Thermodynamic properties of quadrupolar states in the frustrated pyrochlore magnet Tb2_2Ti2_2O7_7

The low-temperature thermodynamic properties of the frustrated pyrochlore Tb$_{2+x}$Ti$_{2-x}$O$_{7+y}$ have been studied using the single crystal of $x=0.005$ sitting in a long range ordered phase in the $x$-$T$ phase diagram. We observed that the specific heat exhibits a minimum around 2 K and slightly increases on cooling, similar to a Schottky-like anomaly for canonical spin ices. A clear specific-heat peak observed at $T_{\rm c} = 0.53$ K is ascribable to the phase transition to a quadrupolar state, which contributes to a relatively large change in entropy, $S \simeq 2.7$ J K$^{-1}$mol$^{-1}$. However, it is still smaller than $R\ln2$ for the ground state doublet of the Tb ions. The entropy release persists to higher temperatures, suggesting strong fluctuations associated with spin ice correlations above $T_{\rm c}$. We discuss the field dependence of the entropy change for $H||[111]$ and $H||[001]$.Comment: 6 pages, 2 figure

Multiple superconducting transitions in the Sr3Ru2O7 region of Sr3Ru2O7-Sr2RuO4 eutectic crystals

We report superconducting properties of Sr3Ru2O7-Sr2RuO4 eutectic crystals, consisting of the spin-triplet superconductor Sr2RuO4 with a monolayer stacking of RuO2 planes and the metamagnetic normal metal Sr3Ru2O7 with a bilayer stacking. Although Sr3Ru2O7 has not been reported to exhibit superconductivity so far, our AC susceptibility measurements revealed multiple superconducting transitions occurring in the Sr3Ru2O7 region of the eutectic crystals. The diamagnetic shielding essentially reached the full fraction at low AC fields parallel to the c axis. However, both the shielding fraction and the onset temperature are easily suppressed by AC fields of larger than 0.1 mT-rms and no anomaly was observed in the specific heat. Moreover, the critical field curves of these transitions have a positive curvature near zero fields, which is different from the upper critical field curve of the bulk Sr2RuO4. These facts suggest that the superconductivity observed in the Sr3Ru2O7 region is not a bulk property. To explain these experimental results, we propose the scenario that stacking RuO2 planes, the building block of superconducting Sr2RuO4, are contained in the Sr3Ru2O7 region as stacking faults.Comment: 8 pages, 10 figures, accepted for publication in Phys. Rev.

Superconductivity in Sr2RuO4-Sr3Ru2O7 eutectic crystals

Superconducting behavior has been observed in the Sr2RuO4-Sr3Ru2O7 eutectic system as grown by the flux-feeding floating zone technique. A supercurrent flows across a single interface between Sr2RuO4 and Sr3Ru2O7 areas at distances that are far beyond those expected in a conventional proximity scenario. The current-voltage characteristics within the Sr3Ru2O7 macrodomain, as extracted from the eutectic, exhibit signatures of superconductivity in the bilayered ruthenate. Detailed microstructural, morphological and compositional analyses address issues on the concentration and the size of Sr2RuO4 inclusions within the Sr3Ru2O7 matrix. We speculate on the possibility of inhomogeneous superconductivity in the eutectic Sr3Ru2O7 and exotic pairing induced by the Sr2RuO4 inclusions.Comment: Pages 4, figures 3, submitted to Phys. Rev. Let

Quadrupole order in the frustrated pyrochlore magnet Tb2Ti2O7

TMU International Symposium on "New Quantum Phases Emerging from Novel Crystal Structure" 24–25 September 2015, Tokyo, Japan.We have studied the hidden long-range order (LRO) of the frustrated pyrochlore magnet Tb2Ti2O7 by means of specific-heat experiments and Monte-Carlo (MC) simulations, which has been discussed as the LRO of quadrupole moments inherent to the non-Kramers ion of Tb3+. We have found that the sharp specific-heat peak is collapsed into a broad hump by magnetic fields above 0.3 T for H//[001]. This result, qualitatively reproduced by MC simulations, suggests that a field-induced magnetic state overcomes the quadrupolar LRO state, as a similar case of a classical spin ice. The present results support the interpretation that Tb2+xTi2-xO7+y is a unique material in the boundary between the quadrupolar (x >= x(c) = -0.0025) and spin-liquid (x <= x(c)) states, where the magnetic field along the [001] axis is a tuning parameter which induces the magnetic ordered state