Metal-Oxide-Based Microjets for the Simultaneous Removal of Organic Pollutants and Heavy Metals

Water contamination from industrial and anthropogenic activities is nowadays a major issue in many countries worldwide. To address this problem, efficient water treatment technologies are required. Recent efforts have focused on the development of self-propelled micromotors that provide enhanced micromixing and mass transfer by the transportation of reactive species, resulting in higher decontamination rates. However, a real application of these micromotors is still limited due to the high cost associated to their fabrication process. Here, we present Fe₂O₃-decorated SiO₂/MnO₂ microjets for the simultaneous removal of industrial organic pollutants and heavy metals present in wastewater. These microjets were synthesized by low-cost and scalable methods. They exhibit an average speed of 485 ± 32 μm s^–1 (∼28 body length per s) at 7% H₂O₂, which is the highest reported for MnO₂-based tubular micromotors. Furthermore, the photocatalytic and adsorbent properties of the microjets enable the efficient degradation of organic pollutants, such as tetracycline and rhodamine B under visible light irradiation, as well as the removal of heavy metal ions, such as Cd²⁺ and Pb²⁺

Metal-Oxide-Based Microjets for the Simultaneous Removal of Organic Pollutants and Heavy Metals

Water contamination from industrial and anthropogenic activities is nowadays a major issue in many countries worldwide. To address this problem, efficient water treatment technologies are required. Recent efforts have focused on the development of self-propelled micromotors that provide enhanced micromixing and mass transfer by the transportation of reactive species, resulting in higher decontamination rates. However, a real application of these micromotors is still limited due to the high cost associated to their fabrication process. Here, we present Fe₂O₃-decorated SiO₂/MnO₂ microjets for the simultaneous removal of industrial organic pollutants and heavy metals present in wastewater. These microjets were synthesized by low-cost and scalable methods. They exhibit an average speed of 485 ± 32 μm s^–1 (∼28 body length per s) at 7% H₂O₂, which is the highest reported for MnO₂-based tubular micromotors. Furthermore, the photocatalytic and adsorbent properties of the microjets enable the efficient degradation of organic pollutants, such as tetracycline and rhodamine B under visible light irradiation, as well as the removal of heavy metal ions, such as Cd²⁺ and Pb²⁺

Metal-Oxide-Based Microjets for the Simultaneous Removal of Organic Pollutants and Heavy Metals

Water contamination from industrial and anthropogenic activities is nowadays a major issue in many countries worldwide. To address this problem, efficient water treatment technologies are required. Recent efforts have focused on the development of self-propelled micromotors that provide enhanced micromixing and mass transfer by the transportation of reactive species, resulting in higher decontamination rates. However, a real application of these micromotors is still limited due to the high cost associated to their fabrication process. Here, we present Fe₂O₃-decorated SiO₂/MnO₂ microjets for the simultaneous removal of industrial organic pollutants and heavy metals present in wastewater. These microjets were synthesized by low-cost and scalable methods. They exhibit an average speed of 485 ± 32 μm s^–1 (∼28 body length per s) at 7% H₂O₂, which is the highest reported for MnO₂-based tubular micromotors. Furthermore, the photocatalytic and adsorbent properties of the microjets enable the efficient degradation of organic pollutants, such as tetracycline and rhodamine B under visible light irradiation, as well as the removal of heavy metal ions, such as Cd²⁺ and Pb²⁺

Metal-Oxide-Based Microjets for the Simultaneous Removal of Organic Pollutants and Heavy Metals

Water contamination from industrial and anthropogenic activities is nowadays a major issue in many countries worldwide. To address this problem, efficient water treatment technologies are required. Recent efforts have focused on the development of self-propelled micromotors that provide enhanced micromixing and mass transfer by the transportation of reactive species, resulting in higher decontamination rates. However, a real application of these micromotors is still limited due to the high cost associated to their fabrication process. Here, we present Fe₂O₃-decorated SiO₂/MnO₂ microjets for the simultaneous removal of industrial organic pollutants and heavy metals present in wastewater. These microjets were synthesized by low-cost and scalable methods. They exhibit an average speed of 485 ± 32 μm s^–1 (∼28 body length per s) at 7% H₂O₂, which is the highest reported for MnO₂-based tubular micromotors. Furthermore, the photocatalytic and adsorbent properties of the microjets enable the efficient degradation of organic pollutants, such as tetracycline and rhodamine B under visible light irradiation, as well as the removal of heavy metal ions, such as Cd²⁺ and Pb²⁺

