16,043 research outputs found
The formation of mixed germanium–cobalt carbonyl clusters: an electrospray mass spectrometric study, and the structure of a high-nuclearity [Ge₂Co₁₀(CO)₂₄]²⁻ anion
The reaction of [µ₄-Ge{Co₂(CO)₇}₂] with [Co(CO)₄]⁻ has been monitored by electrospray mass spectrometry to detect the cluster anions generated. Conditions giving known mixed Ge–Co carbonyl clusters were established, and a new high nuclearity cluster anion, [Ge₂Co₁₀(CO)₂₄]²⁻ was detected. Conditions for its formation were optimised and it was subsequently isolated as its [Et₄N]⁺ salt and characterised by single-crystal X-ray crystallography. The Ge₂Co₁₀ cluster core has a novel geometry with the two germanium atoms in semi-encapsulated positions, forming seven formal Ge–Co bonds. There are also eighteen formal Co–Co bonds. Corresponding reactions of [µ₄-Si{Co₂(CO)₇}₂] with [Co(CO)₄]⁻ were also investigated
Winter Home Range and Habitat Use of the Virginia Northern Flying Squirrel (Glaucomys sabrinus fuscus)
We radio-tracked two male and one female Virginia northern flying squirrels (Glaucomys sabrinus fuscus) in the Allegheny Mountains of West Virginia at Snowshoe Mountain Resort, in winter 2003 and Canaan Valley National Wildlife Refuge in winter 2004, respectively, to document winter home range and habitat use in or near ski areas. Male home range size in the winter was larger than that reported for males during summer and fall, whereas the female home range we observed was smaller than those reported for summer and fall. However, winter habitat use was similar to summer and fall habitat use reported in other studies. Virginia northern flying squirrels foraged and denned in both red spruce (Picea rubens)-dominated forests and northern hardwood forests; however, selection of red spruce-dominated forests and open areas was greater than expected based on availability. Use of northern hardwood forest occurred less than expected based on availability. Male squirrels denned near, and routinely crossed, downhill ski slopes and unimproved roads during foraging bouts, whereas the female approached, but did not cross forest edges onto roads or trails
Fractional statistics in the fractional quantum Hall effect
A microscopic confirmation of the fractional statistics of the {\em
quasiparticles} in the fractional quantum Hall effect has so far been lacking.
We calculate the statistics of the composite-fermion quasiparticles at
and by evaluating the Berry phase for a closed loop
encircling another composite-fermion quasiparticle. A careful consideration of
subtle perturbations in the trajectory due to the presence of an additional
quasiparticle is crucial for obtaining the correct value of the statistics. The
conditions for the applicability of the fractional statistics concept are
discussed.Comment: Phys. Rev. Lett., in pres
Effect of cowpea flour processing on the chemical properties and acceptability of a novel cowpea blended maize porridge
Childhood growth stunting is a pervasive problem in Malawi and is in large part due to low quality complementary foods and chronic gut inflammation. Introducing legumes such as cowpea (Vigna unguiculata) into the complementary diet has the potential to improve childhood growth by improving diet quality through improvements in macro- and micronutrients and also by reducing gut inflammation. However, cowpea is relatively underutilized in complementary feeding in Malawi due to its strong taste, long processing time, and high energy requirements for processing. Effective utilization of cowpea in complementary feeding requires processing which may affect chemical composition as well as sensory quality. The present study evaluated the effect of processing on the retention of zinc, crude fibre, and flavonoid in roasted, boiled, and dehulled cowpea flours, and assessed the acceptability of maize porridge (70%) enriched with one of the three cowpea flours (30%). Roasting, dehulling, and boiling did not have any effect on zinc content. Crude fibre content increased after processing by all methods. Processing had no effect on measurable flavonoids. Roasted, boiled, and dehulled cowpea blended maize porridges were acceptable to children with mean quantities of leftover food of less than 3g from the given 100g. Caregivers also rated the blended flours to be highly acceptable to them as well, with maize porridge blended with dehulled cowpea flour the most acceptable to both children and caregivers. These results demonstrate that cowpea flour, processed by any of these three different methods, could serve as a useful addition to maize porridge for complementary feeding of children in sub-Saharan Africa
The Origin of C IV Absorption Systems at Redshifts z<1---Discovery of Extended C IV Envelopes Around Galaxies
(Abridged) We report the discovery of extended CIV gaseous envelopes around
galaxies of a wide range of luminosity and morphological type. First, we show
that CIV absorption systems are strongly clustered around galaxies on velocity
scales of v < 250 km/s and impact parameter scales of rho < 100 h^{-1} kpc but
not on larger velocity or impact parameter scales. Next, adopting measurements
of galaxy properties presented in previous papers, we examine how properties of
