30 research outputs found
Bubble generation and molecular crystallization at solution surface by intense continuous-wave laser irradiation
We demonstrate bubble generation outside the focus induced by irradiating a focused 1064 nm continuous-wave laser beam into the surface of water and L-phenylalanine H2O solutions. In the former case of water, bubbles stay at positions distant from the focus during the irradiation, and their size and location are controllable by the laser power. In the latter solution, bubbles move outward toward the surrounding area, and subsequently crystallization takes place at the focus. We discuss these behaviors from the viewpoints of the temperature elevation accompanying the decrease in air solubility as well as the optical trapping of L-phenylalanine clusters giving a single crystal. (C) 2018 The Japan Society of Applied Physic
In situ reflection imaging and microspectroscopic study on three-dimensional crystal growth of L-phenylalanine under laser trapping
We investigate growth behavior of an L-phenylalanine crystal formed by laser trapping with the use of reflection imaging and microspectroscopy. Optical reflection micrographs show colored images of the crystal due to constructive interference of incident white light. The color distribution on the crystal is dynamically changed under laser trapping, which is in addition to enlargement of the crystal plane area. The temporal change in the crystal thickness is examined by measuring reflection spectra of the crystal. We discuss the three-dimensional crystal growth under laser trapping by comprehensively considering the changes in crystal thickness and crystal plane area. (C) 2019 The Japan Society of Applied Physic
Millimeter-Scale Dense Liquid Droplet Formation and Crystallization in Glycine Solution Induced by Photon Pressure
A millimeter-scale dense liquid droplet of glycine is prepared by focusing a CW near-infrared laser beam at the glass/solution interface of a thin film of its supersaturated heavy water solution. The formation process is investigated by direct observation with CCD and by measuring temporal change of the surface height with a displacement meter. The droplet becomes much larger than a focal spot size, a few mm width and ∼150 μm height, and observable with the naked eye. Interestingly, the droplet remains for a few tens of seconds even after switching off the laser beam. Whereas the droplet is kept during laser irradiation, the crystallization is immediately attained by shifting the laser beam to the air/droplet surface. It is considered that the droplet is possibly the early stage of the multistep crystallization process and plays an important role in photon pressure-induced crystallization of glycine
Laser Trapping and Crystallization Dynamics of l‑Phenylalanine at Solution Surface
We present laser trapping behavior of l-phenylalanine
(l-Phe) at a surface of its unsaturated aqueous solution
by a focused continuous-wave (CW) near-infrared (NIR) laser beam.
Upon the irradiation into the solution surface, laser trapping of
the liquid-like clusters is induced concurrently with local laser
heating, forming an anhydrous plate-like crystal at the focal spot.
The following laser irradiation into a central part of the plate-like
crystal leads to laser trapping at the crystal surface not only for l-Phe molecules/clusters but also for polystyrene (PS) particles.
The particles are closely packed at crystal edges despite that the
crystal surface is not illuminated by the laser directly. The molecules/clusters
are also gathered and adsorbed to the crystal surface, leading to
crystal growth. The trapping dynamics and mechanism are discussed
in view of optical potential formed at the crystal surface by light
propagation inside the crystal
In situ reflection imaging and microspectroscopic study on three-dimensional crystal growth of L-phenylalanine under laser trapping
Bubble generation and molecular crystallization at solution surface by intense continuous-wave laser irradiation
Photocontrolled Supramolecular Assembling of Azobenzene-Based Biscalix[4]arenes upon Starting and Stopping Laser Trapping.
Laser trapping in chemistry covers various studies ranging from single molecules, nanoparticles, and quantum dots to crystallization and liquid-liquid phase separation of amino acids. In this work, a supramolecular assembly of azobenzene-based biscalix[4]arene is generated in ethyl acetate using laser trapping; its nucleation and growth are elucidated. No trapping behavior was observed when a 1064 nm laser beam was focused inside of the solution; however, interesting assembling phenomena were induced when it was shined at the air/solution interface. A single disk having two layers was first prepared at the focal point of ∼1 μm and then expanded to the size of a few tens of micrometers, although no optical force was exerted outside of the focal volume. Upon switching the trapping laser off, needles were generated at the outer layer of the assembly, giving a stable sea urchin-like morphology to the generated assembly. At a 30-50% dilution of the initial solution in ethyl acetate, a mushroom-like morphology was also observed. Laser trapping-induced assembly of azobenzene-based biscalix[4]arene was quite different from the sharp-ellipsoidal aggregates obtained by the spontaneous evaporation of the solution. These trapping phenomena were specifically observed for biscalix[4]arene in the trans conformation of azo-benzene moiety but not for the cis-form, suggesting that the laser trapping of this azobenzene-based biscalix[4]arene is photocontrollable. Dynamics and mechanism of the supramolecular assembling are considered, referring to laser trapping-induced nucleation and liquid-liquid phase separation of amino acids.info:eu-repo/semantics/publishe
Formation, Dissolution, and Transfer Dynamics of a Millimeter-Scale Thin Liquid Droplet in Glycine Solution by Laser Trapping
The formation, dissolution, and transfer of a millimeter-scale
dense liquid droplet are demonstrated by focusing a CW near-infrared
laser beam into a thin film of glycine solution in heavy water. The
entire process is investigated by directly monitoring the temporal
change in the two-dimensional surface profile using a laser displacement
meter. Upon laser irradiation, the surface depression is initially
induced by laser heating, followed by the formation of the shallow
convex-shaped droplet around the focal spot, in which the droplet
is always in contact with the surrounding solution through the ultrathin
solution layer. After the laser is switched off, the dissolution occurs
through the recovery from the ultrathin layer toward the original
solution film. When the laser is set to the outside of the droplet,
the solution depression is similarly induced, and subsequently the
droplet starts moving toward the focal spot. These processes are summarized
and discussed in view of laser-induced effects of concentration increase
and temperature elevation