414 research outputs found

    Perfect separation of intraband and interband excitations in PdCoO2_2

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    The temperature dependence of the optical properties of the delafossite PdCoO2_2 has been measured in the a-b planes over a wide frequency range. The optical conductivity due to the free-carrier (intraband) response falls well below the interband transitions, allowing the plasma frequency to be determined from the ff-sum rule. Drude-Lorentz fits to the complex optical conductivity yield estimates for the free-carrier plasma frequency and scattering rate. The in-plane plasma frequency has also been calculated using density functional theory. The experimentally-determined and calculated values for the plasma frequencies are all in good agreement; however, at low temperature the optically-determined scattering rate is much larger than the estimate for the transport scattering rate, indicating a strong frequency-dependent renormalization of the optical scattering rate. In addition to the expected in-plane infrared-active modes, two very strong features are observed that are attributed to the coupling of the in-plane carriers to the out-of-plane longitudinal optic modes.Comment: 7 pages with five figures and three tables; 4 pages of supplementary materia

    Evidence of metallic clustering in annealed Ga1-xMnxAs from atypical scaling behavior of the anomalous Hall coefficient

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    We report on the anomalous Hall coefficient and longitudinal resistivity scaling relationships on a series of annealed Ga1-xMnxAs epilayers (x~0.055). As-grown samples exhibit scaling parameter n of ~ 1. Near the optimal annealing temperature, we find n ~ 2 to be consistent with recent theories on the intrinsic origins of anomalous Hall Effect in Ga1-xMnxAs. For annealing temperatures far above the optimum, we note n > 3, similar behavior to certain inhomogeneous systems. This observation of atypical behavior agrees well with characteristic features attributable to spherical resonance from metallic inclusions from optical spectroscopy measurements.Comment: 3 pages, 3 figure

    Magnetic frustration and spontaneous rotational symmetry breaking in PdCrO2

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    In the triangular layered magnet PdCrO2 the intralayer magnetic interactions are strong, however the lattice structure frustrates interlayer interactions. In spite of this, long-range, 120^\circ antiferromagnetic order condenses at TN=38T_N = 38~K. We show here through neutron scattering measurements under in-plane uniaxial stress and in-plane magnetic field that this occurs through a spontaneous lifting of the three-fold rotational symmetry of the nonmagnetic lattice, which relieves the interlayer frustration. We also show through resistivity measurements that uniaxial stress can suppress thermal magnetic disorder within the antiferromagnetic phase.Comment: 9 pages, 9 figure

    The changes of oil palm roots cell wall lipids during pathogenesis of Ganoderma boninense

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    One of the first physical defences of plants against fungal infection is their cell wall. Interaction between combinations of metabolism enzymes known as the "weapons" of pathogen and the host cell wall probably determines the fate of possible invasion of the pathogen in the host. The present work aims to study the biochemical changes of cell wall lipids of oil palm roots and to determine novel information on root cell wall composition during pathogenesis of Ganoderma boninense by using Gas Chromatography Mass Spectrometry. Based on Total Ion Chromatogram analysis, 67 compounds were found more abundant in the roots infected with G. boninense compared to the healthy roots (60 compounds). Interestingly, nine new compounds were identified from the cell wall lipids of roots infected with G. boninense. These includes Cyclohexane, 1,2-dimethyl-, Methyl 2-hydroxy 16-methyl-heptadecanoate, 2-Propenoic acid, methyl ester, Methyl 9-oxohexacosanoate, 5-[(3,7,11,15-Tetramethylhexadecyl) oxy]thiophene-2carboxylic acid, Ergosta-5,7,22,24(28)-tetraen-3beta-ol, 7-Hydroxy-3',4'-methylenedioxyflavan, Glycine and (S)-4'-Hydroxy-4-methoxydalbergione, this may involve as response to pathogen invasion. This paper provides an original comparative lipidomic analysis of oil palm roots cell wall lipids in plant defence during pathogenesis of G. boninense

    Field-induced instability of the quantum-spin-liquid ground state in the Jeff=12J_{\rm eff}=\frac{1}{2} triangular-lattice compound NaYbO2_2

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    Polycrystalline samples of NaYbO2_2 are investigated by bulk magnetization and specific-heat measurements, as well as by nuclear magnetic resonance (NMR) and electron spin resonance (ESR) as local probes. No signatures of long-range magnetic order are found down to 0.3~K, evidencing a highly frustrated spin-liquid-like ground state in zero field. Above 2\,T, signatures of magnetic order are observed in thermodynamic measurements, suggesting the possibility of a field-induced quantum phase transition. The 23^{23}Na NMR relaxation rates reveal the absence of magnetic order and persistent fluctuations down to 0.3~K at very low fields and confirm the bulk magnetic order above 2~T. The HH-TT phase diagram is obtained and discussed along with the existing theoretical concepts for layered spin-12\frac{1}{2} triangular-lattice antiferromagnetsComment: 4 figure

    Quasi two-dimensional Fermi surface topography of the delafossite PdRhO2

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    The authors acknowledge the financial support from the European Research Council (through the QUESTDO project), the Engineering and Physical Sciences Research Council UK (Grants No. EP/I031014/1 and No. EP/L015110/1), the Royal Society, and the Max-Planck Society.We report on a combined study of the de Haas-van Alphen effect and angle resolved photoemission spectroscopy on single crystals of the metallic delafossite PdRhO2 rounded off by ab initio band structure calculations. A high sensitivity torque magnetometry setup with SQUID readout and synchrotron-based photoemission with a light spot size of ~50μm enabled high resolution data to be obtained from samples as small as 150 × 100 × 20(μm)3. The Fermi surface shape is nearly cylindrical with a rounded hexagonal cross section enclosing a Luttinger volume of 1.00(1) electrons per formula unit.PostprintPeer reviewe
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