9 research outputs found
Removal of toxic Cr(VI) from water by a novel magnetic chitosan/glyoxal/PVA hydrogel film
<p>Coprecipitation of FeCl<sub>2</sub> and FeCl<sub>3</sub> produced magnetic iron nanoparticles (Fe<sub>3</sub>O<sub>4</sub>NPs). The latter was dispersed in an acetic acid solution of chitosan (CS), and then cross-linked with glyoxal, followed by addition of polyvinyl alcohol (PVA). The resulting gel was neutralized with NaOH giving our novel Fe<sub>3</sub>O<sub>4</sub>NPs/CS/glyoxal/PVA hydrogel film. This film was used as an efficient and reusable adsorbent for the removal of toxic Cr(VI) from water, at a rather wide range of pH. The absorbent film was characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared, and energy dispersive X-ray. Langmuir isotherm model suggested maximum Cr(VI) adsorption occurring at room temperature. Kinetic studies suggested a <i>pseudo</i>-second-order model for the adsorption. Our Fe<sub>3</sub>O<sub>4</sub>NPs/CS/glyoxal/PVA hydrogel is hoped to serve as a promising Cr(VI) adsorbent in wastewater treatment technology.</p