Surface-charge-induced freezing of colloidal suspensions

Using grand-canonical Monte Carlo simulations we investigate the impact of charged walls on the crystallization properties of charged colloidal suspensions confined between these walls. The investigations are based on an effective model focussing on the colloids alone. Our results demonstrate that the fluid-wall interaction stemming from charged walls has a crucial impact on the fluid's high-density behavior as compared to the case of uncharged walls. In particular, based on an analysis of in-plane bond order parameters we find surface-charge-induced freezing and melting transitions

Crystal structures and freezing of dipolar fluids

We investigate the crystal structure of classical systems of spherical particles with an embedded point dipole at T=0. The ferroelectric ground state energy is calculated using generalizations of the Ewald summation technique. Due to the reduced symmetry compared to the nonpolar case the crystals are never strictly cubic. For the Stockmayer (i.e., Lennard-Jones plus dipolar) interaction three phases are found upon increasing the dipole moment: hexagonal, body-centered orthorhombic, and body-centered tetragonal. An even richer phase diagram arises for dipolar soft spheres with a purely repulsive inverse power law potential $\sim r^{-n}$. A crossover between qualitatively different sequences of phases occurs near the exponent $n=12$. The results are applicable to electro- and magnetorheological fluids. In addition to the exact ground state analysis we study freezing of the Stockmayer fluid by density-functional theory.Comment: submitted to Phys. Rev.

Self-assembly of amphiphilic Janus particles at planar walls: A density functional study

We investigate the structure formation of amphiphilic molecules at planar walls using density functional theory. The molecules are modeled as (hard) spheres composed of a hydrophilic and hydrophobic part. The orientation of the resulting Janus-particles is described as a vector representing an internal degree of freedom. Our density functional approach involves Fundamental Measure Theory combined with a mean-field approximation for the anisotropic interaction. Considering neutral, hydrophilic and hydrophobic walls, we study the adsorption of the particles, focussing on the competition between the surface field and interact ion-induced ordering phenomena. Finally, we consider systems confined between two planar walls. It is shown that the anisotropic Janus interaction yields pronounced frustration effects at low temperatures.Comment: 11 page

Density functional formalism in the canonical ensemble

Density functional theory, when applied to systems with $T\neq 0$, is based on the grand canonical extension of the Hohenberg-Kohn-Sham theorem due to Mermin (HKSM theorem). While a straightforward canonical ensemble generalization fails, work in nanopore systems could certainly benefit from such extension. We show that, if the asymptotic behaviour of the canonical distribution functions is taken into account, the HKSM theorem can be extended to the canonical ensemble. We generate $N$-modified correlation and distribution functions hierarchies and prove that, if they are employed, either a modified external field or the density profiles can be indistinctly used as independent variables. We also write down the $N$% -modified free energy functional and prove that its minimum is reached when the equilibrium values of the new hierarchy are used. This completes the extension of the HKSM theorem.Comment: revtex, to be submitted to Phys. Rev. Let

Inhomogeneous magnetization in dipolar ferromagnetic liquids

At high densities fluids of strongly dipolar spherical particles exhibit spontaneous long-ranged orientational order. Typically, due to demagnetization effects induced by the long range of the dipolar interactions, the magnetization structure is spatially inhomogeneous and depends on the shape of the sample. We determine this structure for a cubic sample by the free minimization of an appropriate microscopic density functional using simulated annealing. We find a vortex structure resembling four domains separated by four domain walls whose thickness increases proportional to the system size L. There are indications that for large L the whole configuration scales with the system size. Near the axis of the mainly planar vortex structure the direction of the magnetization escapes into the third dimension or, at higher temperatures, the absolute value of the magnetization is strongly reduced. Thus the orientational order is characterized by two point defects at the top and the bottom of the sample, respectively. The equilibrium structure in an external field and the transition to a homogeneous magnetization for strong fields are analyzed, too.Comment: 17 postscript figures included, submitted to Phys. Rev.

