29,245 research outputs found
Comparative effects of prolonged rotation at 10 rpm on postural equilibrium in vestibular normal and vestibular defective human subjects
Comparative effects of prolonged rotation on postural equilibrium in vestibular normal and defective human subject
First-place finish : imparting fine surface finishes when micromilling
There are several key milling practices that help impart fine surface finishes in micromilling. They include running at ultrahigh spindle speeds, carefully monitoring chip load, employing climb milling when possible and using CAM software to develop toolpaths that enhance surface finishes. There are also promising developments that can improve surface finishes in areas as diverse as using atomized cutting fluids and milling ultrafine-grain workpieces
A Selected Ion Flow Tube Study of the Reactions of Several Cations with the Group 6B Hexafluorides SF6, SeF6, and TeF6
The first investigation of the ion chemistry of SeF and TeF is presented. Using a selected ion flow tube, the thermal rate coefficients and ion product distributions have been determined at 300 K for the reactions of fourteen atomic and molecular cations, namely HO, CF, CF, CF, HO, NO, O, CO, CO, N, N, Ar, F and Ne (in order of increasing recombination energy), with SeF and TeF. The results are compared with those from the reactions of these ions with SF, for which the reactions with CF, CF, NO and F are reported for the first time. Several distinct processes are observed amongst the large number of reactions studied, including dissociative charge transfer, and F, F, F and F abstraction from the neutral reactant molecule to the reagent ion. The dissociative charge transfer channels are discussed in relation to vacuum ultraviolet photoelectron and threshold photoelectron-photoion coincidence spectra of XF (X = S, Se, and Te). For reagent ions whose recombination energies lie between the first dissociative ionisation limit, XF XF + F + e, and the onset of ionisation of the XF molecule, the results suggest that if dissociative charge transfer occurs, it proceeds via an intimate encounter. For those reagent ions whose recombination energies are greater than the onset of ionisation, long-range electron transfer may occur depending on whether certain physical factors apply, for example non-zero Franck-Condon overlap. From the reaction kinetics, limits for the heats of formation of SeF, SeF, TeF and TeF at 298 K have been obtained; H(SeF) < -369 kJ mol, H(SeF) < -621 kJ mol, H(TeF) > -570 kJ mol, and H(TeF) < -822 kJ mol
Motion sickness precipitated in the weightless phase of parabolic flight by Coriolis accelerations
Human motion sickness susceptibility when exposed to Coriolis accelerations during parabolic flight weightlessnes
N-heterocyclic germylenes: structural characterisation of some heavy analogues of the ubiquitous N-heterocyclic carbenes
The X-ray crystal structures of three N-heterocyclic germylenes (NHGes) have been elucidated including the previously unknown 1,3-bis(2,6-dimethylphenyl)diazagermol-2-ylidene (1). In addition, the X-ray crystal structures of the previously synthesised 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene (2) and 1,3-bis(2,6-diisopropylphenyl)diazagermol-2-ylidene (3) are also reported. The discrete molecular structures of compounds 1 to 3 are comparable, with Ge-N bond lengths in the range 1.835-1.875 Å, while the N-Ge-N bond angles range between 83.6 and 85.2°. Compound 2 was compared to the analogous N-heterocyclic carbene species, 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes). The major geometrical difference observed, as expected, was the bond angle around the divalent group 14 atom. The N-Ge-N bond angle was 83.6° for compound 2 versus the N-C-N bond angle of 101.4° for IMes. The Sn equivalent of (1), 1,3-bis(2,6-dimethylphenyl)diazastannol-2-ylidene (4), has also been synthesised and its crystal structure is reported here. In order to test their suitability as ligands, compounds 1 to 3 were reacted with a wide range of transition metal complexes. No NHGes containing metal complexes were observed. In all cases the NHGe either degraded or gave no reaction
Mission oriented study of advanced nuclear system parameters, phase 6. Volume 1 - Summary technical report Final report
Summarized study tasks, analyses, and results of advanced nuclear propulsion parameters for Mars and Venus mission
RURAL LAND VALUES AND TENURE ARRANGEMENTS IN LOUISIANA
This report presents the results from the first annual Louisiana Rural Land Market Survey. The survey was designed to collect detailed information from rural real estate professionals regarding market conditions in their areas. Results of this study suggest that land values vary by area of the state and the primary commodity grown on the tract. Substantial variation in land value within areas and by parish suggests a number of factors affect rural land values and markets. Further research will be designed to measure the effects of these various factors on rural real estate markets.Land Economics/Use,
Meningiomas occurring during long-term survival after treatment for childhood cancer
Childhood cancer is rare but improvements in treatment over the past five decades have resulted in a cohort of more than 30,000 long-term survivors of childhood cancer in the UK with more added annually. These long-term survivors are at risk of late effects of cancer treatment which replace original tumour recurrence as the leading cause of premature death. Second neoplasms are a particular risk and in the central nervous system meningiomas occur increasingly with increased radiation dose to central nervous system tissue and length of time after exposure, resulting in a 500-fold increase above that expected in the normal population by 40 years of follow up. This multidisciplinary author group and others met to discuss the issue. Our pooled information, and consensus that screening should only follow symptoms, was published online by the Royal College of Radiologists in 2013. We outline here the current knowledge and management of these neoplasms secondary to childhood cancer treatment
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