the CIV absorption systems depend on properties of the galaxies. On the basis
of 14 galaxy and absorber pairs and 36 galaxies that do not produce
corresponding CIV absorption lines to within sensitive upper limits, we find
that: (1) Galaxies of a range of morphological type and luminosity appear to
possess extended CIV gaseous envelopes of radius R ~ 100 h^{-1} kpc, with
abrupt boundaries between the CIV absorbing and non-absorbing regions. (2) The
extent of CIV-absorbing gas around galaxies scales with galaxy B-band
luminosity as R \propto L_B^{0.5 +/- 0.1} but does not depend strongly on
galaxy surface brightness, redshift, or morphological type. And (3) the
covering factor of CIV clouds within ~ 100 h^{-1} kpc of galaxies is nearly
unity, but there is a large scatter in the mean number of clouds encountered
along the line of sight. The most significant implication of the study is that
galaxies of a wide range of luminosity and morphological type are surrounded by
chemically enriched gas that extends for at least ~ 100 h^{-1} kpc. We consider
various scenarios that may have produced metals at large galactic distance and
conclude that accreting satellites are most likely to be responsible for
chemically enriched gas at large galactic distances to regular looking
galaxies.Comment: 19 pages, 3 figures, to appear in ApJ, July 20 200
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Riparian Meadow Response to Modern Conservation Grazing Management.
Riparian meadows occupy a small proportion of the public lands in the western United States but they provide numerous ecosystem services, including the production of high-quality forage for livestock grazing. Modern conservation management strategies (e.g., reductions in livestock stocking rates and adoption of new riparian grazing standards) have been implemented to better balance riparian conservation and livestock production objectives on publicly managed lands. We examined potential relationships between long-term changes in plant community, livestock grazing pressure and environmental conditions at two spatial scales in meadows grazed under conservation management strategies. Changes in plant community were not associated with either livestock stocking rate or precipitation at the grazing allotment (i.e., administrative) scale. Alternatively, both grazing pressure and precipitation had significant, albeit modest, associations with changes in plant community at the meadow (i.e., ecological site) scale. These results suggest that reductions in stocking rate have improved the balance between riparian conservation and livestock production goals. However, associations between elevation, site wetness, precipitation, and changes in plant community suggest that changing climate conditions (e.g., reduced snowpack and changes in timing of snowmelt) could trigger shifts in plant communities, potentially impacting both conservation and agricultural services (e.g., livestock and forage production). Therefore, adaptive, site-specific management strategies are required to meet grazing pressure limits and safeguard ecosystem services within individual meadows, especially under more variable climate conditions
Fast Genome-Wide QTL Association Mapping on Pedigree and Population Data
Since most analysis software for genome-wide association studies (GWAS)
currently exploit only unrelated individuals, there is a need for efficient
applications that can handle general pedigree data or mixtures of both
population and pedigree data. Even data sets thought to consist of only
unrelated individuals may include cryptic relationships that can lead to false
positives if not discovered and controlled for. In addition, family designs
possess compelling advantages. They are better equipped to detect rare
variants, control for population stratification, and facilitate the study of
parent-of-origin effects. Pedigrees selected for extreme trait values often
segregate a single gene with strong effect. Finally, many pedigrees are
available as an important legacy from the era of linkage analysis.
Unfortunately, pedigree likelihoods are notoriously hard to compute. In this
paper we re-examine the computational bottlenecks and implement ultra-fast
pedigree-based GWAS analysis. Kinship coefficients can either be based on
explicitly provided pedigrees or automatically estimated from dense markers.
Our strategy (a) works for random sample data, pedigree data, or a mix of both;
(b) entails no loss of power; (c) allows for any number of covariate
adjustments, including correction for population stratification; (d) allows for
testing SNPs under additive, dominant, and recessive models; and (e)
accommodates both univariate and multivariate quantitative traits. On a typical
personal computer (6 CPU cores at 2.67 GHz), analyzing a univariate HDL
(high-density lipoprotein) trait from the San Antonio Family Heart Study
(935,392 SNPs on 1357 individuals in 124 pedigrees) takes less than 2 minutes
and 1.5 GB of memory. Complete multivariate QTL analysis of the three
time-points of the longitudinal HDL multivariate trait takes less than 5
minutes and 1.5 GB of memory
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