223 research outputs found
ISO Spectroscopy of Young Stellar Objects
Observations of gas-phase and solid-state species toward
young stellar objects (YSOs) with the spectrometers
on board the Infrared Space Observatory
are reviewed. The excitation and abundances of
the atoms and molecules are sensitive to the changing
physical conditions during star-formation. In
the cold outer envelopes around YSOs, interstellar
ices contain a significant fraction of the heavy element
abundances, in particular oxygen. Different ice
phases can be distinguished, and evidence is found for
heating and segregation of the ices in more evolved
objects. The inner warm envelopes around YSOs are
probed through absorption and emission of gas-phase
molecules, including CO, CO_2, CH_4 and H_2O. An
overview of the wealth of observations on gas-phase
H_2O in star-forming regions is presented. Gas/solid
ratios are determined, which provide information on
the importance of gas-grain chemistry and high temperature
gas-phase reactions. The line ratios of molecules
such as H_2, CO and H_2O are powerful probes
to constrain the physical parameters of the gas. Together
with atomic and ionic lines such as [0 I]
63 µm, [S I] 25 µm and (Si II] 35 µm, they can also
be used to distinguish between photon- and shock-heated
gas. Finally, spectroscopic data on circumstellar
disks around young stars are mentioned. The
results are discussed in the context of the physical
and chemical evolution of YSOs
On the global hydration kinetics of tricalcium silicate cement
We reconsider a number of measurements for the overall hydration kinetics of
tricalcium silicate pastes having an initial water to cement weight ratio close
to 0.5. We find that the time dependent ratio of hydrated and unhydrated silica
mole numbers can be well characterized by two power-laws in time, . For early times we find an `accelerated' hydration
() and for later times a `deaccelerated' behavior (). The crossover time is estimated as . We
interpret these results in terms of a global second order rate equation
indicating that (a) hydrates catalyse the hydration process for , (b)
they inhibit further hydration for and (c) the value of the
associated second order rate constant is of magnitude 6x10^{-7} - 7x10^{-6}
liter mol^{-1} s^{-1}. We argue, by considering the hydration process actually
being furnished as a diffusion limited precipitation that the exponents and directly indicate a preferentially `plate' like hydrate
microstructure. This is essentially in agreement with experimental observations
of cellular hydrate microstructures for this class of materials.Comment: RevTeX macros, 6 pages, 4 postscript figure
Changing energy profiles and consumption patterns following electrification in five rural villages, South Africa
Following the democratic transition in South Africa in the early 1990s the government has implemented a widespread electrification programme, as well as introduced a free basic electricity allowance as a means of poverty alleviation. Yet there are limited longitudinal studies on the impacts of the introduction of electricity on the patterns of household energy use, and even more so in the neglected rural sector. This study reports on the patterns of household energy use in five rural settlements in 1991 and again in 2002. Results indicate a changing pattern of energy use for lighting and powering entertainment appliances, more specifically from dry-cell batteries and paraffin to electricity. Yet for thermal needs, most notably cooking, fuelwood has remained the most widespread fuel, and the amount used per month has not changed, despite increasing scarcity of wood in the local environment. There has been an increase in the proportion of households purchasing fuelwood as opposed to collecting their own. Overall, the mean total number of fuel types used per household has increased, indicating that electricity is simply viewed as an additional energy, rather than an alternative. Yet, electricity accounted for approximately 60% of expenditure on energy sources in 2002, despite the government's policy of a free basic allowance of 5–6 kWh per month. This has implications for energy supply costing, as well as the poverty alleviation dimensions of the whole programme
Guided internet-based transdiagnostic individually tailored Cognitive Behavioral Therapy for symptoms of depression and/or anxiety in college students: A randomized controlled trial
Pathways through Adolescenc
Propagation and Structure of Planar Streamer Fronts
Streamers often constitute the first stage of dielectric breakdown in strong
electric fields: a nonlinear ionization wave transforms a non-ionized medium
into a weakly ionized nonequilibrium plasma. New understanding of this old
phenomenon can be gained through modern concepts of (interfacial) pattern
formation. As a first step towards an effective interface description, we
determine the front width, solve the selection problem for planar fronts and
calculate their properties. Our results are in good agreement with many
features of recent three-dimensional numerical simulations.
In the present long paper, you find the physics of the model and the
interfacial approach further explained. As a first ingredient of this approach,
we here analyze planar fronts, their profile and velocity. We encounter a
selection problem, recall some knowledge about such problems and apply it to
planar streamer fronts. We make analytical predictions on the selected front
profile and velocity and confirm them numerically.
(abbreviated abstract)Comment: 23 pages, revtex, 14 ps file
Orbital state and magnetic properties of LiV_2 O_4
LiV_2 O_4 is one of the most puzzling compounds among transition metal oxides
because of its heavy fermion like behavior at low temperatures. In this paper
we present results for the orbital state and magnetic properties of LiV_2 O_4
obtained from a combination of density functional theory within the local
density approximation and dynamical mean-field theory (DMFT). The DMFT
equations are solved by quantum Monte Carlo simulations. The trigonal crystal
field splits the V 3d orbitals such that the a_{1g} and e_{g}^{pi} orbitals
cross the Fermi level, with the former being slightly lower in energy and
narrower in bandwidth. In this situation, the d-d Coulomb interaction leads to
an almost localization of one electron per V ion in the a_{1g} orbital, while
the e_{g}^{pi} orbitals form relatively broad bands with 1/8 filling. 2The
theoretical high-temperature paramagnetic susceptibility chi(T) follows a
Curie-Weiss law with an effective paramagnetic moment p_{eff}=1.65 in agreement
with the experimental results.Comment: 11 pages, 10 figures, 2 table
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