Concentrations and sources of polycyclic aromatic hydrocarbons in surface coastal sediments of the northern Gulf of Mexico

Zucheng Wang is with the Department of Geography, Northeast Normal University, Changchun, China. -- Zucheng Wang and Zhanfei Liu are with the Marine Science Institute, The University of Texas at Austin, Port Aransas, TX, USA. -- Kehui Xu is with the Department of Oceanography and Coastal Sciences, Louisiana State University, Baton Rouge, LA, USA – and – the Coastal Studies Institute, Louisiana State University, Baton Rouge, LA, USA. -- Lawrence M Mayer is with the School of Marine Sciences, University of Maine, Walpole, ME, USA. -- Zulin Zhang is with The James Hutton Institute, Aberdeen, UK. -- Alexander S. Kolker is with Louisiana Universities Marine Consortium, Chauvin, LA, USA. -- Wei Wu is with the Department of Coastal Sciences, Gulf Coast Research Laboratory, The University of Southern Mississippi, Ocean Springs, MS, USA.Background: Coastal sediments in the northern Gulf of Mexico have a high potential of being contaminated by petroleum hydrocarbons, such as polycyclic aromatic hydrocarbons (PAHs), due to extensive petroleum exploration and transportation activities. In this study we evaluated the spatial distribution and contamination sources of PAHs, as well as the bioavailable fraction in the bulk PAH pool, in surface marsh and shelf sediments (top 5 cm) of the northern Gulf of Mexico. Results: PAH concentrations in this region ranged from 100 to 856 ng g−1, with the highest concentrations in Mississippi River mouth sediments followed by marsh sediments and then the lowest concentrations in shelf sediments. The PAH concentrations correlated positively with atomic C/N ratios of sedimentary organic matter (OM), suggesting that terrestrial OM preferentially sorbs PAHs relative to marine OM. PAHs with 2 rings were more abundant than those with 5–6 rings in continental shelf sediments, while the opposite was found in marsh sediments. This distribution pattern suggests different contamination sources between shelf and marsh sediments. Based on diagnostic ratios of PAH isomers and principal component analysis, shelf sediment PAHs were petrogenic and those from marsh sediments were pyrogenic. The proportions of bioavailable PAHs in total PAHs were low, ranging from 0.02% to 0.06%, with higher fractions found in marsh than shelf sediments. Conclusion: PAH distribution and composition differences between marsh and shelf sediments were influenced by grain size, contamination sources, and the types of organic matter associated with PAHs. Concentrations of PAHs in the study area were below effects low-range, suggesting a low risk to organisms and limited transfer of PAHs into food web. From the source analysis, PAHs in shelf sediments mainly originated from direct petroleum contamination, while those in marsh sediments were from combustion of fossil fuels.Marine [email protected]

Evidence for Dirac Fermions in a honeycomb lattice based on silicon

Silicene, a sheet of silicon atoms in a honeycomb lattice, was proposed to be a new Dirac-type electron system similar as graphene. We performed scanning tunneling microscopy and spectroscopy studies on the atomic and electronic properties of silicene on Ag(111). An unexpected $\sqrt{3}\times \sqrt{3}$ reconstruction was found, which is explained by an extra-buckling model. Pronounced quasi-particle interferences (QPI) patterns, originating from both the intervalley and intravalley scattering, were observed. From the QPI patterns we derived a linear energy-momentum dispersion and a large Fermi velocity, which prove the existence of Dirac Fermions in silicene.Comment: 6 pages, 4 figure

Point defects in epitaxial silicene on Ag(111) surface

Silicene, a counterpart of graphene, has achieved rapid development due to its exotic electronic properties and excellent compatibility with the mature silicon-based semiconductor technology. Its low room-temperature mobility of about 100 cm2V-1s-1, however, inhibits device applications such as in field-effect transistors. Generally, defects and grain boundaries would act as scattering centers and thus reduce the carrier mobility. In this paper, the morphologies of various point defects in epitaxial silicene on Ag(111) surfaces have been systematically investigated using first-principles calculations combined with experimental scanning tunneling microscope (STM) observations. The STM signatures for various defects in epitaxial silicene on Ag(111) surface are identified. In particular, the formation energies of point defects in Ag(111)-supported silicene sheets show an interesting dependence on the superstructures, which, in turn, may have implications for controlling the defect density during the synthesis of silicene. Through estimating the concentrations of various point defects in different silicene superstructures, the mystery of the defective appearance of v13*v13 silicene in experiments is revealed, and 4*4 silicene sheet is thought to be the most suitable structure for future device applications.Comment: 29 pages, 14 figure

Sediment transport near ship shoal for coastal restoration in the Louisiana Shelf: a model estimate of the year 2017-2018

© The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Liu, H., Xu, K., Ou, Y., Bales, R., Zang, Z., & Xue, Z. G. Sediment transport near ship shoal for coastal restoration in the Louisiana Shelf: a model estimate of the year 2017-2018. Water, 12(8), (2020): 2212, doi:10.3390/w12082212.Ship Shoal has been a high-priority target sand resource for dredging activities to restore the eroding barrier islands in LA, USA. The Caminada and Raccoon Island pits were dredged on and near Ship Shoal, which resulted in a mixed texture environment with the redistribution of cohesive mud and noncohesive sand. However, there is very limited knowledge about the source and transport process of suspended muddy sediments near Ship Shoal. The objective of this study is to apply the Regional Ocean Modeling System (ROMS) model to quantify the sediment sources and relative contribution of fluvial sediments with the estuary and shelf sediments delivered to Ship Shoal. The model results showed that suspended mud from the Atchafalaya River can transport and bypass Ship Shoal. Only a minimal amount of suspended mud from the Atchafalaya River can be delivered to Ship Shoal in a one-year time scale. Additionally, suspended mud from the inner shelf could be transported cross Ship Shoal and generate a thin mud layer, which is also considered as the primary sediment source infilling the dredge pits near Ship Shoal. Two hurricanes and one tropical storm during the year 2017–2018 changed the direction of the sediment transport flux near Ship Shoal and contributed to the pit infilling (less than 10% for this specific period). Our model also captured that the bottom sediment concentration in the Raccoon Island pit was relatively higher than the one in Caminada in the same period. Suspended mud sediment from the river, inner shelf, and bay can bypass or transport and deposit in the Caminada pit and Raccoon Island pit, which showed that the Caminada pit and Raccoon Island pits would not be considered as a renewable borrow area for future sand dredging activities for coastal restoration.Funding for this study was provided by the U.S. Department of the Interior, Bureau of Ocean Energy Management, Coastal Marine Institute, Washington DC, under Cooperative Agreement Numbers M16AC00018 and M17AC00019