Cosmological Effects of the First Stars: Evolving Spectra of Population III

The first stars hold intrinsic interest for their uniqueness and for their potential importance to galaxy formation, chemical enrichment, and feedback on the intergalactic medium (IGM). The metal-free composition of the first stars restricts the stellar energy source to proton-proton burning rather than the more efficient CNO cycle. Consequently they are hotter, smaller, and have harder spectra than their present-day counterparts of finite metallicity. We present new results from a continuing study of metal-free stars from a cosmological point of view. We have calculated evolving spectra of Pop III clusters, derived from a grid of zero-metallicity stellar evolutionary tracks. We find that H-ionizing photon production from metal-free stellar clusters takes twice as long as that of Pop II to decline to 1/10 its peak value. In addition, metal-free stars produce substantially more photons than Pop II in the HeII ($E > 4$ Ryd) continuum. We suggest that large Ly$\alpha$ equivalent widths ($W_{\rm Ly\alpha} > 400$ Angstroms) may provide a means of detecting metal-free stellar populations at high redshift, and that HeII recombination lines ($\lambda$1640, $\lambda$4686) may confirm identifications of Population III. While Pop III clusters are intrinsically bluer than their Pop II counterparts, nebular continuum emission makes up this difference and may confuse attempts to discern Pop III stars with broadband colors. In a companion paper, we explore the consequences of evolving spectra of Pop III for the reionization of the IGM in both H and He. (ABRIDGED)Comment: Accepted by ApJ; 32 pages, 10 figures, with an updated discussion of the effects of mass loss on Pop III and Pop II comparisons. For full-resolution color figures, see http://casa.colorado.edu/~tumlinso/fs.htm

Double-Mode Stellar Pulsations

The status of the hydrodynamical modelling of nonlinear multi-mode stellar pulsations is discussed. The hydrodynamical modelling of steady double-mode (DM) pulsations has been a long-standing quest that is finally being concluded. Recent progress has been made thanks to the introduction of turbulent convection in the numerical hydrodynamical codes which provide detailed results for individual models. An overview of the modal selection problem in the HR diagram can be obtained in the form of bifurcation diagrams with the help of simple nonresonant amplitude equations that capture the DM phenomenon.Comment: 34 pages, to appear as a chapter in Nonlinear Stellar Pulsation in the Astrophysics and Space Science Library (ASSL), Editors: M. Takeuti & D. Sasselov (prints double column with pstops '2:[email protected](22.0cm,-2cm)[email protected](22.0cm,11.0cm)' in.ps out.ps

Smart Containers With Bidding Capacity: A Policy Gradient Algorithm for Semi-Cooperative Learning

Smart modular freight containers -- as propagated in the Physical Internet paradigm -- are equipped with sensors, data storage capability and intelligence that enable them to route themselves from origin to destination without manual intervention or central governance. In this self-organizing setting, containers can autonomously place bids on transport services in a spot market setting. However, for individual containers it may be difficult to learn good bidding policies due to limited observations. By sharing information and costs between one another, smart containers can jointly learn bidding policies, even though simultaneously competing for the same transport capacity. We replicate this behavior by learning stochastic bidding policies in a semi-cooperative multi agent setting. To this end, we develop a reinforcement learning algorithm based on the policy gradient framework. Numerical experiments show that sharing solely bids and acceptance decisions leads to stable bidding policies. Additional system information only marginally improves performance; individual job properties suffice to place appropriate bids. Furthermore, we find that carriers may have incentives not to share information with the smart containers. The experiments give rise to several directions for follow-up research, in particular the interaction between smart containers and transport services in self-organizing logistics.Comment: 15 page

Does Being Bored Make Us More Creative?

Boredom has traditionally been associated with a range of negative outcomes, both within the workplace and outside it. More recently, however, it has been suggested that boredom can have positive outcomes, one of which might be increased creativity. This study addressed this proposition by examining the relationship between boredom and creative potential on a range of tasks. Two studies were carried out; the first involved 80 participants taking part in either a boring writing activity or not (control group) followed by a creative task. The second study involved a further 90 participants who varied in the type of boring activity they undertook (either a boring written activity, a boring reading activity or control) and the type of creative task that followed. Results suggested that boring activities resulted in increased creativity and that boring reading activities lead to more creativity in some circumstances (such as convergent tasks) than boring written activities. The role of daydreaming as a mediator between boredom and creativity is discussed and implications are outline