Photochemical modeling of the Antarctic stratosphere: Observational constraints from the airborne Antarctic ozone experiment and implications for ozone behavior

The rapid decrease in O3 column densities observed during Antarctic spring has been attributed to several chemical mechanisms involving nitrogen, bromine, or chlorine species, to dynamical mechanisms, or to a combination of the above. Chlorine-related theories, in particular, predict greatly elevated concentrations of ClO and OClO and suppressed abundances of NO2 below 22 km. The heterogeneous reactions and phase transitions proposed by these theories could also impact the concentrations of HCl, ClNO3 and HNO3 in this region. Observations of the above species have been carried out from the ground by the National Ozone Expedition (NOZE-I, 1986, and NOZE-II, 1987), and from aircrafts by the Airborne Antarctic Ozone Experiment (AAOE) during the austral spring of 1987. Observations of aerosol concentrations, size distribution and backscattering ratio from AAOE, and of aerosol extinction coefficients from the SAM-II satellite can also be used to deduce the altitude and temporal behavior of surfaces which catalyze heterogeneous mechanisms. All these observations provide important constraints on the photochemical processes suggested for the spring Antarctic stratosphere. Results are presented for the concentrations and time development of key trace gases in the Antarctic stratosphere, utilizing the AER photochemical model. This model includes complete gas-phase photochemistry, as well as heterogeneous reactions. Heterogeneous chemistry is parameterized in terms of surface concentrations of aerosols, collision frequencies between gas molecules and aerosol surfaces, concentrations of HCl/H2O in the frozen particles, and probability of reaction per collision (gamma). Values of gamma are taken from the latest laboratory measurements. The heterogeneous chemistry and phase transitions are assumed to occur between 12 and 22 km. The behavior of trace species at higher altitudes is calculated by the AER 2-D model without heterogeneous chemistry. Calculations are performed for solar illumination conditions typical of 60, 70, and 80 S, from July 15 to October 31

Quenching of Impurity Spins at Cu/CuO Interfaces: An Antiferromagnetic Proximity Effect

It is observed that the magnetoconductance of bilayer films of copper (Cu) and copper monoxide (CuO) has distinct features compared of that of Cu films on conventional band insulator substrates. We analyze the data above 2 K by the theory of weak antilocalization in two-dimensional metals and suggest that spin-flip scatterings by magnetic impurities inside Cu are suppressed in Cu/CuO samples. Plausibly the results imply a proximity effect of antiferromagnetism inside the Cu layer, which can be understood in the framework of Ruderman-Kittel-Kasuya-Yoshida (RKKY) interactions. The data below 1 K, which exhibit slow relaxation reminiscent of spin glass, are consistent with this interpretation.Comment: 6 pages, 4 figures, 2 tables. Added a supplementary materia

Antarctic ozone decrease: Possible impact on the seasonal and latitudinal distribution of total ozone as simulated by a 2-D model

Satellite borne instruments, the Total Ozone Mapping Spectrometer (TOMS) and the Solar Backscatter Ultraviolet spectrometer (SBUV), show that total column ozone has decreased by more than 5 percent in the neighborhood of 60 S at all seasons since 1979. This is considerably larger than the decrease calculated by 2-D models which take into account solar flux variation and increases of trace gas concentrations over the same period. The meteorological conditions (warmer temperature and the apparent lack of polar stratospheric clouds) at these latitudes do not seem to favor heterogeneous chemistry as the direct cause for the observed ozone reduction. A mechanism involving the seasonal transport of ozone-poor air mass from within the polar vortex to lower latitudes (the so-called dilution effect) is proposed as a possible explanation for the observed year-round ozone reduction in regions away from the vortex

Effects of engine emissions from high-speed civil transport aircraft: A two-dimensional modeling study, part 1

The AER two-dimensional chemistry-transport model is used to study the effect on stratospheric ozone (O3) from operations of supersonic and subsonic aircraft. The study is based on six emission scenarios provided to AER. The study showed that: (1) the O3 response is dominated by the portion of the emitted nitrogen compounds that is entrained in the stratosphere; (2) the entrainment is a sensitive function of the altitude at which the material is injected; (3) the O3 removal efficiency of the emitted material depends on the concentrations of trace gases in the background atmosphere; and (4) evaluation of the impact of fleet operations in the future atmosphere must take into account the expected changes in trace gas concentrations from other activities. Areas for model improvements in future studies are also discussed

