Dynamic elastic properties and magnetic susceptibility across the austenite-martensite transformation in site-disordered ferromagnetic Ni-Fe-Al alloy

Besides permitting an accurate determination of the ferromagnetic-to-paramagnetic phase transition temperature and the characteristic temperatures for the beginning and end of the growth of martensite (austenite) phase at the expense of austenite (martensite) phase while cooling (heating), the results of an extensive ac susceptibility, sound velocity and internal friction investigation of the thermoelastic martensitic transformation in melt-quenched (site-disordered) Ni55Fe20Al25 alloy provide a clear experimental evidence for the following. Irreversible thermoelastic changes (thermal hysteresis) occur in the austenite phase in the premartensitic regime. In the heating cycle, the system retains the "memory" of the initiation and subsequent growth of the martensitic phase (at the expense of the parent austenite phase) that had taken place during the cooling cycle in the austenite-martensite phase coexistence region. We report and discuss these novel findings in this communication.Comment: 5 figure

Chirality of Knots 9429_{42} and 107110_{71} and Chern-Simons Theory

Upto ten crossing number, there are two knots, $9_{42}$ and $10_{71}$ whose chirality is not detected by any of the known polynomials, namely, Jones invariants and their two variable generalisations, HOMFLY and Kauffman invariants. We show that the generalised knot invariants, obtained through $SU(2)$ Chern-Simons topological field theory, which give the known polynomials as special cases, are indeed sensitive to the chirality of these knots.Comment: 15 pages + 7 diagrams (available on request

Representations of Composite Braids and Invariants for Mutant Knots and Links in Chern-Simons Field Theories

We show that any of the new knot invariants obtained from Chern-Simons theory based on an arbitrary non-abelian gauge group do not distinguish isotopically inequivalent mutant knots and links. In an attempt to distinguish these knots and links, we study Murakami (symmetrized version) $r$-strand composite braids. Salient features of the theory of such composite braids are presented. Representations of generators for these braids are obtained by exploiting properties of Hilbert spaces associated with the correlators of Wess-Zumino conformal field theories. The $r$-composite invariants for the knots are given by the sum of elementary Chern-Simons invariants associated with the irreducible representations in the product of $r$ representations (allowed by the fusion rules of the corresponding Wess-Zumino conformal field theory) placed on the $r$ individual strands of the composite braid. On the other hand, composite invariants for links are given by a weighted sum of elementary multicoloured Chern-Simons invariants. Some mutant links can be distinguished through the composite invariants, but mutant knots do not share this property. The results, though developed in detail within the framework of $SU(2)$ Chern-Simons theory are valid for any other non-abelian gauge group.Comment: Latex, 25pages + 16 diagrams available on reques

Quantum phase transitions in bilayer SU(N) anti-ferromagnets

We present a detailed study of the destruction of SU(N) magnetic order in square lattice bilayer anti-ferromagnets using unbiased quantum Monte Carlo numerical simulations and field theoretic techniques. We study phase transitions from an SU(N) N\'eel state into two distinct quantum disordered "valence-bond" phases: a valence-bond liquid (VBL) with no broken symmetries and a lattice-symmetry breaking valence-bond solid (VBS) state. For finite inter-layer coupling, the cancellation of Berry phases between the layers has dramatic consequences on the two phase transitions: the N\'eel-VBS transition is first order for all $N\geq5$ accesible in our model, whereas the N\'eel-VBL transition is continuous for N=2 and first order for N>= 4; for N=3 the N\'eel-VBL transition show no signs of first-order behavior

Knot invariants from rational conformal field theories

A framework for studying knot and link invariants from any rational conformal field theory is developed. In particular, minimal models, superconformal models and $W_N$ models are studied. The invariants are related to the invariants obtained from the Wess-Zumino models associated with the coset representations of these models. Possible Chern-Simons representation of these models is also indicated. This generalises the earlier work on knot and link invariants from Chern-Simons theories.Comment: 18pages+6 figures (available on request through email

Two-dimensional frustrated spin systems in high magnetic fields

We discuss our numerical results on the properties of the S = 1/2 frustrated J1-J2 Heisenberg model on a square lattice as a function of temperature and frustration angle phi = atan(J2/J1) in an applied magnetic field. We cover the full phase diagram of the model in the range -pi <= phi <= pi. The discussion includes the parameter dependence of the saturation field itself, and addresses the instabilities associated with it. We also discuss the magnetocaloric effect of the model and show how it can be used to uniquely determine the effective interaction constants of the compounds which were investigated experimentally.Comment: 4 pages, 5 figures, proceedings of RHMF 200

Stereochemical control of peptide folding

Stereochemically constrained amino acid residues that strongly favour specific backbone conformations may be used to nucleate and stabilize specific secondary structures in designed peptides. An overview of the use of &#945;&#945;-dialkyl amino acids in stabilizing helical structures in synthetic peptides is presented, with an emphasis on work carried out in the authors laboratory. &#945;-Aminoisobutyric acid (Aib) and related achiral homologs facilitate stable helix formation in oligopeptides as exemplified by a large number of crystal structure determinations in the solid state. The ability to design conformationally rigid helical modules has been exploited in attempts to design structurally well characterized helix-linker-helix, using potential nonhelical linking segments. &#946;-Hairpin design has been approached by exploiting the tendency of 'prime turns' to nucleate hairpin formation. The use of nucleating DPro-Gly segments has resulted in the generation of several well characterized &#946;-hairpin structures, including the crystallographic observation of &#946;-hairpin in a synthetic apolar octapeptide. Extensions of this approach to three stranded &#946;-sheets and larger structures containing multiple DPro-Gly segments appear readily possible

Spin correlations and exchange in square lattice frustrated ferromagnets

The J1-J2 model on a square lattice exhibits a rich variety of different forms of magnetic order that depend sensitively on the ratio of exchange constants J2/J1. We use bulk magnetometry and polarized neutron scattering to determine J1 and J2 unambiguously for two materials in a new family of vanadium phosphates, Pb2VO(PO4)2 and SrZnVO(PO4)2, and we find that they have ferromagnetic J1. The ordered moment in the collinear antiferromagnetic ground state is reduced, and the diffuse magnetic scattering is enhanced, as the predicted bond-nematic region of the phase diagram is approached.Comment: 4 pages, 4 figure

Three-Manifold Invariants from Chern-Simons Field Theory with Arbitrary Semi-Simple Gauge Groups

Invariants for framed links in $S^3$ obtained from Chern-Simons gauge field theory based on an arbitrary gauge group (semi-simple) have been used to construct a three-manifold invariant. This is a generalization of a similar construction developed earlier for SU(2) Chern-Simons theory. The procedure exploits a theorem of Lickorish and Wallace and also those of Kirby, Fenn and Rourke which relate three-manifolds to surgeries on framed unoriented links. The invariant is an appropriate linear combination of framed link invariants which does not change under Kirby calculus. This combination does not see the relative orientation of the component knots. The invariant is related to the partition function of Chern-Simons theory. This thus provides an efficient method of evaluating the partition function for these field theories. As some examples, explicit computations of these manifold invariants for a few three-manifolds have been done.Comment: 24 pages Latex file, 26 eps files, included generalisations for arbitrary semi-simple group, corrected typo