Direct current driven by ac electric field in quantum wells

It is shown that the excitation of charge carriers by ac electric field with zero average driving leads to a direct electric current in quantum well structures. The current emerges for both linear and circular polarization of the ac electric field and depends on the field polarization and frequency. We present a micoscopic model and an analytical theory of such a nonlinear electron transport in quantum wells with structure inversion asymmetry. In such systems, dc current is induced by ac electric field which has both the in-plane and out-of-plane components. The ac field polarized in the interface plane gives rise to a direct current if the quantum well is subjected to an in-plane static magnetic field.Comment: 6 pages, 3 figure

Superlattice properties of carbon nanotubes in a transverse electric field

Electron motion in a (n,1) carbon nanotube is shown to correspond to a de Broglie wave propagating along a helical line on the nanotube wall. This helical motion leads to periodicity of the electron potential energy in the presence of an electric field normal to the nanotube axis. The period of this potential is proportional to the nanotube radius and is greater than the interatomic distance in the nanotube. As a result, the behavior of an electron in a (n,1) nanotube subject to a transverse electric field is similar to that in a semiconductor superlattice. In particular, Bragg scattering of electrons from the long-range periodic potential results in the opening of gaps in the energy spectrum of the nanotube. Modification of the bandstructure is shown to be significant for experimentally attainable electric fields, which raises the possibility of applying this effect to novel nanoelectronic devices.Comment: 7 pages, 3 figure

Electron scattering in quantum wells subjected to an in-plane magnetic field

It is shown that the electron scattering by static defects, acoustic or optical phonons in quantum wells subjected to an in-plane magnetic field is asymmetric. The probability of scattering contains terms which are proportional to both the electron wave vector and the magnetic field components. The terms under study are caused by the lack of an inversion center in quantum wells due to structure or bulk inversion asymmetry although they are of pure diamagnetic origin. Such a magnetic field induced asymmetry of scattering can be responsible for a number of phenomena. In particular, the asymmetry of inelastic electron-phonon interaction leads to an electric current flow if only the electron gas is driven out of thermal equilibrium with the crystal lattice.Comment: 5 pages, 1 figur

Chirality effects in carbon nanotubes

We consider chirality related effects in optical, photogalvanic and electron-transport properties of carbon nanotubes. We show that these properties of chiral nanotubes are determined by terms in the electron effective Hamiltonian describing the coupling between the electron wavevector along the tube principal axis and the orbital momentum around the tube circumference. We develop a theory of photogalvanic effects and a theory of d.c. electric current, which is linear in the magnetic field and quadratic in the bias voltage. Moreover, we present analytic estimations for the natural circular dichroism and magneto-spatial effect in the light absorption.Comment: 23 pages, 3 figure

Magneto-Gyrotropic Photogalvanic Effects in Semiconductor Quantum Wells

We show that free-carrier (Drude) absorption of both polarized and unpolarized terahertz radiation in quantum well (QW) structures causes an electric photocurrent in the presence of an in-plane magnetic field. Experimental and theoretical analysis evidences that the observed photocurrents are spin-dependent and related to the gyrotropy of the QWs. Microscopic models for the photogalvanic effects in QWs based on asymmetry of photoexcitation and relaxation processes are proposed. In most of the investigated structures the observed magneto-induced photocurrents are caused by spin-dependent relaxation of non-equilibrium carriers

Highly Dispersed Palladium on Carbon Nanofibers for Hydrogenation of Nitrocompounds to Amines

The effect of palladium dispersion and nature of the support on catalytic performance in hydrogenation of nitrobenzene to aniline was studied. It was shown that the type of the support and modification of palladium with phosphorus make it possible to stabilize highly dispersed (1.5-2 nm) palladium particles in the metallic state, thus increasing the efficiency of new catalysts

Enhancing Electron Coherence via Quantum Phonon Confinement in Atomically Thin Nb3SiTe6

The extraordinary properties of two dimensional (2D) materials, such as the extremely high carrier mobility in graphene and the large direct band gaps in transition metal dichalcogenides MX2 (M = Mo or W, X = S, Se) monolayers, highlight the crucial role quantum confinement can have in producing a wide spectrum of technologically important electronic properties. Currently one of the highest priorities in the field is to search for new 2D crystalline systems with structural and electronic properties that can be exploited for device development. In this letter, we report on the unusual quantum transport properties of the 2D ternary transition metal chalcogenide - Nb3SiTe6. We show that the micaceous nature of Nb3SiTe6 allows it to be thinned down to one-unit-cell thick 2D crystals using microexfoliation technique. When the thickness of Nb3SiTe6 crystal is reduced below a few unit-cells thickness, we observed an unexpected, enhanced weak-antilocalization signature in magnetotransport. This finding provides solid evidence for the long-predicted suppression of electron-phonon interaction caused by the crossover of phonon spectrum from 3D to 2D.Comment: Accepted by Nature Physic