in Cu/Co/Cu single layer nanopillars (~50 nm in diameter) have been studied experimentally as a function of Co layer thickness at low temperatures for large applied fields perpendicular to the layers. For asymmetric junctions current induced excitations are observed at high current densities for only one polarity of the current and are absent at the same current densities in symmetric junctions. These observations confirm recent predictions of spin-transfer torque induced spin wave excitations in single layer junctions with a strong asymmetry in the spin accumulation in the leads.Comment: 4 pages, 3 figures, submitted to Phys. Rev. Let

Slow synaptic transmission in frog sympathetic ganglia

Bullfrog ganglia contain two classes of neurone, B and C cells, which receive different inputs and exhibit different slow synaptic potentials. B cells, to which most effort has been directed, possess slow and late slow EPSPs. The sEPSP reflects a muscarinic action of acetylcholine released from boutons on B cells, whereas the late sEPSP is caused by a peptide (similar to teleost LHRH) released from boutons on C cells. During either sEPSP there is a selective reduction in two slow potassium conductances, designated 'M' and 'AHP'. The M conductance is voltage dependent and the AHP conductance is calcium dependent. Normally they act synergistically to prevent repetitive firing of action potentials during maintained stimuli. Computer stimulation of the interactions of these conductances with the other five voltage-dependent conductances present in the membrane allows a complete reconstruction of the effects of slow synaptic transmission on electrical behaviour

On the Number of Facets of Three-Dimensional Dirichlet Stereohedra III: Full Cubic Groups

We are interested in the maximum possible number of facets that Dirichlet stereohedra for three-dimensional crystallographic groups can have. The problem for non-cubic groups was studied in previous papers by D. Bochis and the second author (Discrete Comput. Geom. 25:3 (2001), 419-444, and Beitr. Algebra Geom., 47:1 (2006), 89-120). This paper deals with ''full'' cubic groups, while ''quarter'' cubic groups are left for a subsequent paper. Here, ''full'' and ''quarter'' refers to the recent classification of three-dimensional crystallographic groups by Conway, Delgado-Friedrichs, Huson and Thurston (math.MG/9911185, Beitr. Algebra Geom. 42.2 (2001), 475-507). Our main result in this paper is that Dirichlet stereohedra for any of the 27 full groups cannot have more than 25 facets. We also find stereohedra with 17 facets for one of these groups.Comment: 28 pages, 12 figures. Changes from v1: apart of some editing (mostly at the end of the introduction) and addition of references, an appendix has been added, which analyzes the case where the base point does not have trivial stabilize

Coupling to haloform molecules in intercalated C60?

For field-effect-doped fullerenes it was reported that the superconducting transition temperature Tc is markedly larger for C60.2CHX_3 (X=Cl, Br) crystals, than for pure C60. Initially this was explained by the expansion of the volume per C60-molecule and the corresponding increase in the density of states at the Fermi level in the intercalated crystals. On closer examination it has, however, turned out to be unlikely that this is the mechanism behind the increase in Tc. An alternative explanation of the enhanced transition temperatures assumes that the conduction electrons not only couple to the vibrational modes of the C60-molecule, but also to the modes of the intercalated molecules. We investigate the possibility of such a coupling. We find that, assuming the ideal bulk structure of the intercalated crystal, both a coupling due to hybridization of the molecular levels, and a coupling via dipole moments should be very small. This suggests that the presence of the gate-oxide in the field-effect-devices strongly affects the structure of the fullerene crystal at the interface.Comment: 4 pages, 1 figure, to be published in PRB (rapid communication