Metal-Oxide-Based Microjets for the Simultaneous Removal of Organic Pollutants and Heavy Metals

Water contamination from industrial and anthropogenic activities is nowadays a major issue in many countries worldwide. To address this problem, efficient water treatment technologies are required. Recent efforts have focused on the development of self-propelled micromotors that provide enhanced micromixing and mass transfer by the transportation of reactive species, resulting in higher decontamination rates. However, a real application of these micromotors is still limited due to the high cost associated to their fabrication process. Here, we present Fe₂O₃-decorated SiO₂/MnO₂ microjets for the simultaneous removal of industrial organic pollutants and heavy metals present in wastewater. These microjets were synthesized by low-cost and scalable methods. They exhibit an average speed of 485 ± 32 μm s^–1 (∼28 body length per s) at 7% H₂O₂, which is the highest reported for MnO₂-based tubular micromotors. Furthermore, the photocatalytic and adsorbent properties of the microjets enable the efficient degradation of organic pollutants, such as tetracycline and rhodamine B under visible light irradiation, as well as the removal of heavy metal ions, such as Cd²⁺ and Pb²⁺

Metal-Oxide-Based Microjets for the Simultaneous Removal of Organic Pollutants and Heavy Metals

Water contamination from industrial and anthropogenic activities is nowadays a major issue in many countries worldwide. To address this problem, efficient water treatment technologies are required. Recent efforts have focused on the development of self-propelled micromotors that provide enhanced micromixing and mass transfer by the transportation of reactive species, resulting in higher decontamination rates. However, a real application of these micromotors is still limited due to the high cost associated to their fabrication process. Here, we present Fe₂O₃-decorated SiO₂/MnO₂ microjets for the simultaneous removal of industrial organic pollutants and heavy metals present in wastewater. These microjets were synthesized by low-cost and scalable methods. They exhibit an average speed of 485 ± 32 μm s^–1 (∼28 body length per s) at 7% H₂O₂, which is the highest reported for MnO₂-based tubular micromotors. Furthermore, the photocatalytic and adsorbent properties of the microjets enable the efficient degradation of organic pollutants, such as tetracycline and rhodamine B under visible light irradiation, as well as the removal of heavy metal ions, such as Cd²⁺ and Pb²⁺

Controlled Photocatalytic Oxidation of Methane to Methanol through Surface Modification of Beta Zeolites

The selective oxidation of methane to methanol is achieved by means of a photocatalytic process. For this purpose, designed Bi- and V-containing beta zeolites prepared by incipient wetness impregnation have been used under different test conditions. While the zeolite proves to be photoactive under UVC irradiation toward the total oxidation process, the formation of V₂O₅ on the surface is an effective alternative for modifying the acid–base surface properties, thus significantly decreasing the undesired CO₂ formation. At the same time the zeolite framework serves as a scaffold for increasing the surface area and distribution of the metal oxide. Additionally, the addition of low Bi amount favors the formation of a BiVO₄/V₂O₅ heterojunction, which acts as a visible light photocatalyst while at the same leading to total selectivity to methanol at the expense of ethylene formation

Discovery of Vibegron: A Potent and Selective β₃ Adrenergic Receptor Agonist for the Treatment of Overactive Bladder

The discovery of vibegron, a potent and selective human β₃-AR agonist for the treatment of overactive bladder (OAB), is described. An early-generation clinical β₃-AR agonist MK-0634 (<b>3</b>) exhibited efficacy in humans for the treatment of OAB, but development was discontinued due to unacceptable structure-based toxicity in preclinical species. Optimization of a series of second-generation pyrrolidine-derived β₃-AR agonists included reducing the risk for phospholipidosis, the risk of formation of disproportionate human metabolites, and the risk of formation of high levels of circulating metabolites in preclinical species. These efforts resulted in the discovery of vibegron, which possesses improved druglike properties and an overall superior preclinical profile compared to MK-0634. Structure–activity relationships leading to the discovery of vibegron and a summary of its preclinical profile are described