110 research outputs found
The states 1^1\Sigma^+_u, 1^1\Pi_u and 2^1\Sigma^+_u of Sr_2 studied by Fourier-transform spectroscopy
A high resolution study of the electronic states 1^1\Sigma^+_u and 1^1\Pi_u
which belong to the asymptote 4^1D + 5^1S and of the state 2(A)^1\Sigma^+_u,
which correlates to the asymptote 5^1P + 5^1S, is performed by
Fourier-transform spectroscopy of fluorescence progressions induced by single
frequency laser excitation. Precise descriptions of the potentials up to 2000
cm^{-1} above the bottom are derived and compared to currently available ab
initio calculations. Especially for the state 1^1\Sigma^+_u large deviations
are found. Rather weak and local perturbations are observed for the states
1^1\Pi_u and 2^1\Sigma^+_u, while a strong coupling of the state 1^1\Sigma^+_u
to the component \Omega=0^+_u of the state 1^3\Pi_u, which belongs to the
asymptote 5^3P + 5^1S, is indicated.Comment: Typing errors corrected (including numbers in table IX), 12 pages, 9
figure
Fourier-transform spectroscopy of Sr2 and revised ground state potential
Precise potentials for the ground state X1Sigma+g and the minimum region of
the excited state 2_1Sigma+u of Sr2 are derived by high resolution
Fourier-transform spectroscopy of fluorescence progressions from single
frequency laser excitation of Sr2 produced in a heat pipe at 950 Celsius. A
change of the rotational assignment by four units compared to an earlier work
(G. Gerber, R. M\"oller, and H. Schneider, J. Chem. Phys. 81, 1538 (1984)) is
needed for a consistent description leading to a significant shift of the
potentials towards longer inter atomic distances. The huge amount of ground
state data derived for the three different isotopomers 88Sr2, 86Sr88Sr and
87Sr88Sr (almost 60% of all excisting bound rovibrational ground state levels
for the isotopomer 88Sr2) fixes this assignment undoubtedly. The presented
ground state potential is derived from the observed transitions for the radial
region from 4 to 11 A (9 cm-1 below the asymptote) and is extended to the longe
range region by the use of theoretical dispersion coefficients together with
already available photoassociation data. New estimations of the scattering
lengths for the complete set of isotopic combinations are derived by mass
scaling with the derived potential. The data set for the excited state
2_1Sigma+u was sufficient to derive a potential energy curve around the
minimum.Comment: 10 pages, 7 figures, some small corrections done especially to the
potential description of the excited state (already included in the published
journal version
The coupled system (2)2Σ+ and (1)2Π of 7Li88Sr
We analyse rovibrational transitions of the (2)2Σ+-X(1)2Σ+ system of LiSr and find the energy levels of the (2)2Σ+ state to be perturbed by coupling between the (2)2Σ+ and (1)2Π states. We present an analysis of the coupled system yielding molecular parameters for the lowest vibrational levels of the (2)2Σ+ state and for higher vibrational levels of the (1)2Π state together with molecular coupling constants. Improved Dunham coefficients for the rovibrational levels of the X(1)2Σ+ state are also obtained, where the correlation with the parameters of the excited states is removed completely. © 2020 The Author(s). Published by IOP Publishing Ltd
Study of coupled states for the (4s^{2})^{1}S + (4s4p)^{3}P asymptote of Ca_{2}
The coupled states A^{1}\Sigma_{u}^{+} (^{1}D +}1}S), c^{3}\Pi_{u} (^{3}P +
^{1}S) and a^{3}\Sigma_{u}^{+} (^{3}P +}1}S) of the calcium dimer are
investigated in a laser induced fluorescence experiment combined with
high-resolution Fourier-transform spectroscopy. A global deperturbation
analysis of the observed levels, considering a model, which is complete within
the subspace of relevant neighboring states, is performed using the Fourier
Grid Hamiltonian method. We determine the potential energy curve of the
A^{1}\Sigma_{u}^{+} and c^{3}\Pi_{u} states and the strengths of the couplings
between them. The c^{3}\Pi_{u} and \as states are of particular importance for
the description of collisional processes between calcium atoms in the ground
state ^{1}S_{0} and excited state ^{3}P_{1} applied in studies for establishing
an optical frequency standard with Ca.Comment: 15 pages, 12 figure
The potential of the ground state of NaRb
The X state of NaRb was studied by Fourier transform
spectroscopy. An accurate potential energy curve was derived from more than
8800 transitions in isotopomers NaRb and NaRb. This
potential reproduces the experimental observations within their uncertainties
of 0.003 \rcm to 0.007 \rcm. The outer classical turning point of the last
observed energy level (, ) lies at \AA, leading
to a energy of 4.5 \rcm below the ground state asymptote.Comment: 8 pages, 6 figures and 2 table
The X and a states of LiCs studied by Fourier-transform spectroscopy
We present the first high-resolution spectroscopic study of LiCs. LiCs is
formed in a heat pipe oven and studied via laser-induced fluorescence
Fourier-transform spectroscopy. By exciting molecules through the
X-B and X-D transitions vibrational
levels of the X ground state have been observed up to 3cm^{-1}
below the dissociation limit enabling an accurate construction of the
potential. Furthermore, rovibrational levels in the a triplet
ground state have been observed because the excited states obtain sufficient
triplet character at the corresponding excited atomic asymptote. With the help
of coupled channels calculations accurate singlet and triplet ground state
potentials were derived reaching the atomic ground state asymptote and allowing
first predictions of cold collision properties of Li + Cs pairs.Comment: 10 pages, 5 figures. Submitted for publicatio
Spectroscopy of the a^3\Sigma_u^+ state and the coupling to the X^1\Sigma_g^+ state of K_2
We report on high resolution Fourier-transform spectroscopy of fluorescence
to the a^3\Sigma_u^+ state excited by two-photon or two-step excitation from
the X^1\Sigma_g^+ state to the 2^3\Pi_g state in the molecule K_2. These
spectroscopic data are combined with recent results of Feshbach resonances and
two-color photoassociation spectra for deriving the potential curves of
X^1\Sigma_g^+ and a^3\Sigma_u^+ up to the asymptote. The precise relative
position of the triplet levels with respect of the singlet levels was achieved
by including the excitation energies from the X^1\Sigma_g^+ state to the
2^3\Pi_g state and down to the a^3\Sigma_u^+ state in the simultaneous fit of
both potentials. The derived precise potential curves allow for reliable
modeling of cold collisions of pairs of potassium atoms in their ^2S ground
state
Formation of ultracold LiCs molecules
We present the first observation of ultracold LiCs molecules. The molecules
are formed in a two-species magneto-optical trap and detected by two-photon
ionization and time-of-flight mass spectrometry. The production rate
coefficient is found to be in the range 10^{-18}\unit{cm^3s^{-1}} to
10^{-16}\unit{cm^3s^{-1}}, at least an order of magnitude smaller than for
other heteronuclear diatomic molecules directly formed in a magneto-optical
trap.Comment: 8 pages, 2 figure
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