Synthesis of the metallocenes for the production of exotic high energy ion beams

Philosophiae Doctor - PhDThe Subatomic Physics Department of iThemba Laboratory for Accelerated Based Sciences (iThemba LABS) conducts experiments that require a variety of particle beams in order to study nuclear properties (reaction, structure, etc.) of various nuclides. These particle beams are accelerated using the K-200 Separated Sector Cyclotron (SSC) and delivered to different physics experimental vaults. Prior to acceleration, the particle beam is first ionised using an Electron Resonance Ion Source (ECRIS). The main goal of this study is the production of exotic metallic beams of 60Ni8+ and 62Ni8+ using ECRIS4, which are required for the Coulomb excitation experiments approved by the Programme Advisory Committee (PAC) at iThemba LABS. In order to provide the metallic beams of nickel, a development study of organometallic materials containing 60Ni and 62Ni isotopes in a form of metallocene complexes was undertaken. The nickelocene (NiCp2) complex, a member of the organometallic family, was synthesised at the Physics Target Laboratory of iThemba LABS for the first time. Method development involved the use of natural nickel during the multi-step synthesis before the use of enriched nickel-60 (60Ni) and nickel-62 (62Ni). Nine samples of NiCp2 were synthesised; two were isotopically enriched nickelocene (60NiCp2 and 62NiCp2). The percentage yields of the synthesised nickelocene samples ranged between 16 to 50 %, and samples were characterised by investigating their crystal structure and bonding arrangements in the complexes by X-ray diffraction (XRD) , Fourier Transform Infrared (FT-IR) spectroscopy, and Proton Nuclear Magnetic Resonance (1H NMR). The synthesised nickelocene were further used with ECRIS4 for the production of Ni beams on the Q-line of the cyclotron. The Metal Ions from Volatile Compounds (MIVOC) technique was used for the conversion of 60Ni and 62Ni to ion species. The method used the organometallic compounds which are volatile at specific pressures at ambient temperatures. Metallic ion beams of nickel were successfully produced after a carefully pre-sample conditioning in the MIVOC container before connecting the MIVOC set-up to the new injection system of the ECRIS4. Measured beam intensities during the experiment for both 60Ni+ and 62Ni+ were approximately 30 μA, optimum for physics measurements. The development of the MIVOC technique opens up new beam-target combinations with the use of new exotic stable beams for new science cases at iThemba LABS. Reactions in inverse kinematics, multi-step Coulomb-excitation and other types of reactions will immensely benefit from these developments

Synthesis and characterisation of 114Cd targets

>Magister Scientiae - MScTo study nuclear reactions and nuclear structures, target materials are bombarded with high-energy particles. The target material can either be in a form of a metal film or gas. A target material designed to study certain nuclear reactions or to produce nuclei to study their structure should yield as minimum as possible of competing reactions under ion bombardment. This requires a chemically and isotopically pure target material prepared as a self supporting thin film, or as alternative, prepared on a thin career foil. Additional requirement for lifetime measurement experiments are homogeneity and precise thickness of the target material. Some of the data obtained from the stopping power experiment where targets of 114Cd were used for lifetime measurement are presented. Moreover, a nuclear target should influence the spectroscopic resolution as little as possible. Thus, film thickness must be adjusted to the respective reaction under study while observing the optimum thickness homogeneity

Green synthesis of silica and silicon from agricultural residue sugarcane bagasse ash – A mini review

Silicon dioxide (SiO2), also known as silica, has received attention in recent years due to wide range of capable applications including biomedical/pharmaceutical, energy, food, and personal care products. This has accelerated research in the extraction of materials from various agricultural wastes; this review investigates the extraction of silica and silicon nanoparticles from sugarcane bagasse ash with potential applications in electronic devices. Specific properties of silica have attracted the interest of researchers, which include surface area, size, biocompatibility, and high functionality. The production of silica from industrial agricultural waste exhibits sustainability and potential reduction in waste production. Bagasse is sustainable and environmentally friendly; though considered waste, it could be a helpful component for sustainable progress and further technological advancement

Encapsulated Sulfur targets for light ion beam experiments

A new method was developed to produce enriched Sulfur targets with minimum loss of material. This was made possible by inserting Sulfur in-between two 0.5 μm Mylar foils (C10H8O4). The initial aim was to ensure that the Sulfur targets reduce by no more than 50% of the initial thickness within 24 hours under the equivalent of 10 J/cm2 of integrated energy deposition by an energetic (Eb > 50 MeV) proton beam. There is no loss of enriched material while making the target, as all the material is deposited within the surface area to be exposed to the beam. During beam irradiation, the targets were frequently swivelled in order to expose each part of the target to the beam and achieve homogeneous irradiation. Targets of 0.4 mg/cm2 thickness were produced and characterised using ion beam analysis technique with a 3 MeV proton beam

Encapsulated Sulfur targets for light ion beam experiments

International audienceA new method was developed to produce enriched Sulfur targets with minimum loss of material. This was made possible by inserting Sulfur in-between two 0.5 μm Mylar foils (C10H8O4). The initial aim was to ensure that the Sulfur targets reduce by no more than 50% of the initial thickness within 24 hours under the equivalent of 10 J/cm2 of integrated energy deposition by an energetic (Eb > 50 MeV) proton beam. There is no loss of enriched material while making the target, as all the material is deposited within the surface area to be exposed to the beam. During beam irradiation, the targets were frequently swivelled in order to expose each part of the target to the beam and achieve homogeneous irradiation. Targets of 0.4 mg/cm2 thickness were produced and characterised using ion beam analysis technique with a 3 MeV proton beam

Encapsulated Sulfur targets for light ion beam experiments

A new method was developed to produce enriched Sulfur targets with minimum loss of material. This was made possible by inserting Sulfur in-between two 0.5 μm Mylar foils (C10H8O4). The initial aim was to ensure that the Sulfur targets reduce by no more than 50% of the initial thickness within 24 hours under the equivalent of 10 J/cm2 of integrated energy deposition by an energetic (Eb > 50 MeV) proton beam. There is no loss of enriched material while making the target, as all the material is deposited within the surface area to be exposed to the beam. During beam irradiation, the targets were frequently swivelled in order to expose each part of the target to the beam and achieve homogeneous irradiation. Targets of 0.4 mg/cm2 thickness were produced and characterised using ion beam analysis technique with a 3 MeV proton beam