Effects of real-time thermal aging on graphite/polyimide composites

As part of a program to evaluate high-temperature advanced composites for use on supersonic cruise transport aircraft, two graphite/polyimide composites have been aged at elevated temperatures for times up to 5.7 years. Work on the first, HT-S/710 graphite/polyimide, was started in 1974. Evaluation of the second polyimide, Celion 6000/LARC-160, began in 1980. Baseline properties are presented, including unnotched and notched tensile data as a function of temperature, compression, flexure, shear, and constant-amplitude fatigue data at R = 0.1 and R = -1. Tensile specimens were aged in ovens where pressure and aging temperatures were controlled for various times up to and including 50,000 hours. Changes in tensile strength were determined and plotted as a function of aging time. The HT-S/710 composite aged at 450 F and 550 F if compared to the Celion 6000/LARC-160 composite aged at 350 F and 450 F. After tensile testing, many of the thermal aging specimens were examined using a scanning electron microscope. Results of these studies are presented, and changes in properties and degradation mechanisms during high-temperature aging are discussed and illustrated using metallographic techniques

In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one-pot conversion of ketones to silyl enol ethers

Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes2Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readily accessible temperatures and without any nucleophilic addition, in an expedient and high yielding one-pot process

Rational-spline approximation with automatic tension adjustment

An algorithm for weighted least-squares approximation with rational splines is presented. A rational spline is a cubic function containing a distinct tension parameter for each interval defined by two consecutive knots. For zero tension, the rational spline is identical to a cubic spline; for very large tension, the rational spline is a linear function. The approximation algorithm incorporates an algorithm which automatically adjusts the tension on each interval to fulfill a user-specified criterion. Finally, an example is presented comparing results of the rational spline with those of the cubic spline

The Greater Sum of Collaboration: Adding Value to Mathematics Education Through Teamwork

The role of a Mathematics Specialist can vary from pre-K through grade 8 schools. One of the most distinguishing factors involves the relationship between the Mathematics Specialists, administrators, and teachers. In this article, we share our experiences in a school culture that supports common language, collective commitments, trust, and transparency. Using this model, we have experienced high levels of teacher professionalism and student success. As lifelong learners, we continually reflect upon our practices and look for ways to meet the needs of our students. This occurs by implementing purposeful meeting structures that allow us to facilitate discussions around mathematics content, lesson planning, assessment results, and student progress. Administrators Brian Butler and Diane Kerr, along with Mathematics Specialists Tracey Hulen and Jennifer Deinhart, have formed a powerful relationship at Mason Crest Elementary School. This is a Title I school with 560 students, pre-K through grade 5, which promotes reflective practices and allows for flexibility and creativity as we continue to strengthen and improve our practices. Together, we share a story of our collaborative journey with teachers and students to create an effective mathematics program that embraces a conceptual learning philosophy. Ultimately there are two kinds of schools: learning-enriched schools and learning impoverished schools. I have yet to see a school where the learning curves ... of the adults were steeped upward and those of the students were not. Teachers and students go hand in hand as learners ... or they don\u27t go at all. [1] Roland Barth, Hand in Hand, We All Lear

Detection of amblyopia utilizing generated retinal reflexes

Investigation confirmed that GRR images can be consistently obtained and that these images contain information required to detect the optical inequality of one eye compared to the fellow eye. Digital analyses, electro-optical analyses, and trained observers were used to evaluate the GRR images. Two and three dimensional plots were made from the digital analyses results. These plotted data greatly enhanced the GRR image content, and it was possible for nontrained observers to correctly identify normal vs abnormal ocular status by viewing the plots. Based upon the criteria of detecting equality or inequality of ocular status of a person's eyes, the trained observer correctly identified the ocular status of 90% of the 232 persons who participated in this program

The Prophecies of the Naysayers - Assessing the Vision of the Protectionists in the U.S.-Canada Debate on Agricultural Reciprocity, 1846-1854

Debates over proposals to liberalise international trade are often heated and acrimonious. They are often argued, in part, on the basis of projections of market conditions after the proposed liberalisation. These argument are often important in influencing trade policy decisions, yet their accuracy is seldom assessed after liberalisation takes place. As a result, the projections may be more influential than they should be. This paper examines the projections of protectionists in the debate surrounding a proposed reciprocity agreement between the United States and British North America over the period 1846-1854 as a case study. The protectionist prophesies on both sides of the border were found not to be supported by the evidence from the subsequent period of reciprocity. A number of reasons for the inaccuracy of the projections are identified.agriculture, protection, reciprocity, trade agreement, International Relations/Trade,

Comparison of ground based and TOMS measurements of SO2 from volcanic emissions

The Brewer Ozone Spectrometer is being used in the World Ozone Network to monitor ozone and SO sub 2. SO sub 2 from natural as well as anthropogenic sources are measured. It has been demonstrated that SO sub 2 interferes with total ozone values as measured by the Dobson Spectrophotometer and the Total Ozone Mapping Spectrometer (TOMS). A small amount of manmade SO sub 2 is difficult to detect and quantify by TOMS because it is located near the surface. However, larger amounts of SO sub 2 injected into the stratosphere from volcanic emissions are detected by TOMS