Science Overview

This report presents an overview of the latest scientific consensus understanding of the effect of aviation emissions on the atmosphere for both local air quality and climate change in order to provide a contextual framework for raising future questions to help assess the environmental benefits of technology goals. The questions may take the form of what are the environmental benefits that would result if goals are achieved, what are the consequences for other aviation pollutants, and whether tools exist to evaluate the trade-off. In addition to this documents, presentations will be made at the meeting to illustrate current developing views on these subjects. To facilitate studies on trade-offs among environmental impacts from aviation, one must start with scientific investigations that quantify the impacts. A second step is to select representative metrics with policy relevance so that diverse impacts can be put on the same common scale. The IPCC Special Report on Aviation (IPCC, 1999) serves as an excellent example of the first step. The report was produced by IPCC's Working Group 1, whose mandate is to provide the assessment of the scientific aspects of the climate system and climate change. An example of the second step is Witt et al. (2005), a study commissioned by the Environment DG of the European Commission. Within the context of CAEP, step 1 is aligned with the responsibilities of the Research Focal Points, while step 2 is more related to activities of FESG. These steps are likely to be iterative as proposed policy options will raise new science questions, and new science will expand or limit policy options. Past experiences show that clearly defined policy-related scientific needs will help focus the scientific community to marshal their intellects to provide the needed answers

Relative effects on global warming of halogenated methanes and ethanes of social and industrial interest

The relative potential global warming effects for several halocarbons (chlorofluorocarbons (CFC's)-11, 12, 113, 114, and 115; hydrochlorofluorocarbons (HCFC's) 22, 123, 124, 141b, and 142b; and hydrofluorocarbons (HFC's) 125, 134a, 143a, and 152a; carbon tetrachloride; and methyl chloroform) were calculated by two atmospheric modeling groups. These calculations were based on atmospheric chemistry and radiative convective models to determine the chemical profiles and the radiative processes. The resulting relative greenhouse warming when normalized to the effect of CFC-11 agree reasonably well as long as we account for differences between modeled lifetimes. Differences among results are discussed. Sensitivity of relative warming values is determined with respect to trace gas levels assumed. Transient relative global warming effects are analyzed

Science Overview: The LTTG Technology Review Meeting March 2006 Summary Report

This report presents an overview of the latest scientific consensus understanding of the effect of aviation emissions on the atmosphere for both local air quality and climate change in order to provide a contextual framework for raising future questions to help assess the environmental benefits of technology goals. Although studies of the two issues share a common framework (of quantifying the emissions, the change in concentrations in the atmosphere, and the environmental impacts), the communities of practitioners are distinctly different. The scientific community will continue to provide guidelines on trade-off among different contributors to a specific environmental impact, such as global climate, or local air quality. Ultimately, monetization of the costs and benefits of mitigation actions is the proper tool for quantifying and analyzing trade-offs between the two issues. Scientific assessment of the impacts and their uncertainties are critical inputs to these analyses. Until environmental effects of aviation emerge as a policy driven issue, there is little incentive within the scientific community to focus on research efforts specific to trade-off studies between local and global impacts

Effects of engine emissions from high-speed civil transport aircraft: A two-dimensional modeling study, part 2

The AER two-dimensional chemistry-transport model is used to study the effect of supersonic and subsonic aircraft operation in the 2010 atmosphere on stratospheric ozone (O3). The results show that: (1) the calculated O3 response is smaller in the 2010 atmosphere compared to previous calculations performed in the 1980 atmosphere; (2) with the emissions provided, the calculated decrease in O3 column is less than 1 percent; and (3) the effect of model grid resolution on O3 response is small provided that the physics is not modified

Utilization of UARS Data in Validation of Photochemical and Dynamical Mechanism in Stratospheric Models

We proposed model-data intercomparison studies for UARS data. In the past three months, we have been working on constructing analysis tools to diagnose the UARS data. The 'Trajectory mapping' technique, which was developed by Morris (1994), is adaptable to generate synoptic maps of trace gas data from asynoptic observations. An in-house trajectory model (kinematic methods following Merrill et al., 1986 and Pickering et al., 1994) has been developed in AER under contract with NASA/ACMAP and the trajectory mapping tool has been applied to analyze UARS measurement