30 research outputs found
Determination of the complex refractive index and optical bandgap of CH3NH3PbI3 thin films
We report the complex refractive index of methylammonium lead iodide CH3NH3PbI3 perovskite thin films obtained by means of variable angle spectroscopic ellipsometry and transmittance reflectance spectrophotometry in the wavelength range of 190 amp; 8201;nm to 2500 amp; 8201;nm. The film thickness and roughness layer thickness are determined by minimizing a global unbiased estimator in the region where the spectrophotometry and ellipsometry spectra overlap. We then determine the optical bandgap and Urbach energy from the absorption coefficient, by means of a fundamental absorption model based on band fluctuations in direct emiconductors. This model merges both the Urbach tail and the absorption edge regions in a single equation. In this way, we increase the fitting region and extend the conventional amp; 945; amp; 8463; amp; 969; 2 plot method to obtain accurate bandgap value
Efficient Light Management by Textured Nanoimprinted Layers for Perovskite Solar Cells
Inorganic organic perovskites like methylammonium lead iodide have proven to be an effective class of materials for fabricating efficient solar cells. To improve their performance, light management techniques using textured surfaces, similar to those used in established solar cell technologies, should be considered. Here, we apply a light management foil created by UV nanoimprint lithography on the glass side of an inverted p i n perovskite solar cell with 16.3 efficiency. The obtained 1 mA cm 2 increase in the short circuit current density translates to a relative improvement in cell performance of 5 , which results in a power conversion efficiency of 17.1 . Optical 3D simulations based on experimentally obtained parameters were used to support the experimental findings. A good match between the simulated and experimental data was obtained, validating the model. Optical simulations reveal that the main improvement in device performance is due to a reduction in total reflection and that relative improvement in the short circuit current density of up to 10 is possible for large area devices. Therefore, our results present the potential of light management foils for improving the device performance of perovskite solar cells and pave the way for further use of optical simulations in the field of perovskite solar cell
Correction Roadmap and roadblocks for the band gap tunability of metal halide perovskites
Correction for âRoadmap and roadblocks for the band gap tunability of metal halide perovskitesâ by E. L. Unger et al., J. Mater. Chem. A, 2017, 5, 11401â11409.</p
Three Terminal Perovskite Silicon Tandem Solar Cells with Top and Interdigitated Rear Contacts
We present a three terminal 3T tandem approachfor the interconnection of a perovskite top cell with aninterdigitated back contact IBC silicon heterojunction SHJ bottom cell. The general viability of our cell design is verified withdrift diffusion simulations indicating efficient charge carriertransport throughout the whole device and an efficiency potentialof amp; 8776;27 by using readily available absorber and contact materials.Our experimental proof of concept device reaches a combinedPCE of 17.1 when both subcells are operating at their individualmaximum power point. To emulate different operation conditions,the current amp; 8722;voltage characteristics of both cells were obtained bymeasuring one subcell while the other cell was set to afixed biasvoltage. Only a slight mutual dependence of both subcells wasfound. As determined by electrical simulations, this dependence likely stems from the resistance of the electron contact on the cell srear side, which is shared by both subcells. The optimization of this contact turns out to be a major design criterion for IBC 3Ttandems. We demonstrate that our current proof of concept cells are limited by this series resistance as well as by optical losses, andwe discuss pathways to approach the simulated efficiency potential by an optimized device desig
It Takes Two to Tango Double Layer Selective Contacts in Perovskite Solar Cells for Improved Device Performance and Reduced Hysteresis
Solar cells made from inorganic amp; 8722;organic perovskites have gradually approached market requirements as their efficiency and stability have improved tremendously in recent years. Planar low temperature processed perovskite solar cells are advantageous for possible large scale production but are more prone to exhibiting photocurrent hysteresis, especially in the regular n amp; 8722;i amp; 8722;p structure. Here, a systematic characterization of different electron selective contacts with a variety of chemical and electrical properties in planar n amp; 8722;i amp; 8722;p devices processed below 180 C is presented. The inorganic metal oxides TiO2 and SnO2, the organic fullerene derivatives C60, PCBM, and ICMA, as well as double layers with a metal oxide PCBM structure are used as electron transport materials ETMs . Perovskite layers deposited atop the different ETMs with the herein applied fabrication method show a similar morphology according to scanning electron microscopy. Further, surface photovoltage spectroscopy measurements indicate comparable perovskite absorber qualities on all ETMs, except TiO2, which shows a more prominent influence of defect states. Transient photoluminescence studies together with current amp; 8722;voltage scans over a broad range of scan speeds reveal faster charge extraction, less pronounced hysteresis effects, and higher efficiencies for devices with fullerene compared to those with metal oxide ETMs. Beyond this, only ouble layer ETM structures substantially diminish hysteresis effects for all performed scan speeds and strongly enhance the power conversion efficiency up to a champion stabilized value of 18.0 . The results indicate reduced recombination losses for a double layer TiO2 PCBM contact design First, a reduction of shunt paths through the fullerene to the ITO layer. Second, an improved hole blocking by the wide band gap metal oxide. Third, decreased transport losses due to an energetically more favorable contact, as implied by photoelectron spectroscopy measurements. The herein demonstrated improvements of multilayer selective contacts may serve as a general design guideline for perovskite solar cell
Three Terminal Perovskite Silicon Tandem Solar Cells with Top and Interdigitated Back Contacts
Roadmap and roadblocks for the band gap tunability of metal halide perovskites
Solar cells based on metal halide perovskite semiconductors inspire high hopes for efficient low cost solar cell technology. This material class exhibits a facile tunability of the band gap making them interesting for multijunction device technology. We here compare and highlight trends in the band gap tunability and device performance metrics in reported metal halide perovskite alloys of a wide compositional range from low band gap compounds, such as FA0.75Cs0.25Sn0.5Pb0.5I3 with an absorption onset of 1.2 eV, to high bandgap compounds, such as CsPbBr3 with an absorption onset close to 2.4 eV. In between, metal halide perovskites can seemingly be seamlessly tuned by compositional engineering. However, mixed bromide iodide compounds with band gaps above 1.7 eV often exhibit photo induced phase segregation inducing domains with lower band gaps that emit photons of low energy. This effect also reduces the photoluminescence quantum yield and hence the maximum open circuit voltage achievable in devices. This highlight summarizes general trends for metal halide perovskites with respect to their absorption onset. Furthermore recent progress as well as possible roadblocks for the band gap tunability of metal halide perovskites are highlighted as this is of particular importance for the development of multifunction solar cell technolog